logo

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Phys. Chem. B 2006, 110, 25, 12682-12688
RETURN TO ISSUEPREVArticleNEXT

Dielectric Response of Imidazolium-Based Room-Temperature Ionic Liquids

View Author Information
Physical Chemistry 2, Ruhr-University Bochum, D-44780 Bochum, Germany, Ecole Polytechnique Fédérale de Lausanne, Institut des Sciences et Ingénerie Chimiques, CH-1015 Lausanne, Switzerland, and Institut für Anorganische und Analytische Chemie, Albert-Ludwigs-Universität Freiburg, Albertstrasse 21, D-79104 Freiburg, Germany
Cite this: J. Phys. Chem. B 2006, 110, 25, 12682–12688
Publication Date (Web):June 3, 2006
https://doi.org/10.1021/jp0604903
Copyright © 2006 American Chemical Society
RIGHTS & PERMISSIONS
Article Views
2556
Altmetric
-
Citations
255
LEARN ABOUT THESE METRICS
Read OnlinePDF (80 KB)
Get e-Alerts
SUBJECTS:

Abstract

We have used microwave dielectric relaxation spectroscopy to study the picosecond dynamics of five low-viscosity, highly conductive room temperature ionic liquids based on 1-alkyl-3-methylimidazolium cations paired with the bis((trifluoromethyl)sulfonyl)imide anion. Up to 20 GHz the dielectric response is bimodal. The longest relaxation component at the time scale of several 100 ps reveals strongly nonexponential dynamics and correlates with the viscosity in a manner consistent with hydrodynamic predictions for the diffusive reorientation of dipolar ions. Methyl substitution at the C2 position destroys this correlation. The time constants of the weak second process at the 20 ps time scale are practically the same for each salt. This intermediate process seems to correlate with similar modes in optical Kerr effect spectra, but its physical origin is unclear. The missing high-frequency portion of the spectra indicates relaxation beyond the upper cutoff frequency of 20 GHz, presumably due to subpicosecond translational and librational displacements of ions in the cage of their counterions. There is no evidence for orientational relaxation of long-lived ion pairs.

†

 Ecole Polytechnique Fédérale de Lausanne, Institut des Sciences et Ingénerie Chimiques.

§

 Institut für Anorganische und Analytische Chemie, Albert-Ludwigs-Universität Freiburg.

‡

 Physical Chemistry 2, Ruhr-University Bochum.

*

 To whom correspondence may be addressed. E-mail: [email protected]

Cited By

This article is cited by 255 publications.

  1. Filippa Lundin, Henriette Wase Hansen, Karolina Adrjanowicz, Bernhard Frick, Daniel Rauber, Rolf Hempelmann, Olga Shebanova, Kristine Niss, Aleksandar Matic. Pressure and Temperature Dependence of Local Structure and Dynamics in an Ionic Liquid. The Journal of Physical Chemistry B 2021, 125 (10) , 2719-2728. https://doi.org/10.1021/acs.jpcb.1c00147
  2. C. J. Kelsheimer, Sean Garrett-Roe. Intramolecular Vibrational Energy Relaxation of CO2 in Cross-Linked Poly(ethylene glycol) Diacrylate-Based Ion Gels. The Journal of Physical Chemistry B 2021, 125 (5) , 1402-1415. https://doi.org/10.1021/acs.jpcb.0c06685
  3. Vitor H. Paschoal, Mauro C. C. Ribeiro. Pseudo-Optical Modes in Room-Temperature Ionic Liquids. The Journal of Physical Chemistry B 2020, 124 (13) , 2661-2667. https://doi.org/10.1021/acs.jpcb.0c00890
  4. Daijiro Okaue, Ichiro Tanabe, Sakurako Ono, Kota Sakamoto, Taiki Sato, Akihito Imanishi, Yoshitada Morikawa, Jun Takeya, Ken-ichi Fukui. Ionic-Liquid-Originated Carrier Trapping Dynamics at the Interface in Electric Double-Layer Organic FET Revealed by Operando Interfacial Analyses. The Journal of Physical Chemistry C 2020, 124 (4) , 2543-2552. https://doi.org/10.1021/acs.jpcc.9b10636
  5. Derek Fujimoto, Ryan M. L. McFadden, Martin H. Dehn, Yael Petel, Aris Chatzichristos, Lars Hemmingsen, Victoria L. Karner, Robert F. Kiefl, C. D. Philip Levy, Iain McKenzie, Carl A. Michal, Gerald D. Morris, Matthew R. Pearson, Daniel Szunyogh, John O. Ticknor, Monika Stachura, W. Andrew MacFarlane. Dynamics of Liquid 1-Ethyl-3-Methylimidazolium Acetate Measured with Implanted-Ion 8Li β-NMR. Chemistry of Materials 2019, 31 (22) , 9346-9353. https://doi.org/10.1021/acs.chemmater.9b02864
  6. Shrikant P. Musale, Ashok C. Kumbharkhane, Dilip H. Dagade. Dielectric Relaxation and Hydration Interactions for Protic and Aprotic Ionic Liquids using Time Domain Reflectometry. The Journal of Physical Chemistry B 2019, 123 (42) , 8976-8986. https://doi.org/10.1021/acs.jpcb.9b07914
  7. Ejaj Tarif, Biswajit Saha, Kallol Mukherjee, Priyadarsi De, Ranjit Biswas. Exploring Aqueous Solution Dynamics of an Amphiphilic Diblock Copolymer: Dielectric Relaxation and Time-Resolved Fluorescence Measurements. The Journal of Physical Chemistry B 2019, 123 (27) , 5892-5901. https://doi.org/10.1021/acs.jpcb.9b00889
  8. Xinyu Wang, Songna Zhang, Jia Yao, Haoran Li. The Polarity of Ionic Liquids: Relationship between Relative Permittivity and Spectroscopic Parameters of Probe. Industrial & Engineering Chemistry Research 2019, 58 (17) , 7352-7361. https://doi.org/10.1021/acs.iecr.9b00485
  9. Xiao Zhang, Jing Zhao, Changhuai Ye, Tzu-Yu Lai, Chad R. Snyder, Alamgir Karim, Kevin A. Cavicchi, David S. Simmons. Dynamical Correlations for Statistical Copolymers from High-Throughput Broad-Band Dielectric Spectroscopy. ACS Combinatorial Science 2019, 21 (4) , 276-299. https://doi.org/10.1021/acscombsci.8b00160
  10. Savio J. Poovathingal, Timothy K. Minton, Robert K. Szilagyi. Evaluating Density Functionals by Examining Molecular Structures, Chemical Bonding, and Relative Energies of Mononuclear Ru–Cl–H–PR3 Isomers. The Journal of Physical Chemistry A 2019, 123 (1) , 343-358. https://doi.org/10.1021/acs.jpca.8b03216
  11. Edward Zorębski, Michał Zorębski, Małgorzata Musiał, and Marzena Dzida . Ultrasonic Relaxation Spectra for Pyrrolidinium Bis(trifluoromethylsulfonyl)imides: A Comparison with Imidazolium Bis(trifluoromethylsulfonyl)imides. The Journal of Physical Chemistry B 2017, 121 (42) , 9886-9894. https://doi.org/10.1021/acs.jpcb.7b07433
  12. Wei Guan, Ning Chang, Lili Yang, Xiaoxue Bu, Jie Wei, and Qingshan Liu . Determination and Prediction for the Polarity of Ionic Liquids. Journal of Chemical & Engineering Data 2017, 62 (9) , 2610-2616. https://doi.org/10.1021/acs.jced.7b00082
  13. Christopher A. Rumble, Anne Kaintz, Sharad K. Yadav, Brian Conway, Juan C. Araque, Gary A. Baker, Claudio Margulis, and Mark Maroncelli . Rotational Dynamics in Ionic Liquids from NMR Relaxation Experiments and Simulations: Benzene and 1-Ethyl-3-Methylimidazolium. The Journal of Physical Chemistry B 2016, 120 (35) , 9450-9467. https://doi.org/10.1021/acs.jpcb.6b06715
  14. Tamisra Pal and Ranjit Biswas . Composition Dependence of Dynamic Heterogeneity Time- and Length Scales in [Omim][BF4]/Water Binary Mixtures: Molecular Dynamics Simulation Study. The Journal of Physical Chemistry B 2015, 119 (51) , 15683-15695. https://doi.org/10.1021/acs.jpcb.5b08763
  15. Xiao-Song Xue, Ya Wang, Chen Yang, Pengju Ji, and Jin-Pei Cheng . Toward Prediction of the Chemistry in Ionic Liquids: An Accurate Computation of Absolute pKa Values of Benzoic Acids and Benzenethiols. The Journal of Organic Chemistry 2015, 80 (18) , 8997-9006. https://doi.org/10.1021/acs.joc.5b00693
  16. Alexander B. A. Rupp and Ingo Krossing . Ionic Liquids with Weakly Coordinating [MIII(ORF)4]− Anions. Accounts of Chemical Research 2015, 48 (9) , 2537-2546. https://doi.org/10.1021/acs.accounts.5b00247
  17. Robert Hayes, Gregory G. Warr, and Rob Atkin . Structure and Nanostructure in Ionic Liquids. Chemical Reviews 2015, 115 (13) , 6357-6426. https://doi.org/10.1021/cr500411q
  18. Kallol Mukherjee, Anuradha Das, Samiran Choudhury, Anjan Barman, and Ranjit Biswas . Dielectric Relaxations of (Acetamide + Electrolyte) Deep Eutectic Solvents in the Frequency Window, 0.2 ≤ ν/GHz ≤ 50: Anion and Cation Dependence. The Journal of Physical Chemistry B 2015, 119 (25) , 8063-8071. https://doi.org/10.1021/acs.jpcb.5b01502
  19. Issei Nakamura . Dipolar Self-Consistent Field Theory for Ionic Liquids: Effects of Dielectric Inhomogeneity in Ionic Liquids between Charged Plates. The Journal of Physical Chemistry C 2015, 119 (13) , 7086-7094. https://doi.org/10.1021/jp511770r
  20. Anirban Mondal and Sundaram Balasubramanian . Vibrational Signatures of Cation–Anion Hydrogen Bonding in Ionic Liquids: A Periodic Density Functional Theory and Molecular Dynamics Study. The Journal of Physical Chemistry B 2015, 119 (5) , 1994-2002. https://doi.org/10.1021/jp5113679
  21. Alpha A. Lee, Dominic Vella, Susan Perkin, and Alain Goriely . Are Room-Temperature Ionic Liquids Dilute Electrolytes?. The Journal of Physical Chemistry Letters 2015, 6 (1) , 159-163. https://doi.org/10.1021/jz502250z
  22. Jing Tong, Hong-Xu Yang, Ru-Jing Liu, Chi Li, Li-Xin Xia, and Jia-Zhen Yang . Determination of the Enthalpy of Vaporization and Prediction of Surface Tension for Ionic Liquid 1-Alkyl-3-methylimidazolium Propionate [Cnmim][Pro](n = 4, 5, 6). The Journal of Physical Chemistry B 2014, 118 (45) , 12972-12978. https://doi.org/10.1021/jp509240w
  23. Taro Uematsu, Masahiro Baba, Yoshifumi Oshima, Tetsuya Tsuda, Tsukasa Torimoto, and Susumu Kuwabata . Atomic Resolution Imaging of Gold Nanoparticle Generation and Growth in Ionic Liquids. Journal of the American Chemical Society 2014, 136 (39) , 13789-13797. https://doi.org/10.1021/ja506724w
  24. Victoria A. Nikitina, Alexander V. Rudnev, Galina A. Tsirlina, and Thomas Wandlowski . Long Distance Electron Transfer at the Metal/Alkanethiol/Ionic Liquid Interface. The Journal of Physical Chemistry C 2014, 118 (29) , 15970-15977. https://doi.org/10.1021/jp5055843
  25. B. Schmidtke, N. Petzold, B. Pötzschner, H. Weingärtner, and E. A. Rössler . Relaxation Stretching, Fast Dynamics, and Activation Energy: A Comparison of Molecular and Ionic Liquids as Revealed by Depolarized Light Scattering. The Journal of Physical Chemistry B 2014, 118 (25) , 7108-7118. https://doi.org/10.1021/jp412297u
  26. Youngseon Shim and Hyung J. Kim . Dielectric Relaxation and Solvation Dynamics in a Room-Temperature Ionic Liquid: Temperature Dependence. The Journal of Physical Chemistry B 2013, 117 (39) , 11743-11752. https://doi.org/10.1021/jp406353j
  27. Xin-Xing Zhang, Min Liang, Nikolaus P. Ernsting, and Mark Maroncelli . Complete Solvation Response of Coumarin 153 in Ionic Liquids. The Journal of Physical Chemistry B 2013, 117 (16) , 4291-4304. https://doi.org/10.1021/jp305430a
  28. Tsuyoshi Yamaguchi, Eiichiro Nakahara, Keitaro Sueda, and Shinobu Koda . Interpretation of the Variation of the Walden Product of Ionic Liquids with Different Alkyl Chain Lengths in Terms of Relaxation Spectra. The Journal of Physical Chemistry B 2013, 117 (15) , 4121-4126. https://doi.org/10.1021/jp401280a
  29. Maiko Kofu, Michihiro Nagao, Takeshi Ueki, Yuzo Kitazawa, Yutaro Nakamura, Syota Sawamura, Masayoshi Watanabe, and Osamu Yamamuro . Heterogeneous Slow Dynamics of Imidazolium-Based Ionic Liquids Studied by Neutron Spin Echo. The Journal of Physical Chemistry B 2013, 117 (9) , 2773-2781. https://doi.org/10.1021/jp312608r
  30. Todd M. Alam, Daniel R. Dreyer, Christopher W. Bielawski, and Rodney S. Ruoff . Combined Measurement of Translational and Rotational Diffusion in Quaternary Acyclic Ammonium and Cyclic Pyrrolidinium Ionic Liquids. The Journal of Physical Chemistry B 2013, 117 (6) , 1967-1977. https://doi.org/10.1021/jp3111953
  31. U Hyeok Choi, Anuj Mittal, Terry L. Price, Jr., Harry W. Gibson, James Runt, and Ralph H. Colby . Polymerized Ionic Liquids with Enhanced Static Dielectric Constants. Macromolecules 2013, 46 (3) , 1175-1186. https://doi.org/10.1021/ma301833j
  32. Koichi Fumino, Kai Wittler, and Ralf Ludwig . The Anion Dependence of the Interaction Strength between Ions in Imidazolium-Based Ionic Liquids Probed by Far-Infrared Spectroscopy. The Journal of Physical Chemistry B 2012, 116 (31) , 9507-9511. https://doi.org/10.1021/jp306173t
  33. Varinia S. Bernales, Aleksandr V. Marenich, Renato Contreras, Christopher J. Cramer, and Donald G. Truhlar . Quantum Mechanical Continuum Solvation Models for Ionic Liquids. The Journal of Physical Chemistry B 2012, 116 (30) , 9122-9129. https://doi.org/10.1021/jp304365v
  34. U Hyeok Choi, Minjae Lee, Sharon Wang, Wenjuan Liu, Karen I. Winey, Harry W. Gibson, and Ralph H. Colby . Ionic Conduction and Dielectric Response of Poly(imidazolium acrylate) Ionomers. Macromolecules 2012, 45 (9) , 3974-3985. https://doi.org/10.1021/ma202784e
  35. Yiwei Lian and Kongshuang Zhao . Dielectric Analysis of Micelles and Microemulsions Formed in a Hydrophilic Ionic Liquid. I. Interaction and Percolation. The Journal of Physical Chemistry B 2011, 115 (39) , 11368-11374. https://doi.org/10.1021/jp205493r
  36. Yuki Kato, Yoshiaki Imanishi, Masaaki Taguchi, Mami Wayama, and Tadashi Watanabe . Anomalous Charge Transfer Behavior of an Iodide/Triiodide Redox Couple at an Ionic Liquid/Pt-Electrode Interface. The Journal of Physical Chemistry C 2011, 115 (33) , 16637-16643. https://doi.org/10.1021/jp204812k
  37. Jason P. Hallett and Tom Welton . Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2. Chemical Reviews 2011, 111 (5) , 3508-3576. https://doi.org/10.1021/cr1003248
  38. Jan Forsman, Clifford E. Woodward, and Martin Trulsson . A Classical Density Functional Theory of Ionic Liquids. The Journal of Physical Chemistry B 2011, 115 (16) , 4606-4612. https://doi.org/10.1021/jp111747w
  39. Mian-Mian Huang, Yanping Jiang, Padmanabhan Sasisanker, Gordon W. Driver, and Hermann Weingärtner . Static Relative Dielectric Permittivities of Ionic Liquids at 25 °C. Journal of Chemical & Engineering Data 2011, 56 (4) , 1494-1499. https://doi.org/10.1021/je101184s
  40. S. S. Sarangi, S. K. Reddy, and S. Balasubramanian . Low Frequency Vibrational Modes of Room Temperature Ionic Liquids. The Journal of Physical Chemistry B 2011, 115 (8) , 1874-1880. https://doi.org/10.1021/jp111420q
  41. V. Rodriguez, J. Grondin, F. Adamietz, and Y. Danten. Local Structure in Ionic Liquids Investigated by Hyper-Rayleigh Scattering. The Journal of Physical Chemistry B 2010, 114 (46) , 15057-15065. https://doi.org/10.1021/jp107165k
  42. Yoshifumi Kimura, Masanori Fukuda, Kayo Suda and Masahide Terazima. Excited State Intramolecular Proton Transfer Reaction of 4′-N,N-Diethylamino-3-hydroxyflavone and Solvation Dynamics in Room Temperature Ionic Liquids Studied by Optical Kerr Gate Fluorescence Measurement. The Journal of Physical Chemistry B 2010, 114 (36) , 11847-11858. https://doi.org/10.1021/jp105033q
  43. Kenji Nakamura, Tatsuya Saiwaki and Koji Fukao. Dielectric Relaxation Behavior of Polymerized Ionic Liquid. Macromolecules 2010, 43 (14) , 6092-6098. https://doi.org/10.1021/ma100918e
  44. Thierry Buffeteau, Joseph Grondin, Yann Danten and Jean-Claude Lassègues. Imidazolium-Based Ionic Liquids: Quantitative Aspects in the Far-Infrared Region. The Journal of Physical Chemistry B 2010, 114 (22) , 7587-7592. https://doi.org/10.1021/jp102087m
  45. Tianying Yan, Yanting Wang and Craig Knox . On the Dynamics of Ionic Liquids: Comparisons between Electronically Polarizable and Nonpolarizable Models II. The Journal of Physical Chemistry B 2010, 114 (20) , 6886-6904. https://doi.org/10.1021/jp908914d
  46. Berit Heggen, Wei Zhao, Frédéric Leroy, Anton J. Dammers and Florian Müller-Plathe . Interfacial Properties of an Ionic Liquid by Molecular Dynamics. The Journal of Physical Chemistry B 2010, 114 (20) , 6954-6961. https://doi.org/10.1021/jp911128j
  47. Santiago Aparicio, Rafael Alcalde and Mert Atilhan. Experimental and Computational Study on the Properties of Pure and Water Mixed 1-Ethyl-3-methylimidazolium l-(+)-Lactate Ionic Liquid. The Journal of Physical Chemistry B 2010, 114 (17) , 5795-5809. https://doi.org/10.1021/jp911536z
  48. Youngseon Shim and Hyung J. Kim . Nanoporous Carbon Supercapacitors in an Ionic Liquid: A Computer Simulation Study. ACS Nano 2010, 4 (4) , 2345-2355. https://doi.org/10.1021/nn901916m
  49. Kendall Fruchey and M. D. Fayer. Dynamics in Organic Ionic Liquids in Distinct Regions Using Charged and Uncharged Orientational Relaxation Probes. The Journal of Physical Chemistry B 2010, 114 (8) , 2840-2845. https://doi.org/10.1021/jp911123v
  50. André Pinkert, Kenneth N. Marsh, Shusheng Pang and Mark P. Staiger. Ionic Liquids and Their Interaction with Cellulose. Chemical Reviews 2009, 109 (12) , 6712-6728. https://doi.org/10.1021/cr9001947
  51. Wei Zhao, Frédéric Leroy, Berit Heggen, Stefan Zahn, Barbara Kirchner, Sundaram Balasubramanian and Florian Müller-Plathe . Are There Stable Ion-Pairs in Room-Temperature Ionic Liquids? Molecular Dynamics Simulations of 1-n-Butyl-3-methylimidazolium Hexafluorophosphate. Journal of the American Chemical Society 2009, 131 (43) , 15825-15833. https://doi.org/10.1021/ja906337p
  52. Youngseon Shim and Hyung J. Kim . Adiabatic Electron Transfer in a Room-Temperature Ionic Liquid: Reaction Dynamics and Kinetics. The Journal of Physical Chemistry B 2009, 113 (39) , 12964-12972. https://doi.org/10.1021/jp9065407
  53. Luke D. Simoni, Joan F. Brennecke and Mark A. Stadtherr. Asymmetric Framework for Predicting Liquid−Liquid Equilibrium of Ionic Liquid−Mixed-Solvent Systems. 1. Theory, Phase Stability Analysis, and Parameter Estimation. Industrial & Engineering Chemistry Research 2009, 48 (15) , 7246-7256. https://doi.org/10.1021/ie900461j
  54. Luke D. Simoni, Alexandre Chapeaux, Joan F. Brennecke and Mark A. Stadtherr. Asymmetric Framework for Predicting Liquid−Liquid Equilibrium of Ionic Liquid−Mixed-Solvent Systems. 2. Prediction of Ternary Systems. Industrial & Engineering Chemistry Research 2009, 48 (15) , 7257-7265. https://doi.org/10.1021/ie9004628
  55. Niall J. English and Damian A. Mooney. Very Different Responses to Electromagnetic Fields in Binary Ionic Liquid-Water Solutions. The Journal of Physical Chemistry B 2009, 113 (30) , 10128-10134. https://doi.org/10.1021/jp902500m
  56. Johannes Hunger, Alexander Stoppa and Richard Buchner, Glenn Hefter. Dipole Correlations in the Ionic Liquid 1-N-Ethyl-3-N-methylimidazolium Ethylsulfate and Its Binary Mixtures with Dichloromethane. The Journal of Physical Chemistry B 2009, 113 (28) , 9527-9537. https://doi.org/10.1021/jp9024574
  57. Stanislaw Lamperski, Christopher W. Outhwaite and Lutful B. Bhuiyan . The Electric Double-Layer Differential Capacitance at and near Zero Surface Charge for a Restricted Primitive Model Electrolyte. The Journal of Physical Chemistry B 2009, 113 (26) , 8925-8929. https://doi.org/10.1021/jp900037h
  58. Y. Danten, M. I. Cabaço and M. Besnard. Interaction of Water Highly Diluted in 1-Alkyl-3-methyl Imidazolium Ionic Liquids with the PF6− and BF4− Anions. The Journal of Physical Chemistry A 2009, 113 (12) , 2873-2889. https://doi.org/10.1021/jp8108368
  59. Aniruddha Paul and Anunay Samanta. Free Volume Dependence of the Internal Rotation of a Molecular Rotor Probe in Room Temperature Ionic Liquids. The Journal of Physical Chemistry B 2008, 112 (51) , 16626-16632. https://doi.org/10.1021/jp8060575
  60. Keith E. Gutowski and Edward J. Maginn. Amine-Functionalized Task-Specific Ionic Liquids: A Mechanistic Explanation for the Dramatic Increase in Viscosity upon Complexation with CO2 from Molecular Simulation. Journal of the American Chemical Society 2008, 130 (44) , 14690-14704. https://doi.org/10.1021/ja804654b
  61. Johannes Hunger, Alexander Stoppa and Richard Buchner, Glenn Hefter. From Ionic Liquid to Electrolyte Solution: Dynamics of 1-N-Butyl-3-N-methylimidazolium Tetrafluoroborate/Dichloromethane Mixtures. The Journal of Physical Chemistry B 2008, 112 (41) , 12913-12919. https://doi.org/10.1021/jp8045627
  62. Yasith S. Nanayakkara, Hyejin Moon, Tharanga Payagala, Aruna B. Wijeratne, Jeffrey A. Crank, Pritesh S. Sharma and Daniel W. Armstrong. A Fundamental Study on Electrowetting by Traditional and Multifunctional Ionic Liquids: Possible Use in Electrowetting on Dielectric-Based Microfluidic Applications. Analytical Chemistry 2008, 80 (20) , 7690-7698. https://doi.org/10.1021/ac8009802
  63. Youngseon Shim and Hyung J. Kim. Dielectric Relaxation, Ion Conductivity, Solvent Rotation, and Solvation Dynamics in a Room-Temperature Ionic Liquid. The Journal of Physical Chemistry B 2008, 112 (35) , 11028-11038. https://doi.org/10.1021/jp802595r
  64. Alexander S. Barnes, Emma I. Rogers, Ian Streeter, Leigh Aldous, Christopher Hardacre, Gregory G. Wildgoose and Richard G. Compton. Unusual Voltammetry of the Reduction of O2 in [C4dmim][N(Tf)2] Reveals a Strong Interaction of O2•− with the [C4dmim]+ Cation. The Journal of Physical Chemistry C 2008, 112 (35) , 13709-13715. https://doi.org/10.1021/jp803349z
  65. Wei Huang and Ranko Richert. The Physics of Heating by Time-Dependent Fields: Microwaves and Water Revisited. The Journal of Physical Chemistry B 2008, 112 (32) , 9909-9913. https://doi.org/10.1021/jp8038187
  66. Philippe Hapiot, and Corinne Lagrost, . Electrochemical Reactivity in Room-Temperature Ionic Liquids. Chemical Reviews 2008, 108 (7) , 2238-2264. https://doi.org/10.1021/cr0680686
  67. Kazuhide Ueno, Aya Inaba, Masashi Kondoh and Masayoshi Watanabe . Colloidal Stability of Bare and Polymer-Grafted Silica Nanoparticles in Ionic Liquids. Langmuir 2008, 24 (10) , 5253-5259. https://doi.org/10.1021/la704066v
  68. Ana Maria Blanco-Rodríguez,, Kate L. Ronayne,, Stanislav Záliš,, Jan Sýkora,, Martin Hof, and, Antonín Vlček, Jr.. Solvation-Driven Excited-State Dynamics of [Re(4-Et-Pyridine)(CO)3(2,2‘-bipyridine)]+ in Imidazolium Ionic Liquids. A Time-Resolved Infrared and Phosphorescence Study. The Journal of Physical Chemistry A 2008, 112 (16) , 3506-3514. https://doi.org/10.1021/jp710442v
  69. Alexander Stoppa,, Johannes Hunger, and, Richard Buchner, , Glenn Hefter, , Andreas Thoman and, Hanspeter Helm. Interactions and Dynamics in Ionic Liquids. The Journal of Physical Chemistry B 2008, 112 (16) , 4854-4858. https://doi.org/10.1021/jp800852z
  70. Steven Baldelli. Surface Structure at the Ionic Liquid−Electrified Metal Interface. Accounts of Chemical Research 2008, 41 (3) , 421-431. https://doi.org/10.1021/ar700185h
  71. Peter W. Lohse,, Reinhard Bürsing,, Thomas Lenzer, and, Kawon Oum. Exploring 12‘-Apo-β-carotenoic-12‘-acid as an Ultrafast Polarity Probe for Ionic Liquids. The Journal of Physical Chemistry B 2008, 112 (10) , 3048-3057. https://doi.org/10.1021/jp710766z
  72. Giuseppe Ranieri,, Jason P. Hallett, and, Tom Welton. Nucleophilic Reactions at Cationic Centers in Ionic Liquids and Molecular Solvents. Industrial & Engineering Chemistry Research 2008, 47 (3) , 638-644. https://doi.org/10.1021/ie070632v
  73. Baofu Qiao,, Christian Krekeler,, Robert Berger,, Luigi Delle Site, and, Christian Holm. Effect of Anions on Static Orientational Correlations, Hydrogen Bonds, and Dynamics in Ionic Liquids:  A Simulational Study. The Journal of Physical Chemistry B 2008, 112 (6) , 1743-1751. https://doi.org/10.1021/jp0759067
  74. Aniruddha Paul and, Anunay Samanta. Effect of Nonpolar Solvents on the Solute Rotation and Solvation Dynamics in an Imidazolium Ionic Liquid. The Journal of Physical Chemistry B 2008, 112 (3) , 947-953. https://doi.org/10.1021/jp077536s
  75. Youngseon Shim, Daun Jeong, Swati Manjari, Moo Young Choi and Hyung J. Kim. Solvation, Solute Rotation and Vibration Relaxation, and Electron-Transfer Reactions in Room-Temperature Ionic Liquids. Accounts of Chemical Research 2007, 40 (11) , 1130-1137. https://doi.org/10.1021/ar700061r
  76. Naoki Ito and, Ranko Richert. Solvation Dynamics and Electric Field Relaxation in an Imidazolium-PF6 Ionic Liquid:  from Room Temperature to the Glass Transition. The Journal of Physical Chemistry B 2007, 111 (18) , 5016-5022. https://doi.org/10.1021/jp0640023
  77. Hermann Weingärtner,, Padmanabhan Sasisanker,, Corinne Daguenet,, Paul J. Dyson,, Ingo Krossing,, John M. Slattery, and, Thomas Schubert. The Dielectric Response of Room-Temperature Ionic Liquids:  Effect of Cation Variation. The Journal of Physical Chemistry B 2007, 111 (18) , 4775-4780. https://doi.org/10.1021/jp0671188
  78. Kohji Yamamoto,, Masahiko Tani, and, Masanori Hangyo. Terahertz Time-Domain Spectroscopy of Imidazolium Ionic Liquids. The Journal of Physical Chemistry B 2007, 111 (18) , 4854-4859. https://doi.org/10.1021/jp067171w
  79. Alexei A. Kornyshev. Double-Layer in Ionic Liquids:  Paradigm Change?. The Journal of Physical Chemistry B 2007, 111 (20) , 5545-5557. https://doi.org/10.1021/jp067857o
  80. Aniruddha Paul and, Anunay Samanta. Photoinduced Electron Transfer Reaction in Room Temperature Ionic Liquids:  A Combined Laser Flash Photolysis and Fluorescence Study. The Journal of Physical Chemistry B 2007, 111 (8) , 1957-1962. https://doi.org/10.1021/jp067481e
  81. Jian Wang, Junshuang Wu, Wenqing Wu, Jing Tong. Estimation of the polarity and prediction of the molar surface Gibbs energy for amino acid ionic liquids — [C4Dmim][Gly] and [C4Dmim][Ala]. The Journal of Chemical Thermodynamics 2021, 158 , 106418. https://doi.org/10.1016/j.jct.2021.106418
  82. Zongren Song, Qiang Yan, Meichen Xia, Xiaochen Qi, Zhiheng Zhang, Jie Wei, Dawei Fang, Xiaoxue Ma. Physicochemical properties of N-alkylpyridine trifluoroacetate ionic liquids [C Py][TFA] (n = 2–6). The Journal of Chemical Thermodynamics 2021, 155 , 106366. https://doi.org/10.1016/j.jct.2020.106366
  83. Ashish A. Mishra, Bhalchandra M. Bhanage. Ru-Tethered ( R,R )-TsDPEN with DMAB as an efficient catalytic system for high enantioselective one-pot synthesis of chiral β-aminol via asymmetric transfer hydrogenation. New Journal of Chemistry 2021, 45 (12) , 5357-5362. https://doi.org/10.1039/D0NJ06108E
  84. Qiang Yan, Min Liu, Chuanyou Xiao, Donglu Fu, Jie Wei, Dawei Fang, Jiazhen Yang. Predicting properties of ionic liquid homologue of N-alkylpyridinium acetate. Journal of Molecular Liquids 2021, 324 , 114720. https://doi.org/10.1016/j.molliq.2020.114720
  85. Lu Liu, Yue Zhao, Junshuang Wu, Mei Hong, Yuxia Kong, Jing Tong. A simple study on vaporization enthalpy of taurine anion-based ionic liquid. Journal of Molecular Liquids 2021, 323 , 115007. https://doi.org/10.1016/j.molliq.2020.115007
  86. Kio Kawata, Atsushi Kitada, Naoki Tsuchida, Masayuki Saimura, Takashi Nagata, Masato Katahira, Kazuhiro Fukami, Kuniaki Murase. Proton conduction in hydronium solvate ionic liquids affected by ligand shape. Physical Chemistry Chemical Physics 2021, 23 (1) , 449-456. https://doi.org/10.1039/D0CP05025C
  87. Johannes Ingenmey, Oldamur Hollóczki, Barbara Kirchner. Ion Pairing in Ionic Liquids. 2021,,, 1-14. https://doi.org/10.1007/978-981-10-6739-6_63-1
  88. Chunyi Gu, Li Yin, Shu Li, Bohai Zhang, Xiaohong Liu, Tianying Yan. Differential capacitance of ionic liquid and mixture with organic solvent. Electrochimica Acta 2021, 367 , 137517. https://doi.org/10.1016/j.electacta.2020.137517
  89. Manuel Gamero-Castaño, Albert Cisquella-Serra. Electrosprays of highly conducting liquids: A study of droplet and ion emission based on retarding potential and time-of-flight spectrometry. Physical Review Fluids 2021, 6 (1) https://doi.org/10.1103/PhysRevFluids.6.013701
  90. Johannes Zeman, Svyatoslav Kondrat, Christian Holm. Bulk ionic screening lengths from extremely large-scale molecular dynamics simulations. Chemical Communications 2020, 56 (100) , 15635-15638. https://doi.org/10.1039/D0CC05023G
  91. Qiang Yan, Jie Wei, Jin Liu, Zhiheng Zhang, Dawei Fang. Physicochemical properties of hydrophobic hexafluoroantimonate ionic liquids and applications of the mole surface Gibbs free energy. Ionics 2020, 26 (11) , 5585-5595. https://doi.org/10.1007/s11581-020-03673-8
  92. Nolan M. Uchizono, Adam L. Collins, Anirudh Thuppul, Peter L. Wright, Daniel Q. Eckhardt, John Ziemer, Richard E. Wirz. Emission Modes in Electrospray Thrusters Operating with High Conductivity Ionic Liquids. Aerospace 2020, 7 (10) , 141. https://doi.org/10.3390/aerospace7100141
  93. Duo Zhang, Biao Li, Mei Hong, Yu-Xia Kong, Jing Tong, Wei-Guo Xu. Synthesis and characterization of physicochemical properties of new ether-functionalized amino acid ionic liquids. Journal of Molecular Liquids 2020, 304 , 112718. https://doi.org/10.1016/j.molliq.2020.112718
  94. Ekaterina A. Shelepova, Dietmar Paschek, Ralf Ludwig, Nikolai N. Medvedev. Comparing the void space and long-range structure of an ionic liquid with a neutral mixture of similar sized molecules. Journal of Molecular Liquids 2020, 299 , 112121. https://doi.org/10.1016/j.molliq.2019.112121
  95. Pablo B. Sánchez, Shuntaro Tsubaki, Agílio A. H. Pádua, Yuji Wada. Kinetic analysis of microwave-enhanced cellulose dissolution in ionic solvents. Physical Chemistry Chemical Physics 2020, 22 (3) , 1003-1010. https://doi.org/10.1039/C9CP06239D
  96. Shuhan Wang, Bingqing Ge, Yixuan Yin, Xinru Wu, Haibo Zhu, Yuanyuan Yue, Zhengshuai Bai, Xiaojun Bao, Pei Yuan. Solvent Effect in Heterogeneous Catalytic Selective Hydrogenation of Nitrile Butadiene Rubber: Relationship between Reaction Activity and Solvents with Density Functional Theory Analysis. ChemCatChem 2020, 12 (2) , 663-672. https://doi.org/10.1002/cctc.201901555
  97. Anas R. Al Johani, Saud M. Almutairi, Wael S. El-Sayed, Pramod K. Sahu, Praveen K. Sahu, Mouslim Messali. Design, Sustainable Synthesis, Characterization, Antimicrobial Evaluation and in silico ADMET Prediction of New Functionalized Imidazolium Based Ionic Liquids. Asian Journal of Chemistry 2020, 32 (8) , 1972-1980. https://doi.org/10.14233/ajchem.2020.22747
  98. V.A. Rana, D.K. Barot, H.P. Vankar, T.R. Pandit, J.B. Karakthala. AC/DC conductivity and dielectric relaxation behavior of ionic solutions of 1-butyl-3-methylimidazolium chloride in methanol. Journal of Molecular Liquids 2019, 296 , 111804. https://doi.org/10.1016/j.molliq.2019.111804
  99. Elliot L. Bennett, Chaoyun Song, Yi Huang, Jianliang Xiao. Measured relative complex permittivities for multiple series of ionic liquids. Journal of Molecular Liquids 2019, 294 , 111571. https://doi.org/10.1016/j.molliq.2019.111571
  100. Luca Guglielmero, Lorenzo Guazzelli, Alessandra Toncelli, Cinzia Chiappe, Alessandro Tredicucci, Christian Silvio Pomelli. An insight into the intermolecular vibrational modes of dicationic ionic liquids through far-infrared spectroscopy and DFT calculations. RSC Advances 2019, 9 (52) , 30269-30276. https://doi.org/10.1039/C9RA05735H
Load more citations

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect

This website uses cookies to improve your user experience. By continuing to use the site, you are accepting our use of cookies. Read the ACS privacy policy.

CONTINUE