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Formation of an Atomically Abrupt Interface between a Polycyclic Aromatic Molecule and the Silicon (001) Surface via Direct Si−C Linkage
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    Formation of an Atomically Abrupt Interface between a Polycyclic Aromatic Molecule and the Silicon (001) Surface via Direct Si−C Linkage
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    Department of Chemistry, University of WisconsinMadison, 1101 University Avenue, Madison, Wisconsin 53706
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    The Journal of Physical Chemistry B

    Cite this: J. Phys. Chem. B 2003, 107, 1, 224–228
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    https://doi.org/10.1021/jp0265844
    Published December 10, 2002
    Copyright © 2003 American Chemical Society

    Abstract

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    The reaction of acenaphthylene with the Si(001) surface has been investigated as a model system for understanding how complex π-systems interact with a π-bonded semiconductor surface. Scanning tunneling microscopy (STM) reveals that bonding occurs over a dimer row for more than 90% of the adsorbed molecules. Fourier transform infrared spectroscopy (FTIR), using isotopically labeled derivatives of acenaphthylene, shows that bonding occurs through the 1,2-alkene, leaving the aromatic portion of the molecule mostly unperturbed. The reaction between acenaphthylene and Si(001) represents a potential method for coupling extended π-electron systems with group IV semiconductor surfaces.

    Copyright © 2003 American Chemical Society

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     Corresponding author. Phone:  608-262-6371. Fax:  608-262-0453. E-mail:  [email protected].

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    This article is cited by 18 publications.

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    The Journal of Physical Chemistry B

    Cite this: J. Phys. Chem. B 2003, 107, 1, 224–228
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jp0265844
    Published December 10, 2002
    Copyright © 2003 American Chemical Society

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