logo

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Phys. Chem. A 2011, 115, 6, 986-997
RETURN TO ISSUEPREVA: Dynamics, Cluster...A: Dynamics, Clusters, Excited StatesNEXT

Formation of a Hybrid Compound Composed of a Saddle-Distorted Tin(IV)−Porphyrin and a Keggin-Type Heteropolyoxometalate To Undergo Intramolecular Photoinduced Electron Transfer

View Author Information
† Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
‡ Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan
§ X-ray Research Laboratory, Rigaku Corporation, 3-9-12 Matsubara, Akishima-shi, Tokyo 196-68666, Japan
∥ Department of Bioinspired Chemistry, Ewha Womans University, Seoul 120-750, Korea
*E-mail: T.K., [email protected].tsukuba.ac.jp; S.F., [email protected]
Cite this: J. Phys. Chem. A 2011, 115, 6, 986–997
Publication Date (Web):January 26, 2011
https://doi.org/10.1021/jp109863d
Copyright © 2011 American Chemical Society
RIGHTS & PERMISSIONS
Article Views
1211
Altmetric
-
Citations
29
LEARN ABOUT THESE METRICS

Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.

Read OnlinePDF (3 MB)
Get e-Alerts
Supporting Info (3)»
SUBJECTS:

Abstract

Abstract Image

Nonplanar Sn(IV)−porphyrin complexes, [Sn(TMPP(Ph)8)-Cl2] (1) and [Sn(TMPP(Ph)8)(OMe)2] (2) (TMPP(Ph)8: 5,10,15,20-tetrakis(4-methoxyphenyl)-2,3,7,8,12,13,17,18-octaphenylporphyrinato), were prepared and characterized by spectroscopic and electrochemical methods together with X-ray crystallography. Variable-temperature 1H NMR study revealed that the coordination of the methoxo ligand of 2 is weak enough in solution to enhance the axial ligand exchange with a Keggin-type phosphotungstate (α-[PW12O40]3−) due to the steric stress between the axial methoxo ligand and the peripheral phenyl groups of the porphyrin ligand. The formation of a novel 1:1 donor−acceptor complex, [Sn(TMPP(Ph)8)(OMe)(α-[PW12O40])]2− (4) was confirmed by 1H NMR and UV−vis spectral titrations, and also by MALDI-TOF-MS measurements. Electrochemical measurements for the donor−acceptor complex in PhCN revealed that the Sn(IV)−TMPP(Ph)8 moiety acts as an electron donor and the α-[PW12O40]3− moiety acts as an electron acceptor and that the energy level of the electron-transfer (ET) state of the 1:1 complex (1.17 eV) is lower than that of the triplet excited states of the SnTMPP(Ph)8 complex (1.31 eV). Femtosecond and nanosecond laser flash photolysis measurements indicate that intersystem crossing from the singlet excited sate to the triplet excited state occurs followed by intramolecular photoinduced electron transfer from the triplet excited state of the Sn(IV)−TMPP(Ph)8 moiety to the α-[PW12O40]3− moiety in the 1:1 complex in benzonitrile.

Supporting Information

ARTICLE SECTIONS
Jump To

Details of crystallographic analysis, crystallographic data in CIF format, displacements of atoms from the least-squares in porphyrin cores for 1 and 2, MALDI-TOF-MS spectra, femtosecond transient absorption spectra of 1 in PhCN at room temperature. This material is available free of charge via the Internet at http://pubs.acs.org.

Terms & Conditions

Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

Cited By

This article is cited by 29 publications.

  1. Agnese Amati, Paolo Cavigli, Nicola Demitri, Mirco Natali, Maria Teresa Indelli, Elisabetta Iengo. Sn(IV) Multiporphyrin Arrays as Tunable Photoactive Systems. Inorganic Chemistry 2019, 58 (7) , 4399-4411. https://doi.org/10.1021/acs.inorgchem.8b03542
  2. Kenneth P. Ghiggino, Neeraj Kumar Giri, Jordan Hanrieder, Jonathon D. Martell, Jens Müller, Matthew F. Paige, Benjamin Robotham, Jędrzej Szmytkowski, and Ronald P. Steer . Photophysics of Soret-Excited Tin(IV) Porphyrins in Solution. The Journal of Physical Chemistry A 2013, 117 (33) , 7833-7840. https://doi.org/10.1021/jp406025j
  3. Maria Barsukova-Stuckart, Luis F. Piedra-Garza, Bimersha Gautam, Gabriela Alfaro-Espinoza, Natalya V. Izarova, Abhishek Banerjee, Bassem S. Bassil, Matthias S. Ullrich, Hans J. Breunig, Cristian Silvestru, and Ulrich Kortz . Synthesis and Biological Activity of Organoantimony(III)-Containing Heteropolytungstates. Inorganic Chemistry 2012, 51 (21) , 12015-12022. https://doi.org/10.1021/ic301892s
  4. Marie-Pierre Santoni, Amlan K. Pal, Garry S. Hanan, Anna Proust, and Bernold Hasenknopf . Discrete Covalent Organic–Inorganic Hybrids: Terpyridine Functionalized Polyoxometalates Obtained by a Modular Strategy and Their Metal Complexation. Inorganic Chemistry 2011, 50 (14) , 6737-6745. https://doi.org/10.1021/ic200752v
  5. Yusen Luo, Salam Maloul, Stefanie Schönweiz, Maria Wächtler, Carsten Streb, Benjamin Dietzek. Yield—not only Lifetime—of the Photoinduced Charge‐Separated State in Iridium Complex–Polyoxometalate Dyads Impact Their Hydrogen Evolution Reactivity. Chemistry – A European Journal 2020, 26 (36) , 8045-8052. https://doi.org/10.1002/chem.202000982
  6. Pavithra Jayachandran, Abiram Angamuthu, Praveena Gopalan. UV-vis absorption spectra of Sn(IV)tetrakis(4-pyridyl) porphyrins on the basis of axial ligation and pyridine protonation. Journal of Molecular Modeling 2019, 25 (9) https://doi.org/10.1007/s00894-019-4166-5
  7. Zhaohui Huo, Antoine Bonnefont, Yiming Liang, Rana Farha, Michel Goldmann, Eric Saint-Aman, Hualong Xu, Christophe Bucher, Laurent Ruhlmann. Photovoltaic properties of supramolecular assemblies obtained by incorporation of Preysler's type polyoxometalate in a polycationic copolymer of porphyrin. Electrochimica Acta 2018, 274 , 177-191. https://doi.org/10.1016/j.electacta.2018.04.088
  8. Yusen Luo, Maria Wächtler, Kevin Barthelmes, Andreas Winter, Ulrich S. Schubert, Benjamin Dietzek. Direct detection of the photoinduced charge-separated state in a Ru( ii ) bis(terpyridine)–polyoxometalate molecular dyad. Chemical Communications 2018, 54 (24) , 2970-2973. https://doi.org/10.1039/C7CC09181H
  9. Peng Luo, Paul-Ludovic Karsenti, Benoit Marsan, Pierre D. Harvey. Triplet energy vs. electron transfers in porphyrin- and tetrabenzoporphyrin-carboxylates/Pd 3 (dppm) 3 (CO) 2+ cluster assemblies; a question of negative charge. New Journal of Chemistry 2018, 42 (10) , 8160-8168. https://doi.org/10.1039/C7NJ03943C
  10. Yusen Luo, Maria Wächtler, Kevin Barthelmes, Andreas Winter, Ulrich S. Schubert, Benjamin Dietzek. Coexistence of distinct intramolecular electron transfer pathways in polyoxometalate based molecular triads. Physical Chemistry Chemical Physics 2018, 20 (17) , 11740-11748. https://doi.org/10.1039/C8CP01007B
  11. Yoshinao Shinozaki, Yuta Mizumura, Yuki Kida, Kosuke Sugawa, Kaori Wada, Sachiko Kishiro, Joe Otsuki. Crystal Structures and Side-arm Dynamics of Cerium meso -Tetrathienylporphyrin Double-decker Complexes. Chemistry Letters 2016, 45 (9) , 1123-1125. https://doi.org/10.1246/cl.160549
  12. Rahmatollah Rahimi, Marzieh Yaghoubi-Berijani, Solmaz Zargari, Mahboubeh Rabbani, Samaneh Shariatinia. SnTCPP-modified ZnO nanorods prepared via a simple co-precipitation method: application as a new photocatalyst for photodegradation and photoreduction processes. Research on Chemical Intermediates 2016, 42 (5) , 4697-4714. https://doi.org/10.1007/s11164-015-2309-6
  13. Solmaz Zargari, Rahmatollah Rahimi, Ali Ghaffarinejad, Ali Morsali. Enhanced visible light photocurrent response and photodegradation efficiency over TiO2–graphene nanocomposite pillared with tin porphyrin. Journal of Colloid and Interface Science 2016, 466 , 310-321. https://doi.org/10.1016/j.jcis.2015.12.046
  14. James J. Walsh, Alan M. Bond, Robert J. Forster, Tia E. Keyes. Hybrid polyoxometalate materials for photo(electro-) chemical applications. Coordination Chemistry Reviews 2016, 306 , 217-234. https://doi.org/10.1016/j.ccr.2015.06.016
  15. S. Zargari, R. Rahimi, A. Yousefi. An efficient visible light photocatalyst based on tin porphyrin intercalated between TiO 2 –graphene nanosheets for inactivation of E. coli and investigation of charge transfer mechanism. RSC Advances 2016, 6 (29) , 24218-24228. https://doi.org/10.1039/C5RA19927A
  16. Peng Yang, Bassem S. Bassil, Zhengguo Lin, Ali Haider, Gabriela Alfaro-Espinoza, Matthias S. Ullrich, Cristian Silvestru, Ulrich Kortz. Organoantimony(III)-Containing Tungstoarsenates(III): From Controlled Assembly to Biological Activity. Chemistry - A European Journal 2015, 21 (44) , 15600-15606. https://doi.org/10.1002/chem.201502398
  17. Zhaohui Huo, Dejin Zang, Shu Yang, Rana Farha, Michel Goldmann, Bernold Hasenknopf, Hualong Xu, Laurent Ruhlmann. Synthesis and characterization of Lindqvist-type polyoxometalate–porphyrin copolymers. Electrochimica Acta 2015, 179 , 326-335. https://doi.org/10.1016/j.electacta.2015.03.178
  18. Changhong Li, Ki-Min Park, Hee-Joon Kim. Ionic assembled hybrid nanoparticle consisting of tin(IV) porphyrin cations and polyoxomolybdate anions, and photocatalytic hydrogen production by its visible light sensitization. Inorganic Chemistry Communications 2015, 60 , 8-11. https://doi.org/10.1016/j.inoche.2015.07.016
  19. Zhaohui Huo, Iban Azcarate, Rana Farha, Michel Goldmann, Hualong Xu, Bernold Hasenknopf, Emmanuel Lacôte, Laurent Ruhlmann. Copolymeric films obtained by electropolymerization of porphyrins and dipyridyl-spacers including Dawson-type polyoxometalates. Journal of Solid State Electrochemistry 2015, 19 (9) , 2611-2621. https://doi.org/10.1007/s10008-015-2828-5
  20. Kenji Ohashi, Hiroyuki Takeda, Kazuhide Koike, Osamu Ishitani. Synthesis and strong photooxidation power of a supramolecular hybrid comprising a polyoxometalate and Ru( ii ) polypyridyl complex with zinc( ii ). Faraday Discussions 2015, 185 , 171-185. https://doi.org/10.1039/C5FD00080G
  21. Tomoya Ishizuka, Shunichi Fukuzumi, Takahiko Kojima. Molecular assemblies based on strong axial coordination in metal complexes of saddle-distorted dodecaphenylporphyrins. Journal of Porphyrins and Phthalocyanines 2015, 19 (01-03) , 32-44. https://doi.org/10.1142/S1088424615500273
  22. Marie-Pierre Santoni, Garry S. Hanan, Bernold Hasenknopf. Covalent multi-component systems of polyoxometalates and metal complexes: Toward multi-functional organic–inorganic hybrids in molecular and material sciences. Coordination Chemistry Reviews 2014, 281 , 64-85. https://doi.org/10.1016/j.ccr.2014.09.003
  23. Ya-hong Wu, Lin Chen, Jian Yu, Shan-ling Tong, Yan Yan. Synthesis and spectroscopic characterization of meso-tetra (Schiff-base substituted phenyl) porphyrins and their zinc complexes. Dyes and Pigments 2013, 97 (3) , 423-428. https://doi.org/10.1016/j.dyepig.2012.12.032
  24. Clémence Allain, Delphine Schaming, Nikolaos Karakostas, Marie Erard, Jean-Paul Gisselbrecht, Sébastien Sorgues, Isabelle Lampre, Laurent Ruhlmann, Bernold Hasenknopf. Synthesis, electrochemical and photophysical properties of covalently linked porphyrin–polyoxometalates. Dalton Trans. 2013, 42 (8) , 2745-2754. https://doi.org/10.1039/C2DT31415K
  25. Dongdi Zhang, Juan Zhao, Yanhui Zhang, Xiaojing Hu, Longsheng Li, Pengtao Ma, Jingping Wang, Jingyang Niu. Octamolybdate-supported tricarbonyl metal derivatives: [{H2Mo8O30}{M(CO)3}2]8− (M = MnI and ReI). Dalton Transactions 2013, 42 (8) , 2696. https://doi.org/10.1039/c2dt32678g
  26. Iban Azcarate, Iftikhar Ahmed, Rana Farha, Michel Goldmann, Xiaoxia Wang, Hualong Xu, Bernold Hasenknopf, Emmanuel Lacôte, Laurent Ruhlmann. Synthesis and characterization of conjugated Dawson-type polyoxometalate–porphyrin copolymers. Dalton Transactions 2013, 42 (35) , 12688. https://doi.org/10.1039/c3dt50850a
  27. Tomoya Ishizuka, Muniappan Sankar, Takahiko Kojima. Control of the spatial arrangements of supramolecular networks based on saddle-distorted porphyrins by intermolecular hydrogen bonding. Dalton Transactions 2013, 42 (45) , 16073. https://doi.org/10.1039/c3dt51467f
  28. Luis Fernando Piedra-Garza, Maria Barsukova-Stuckart, Bassem S. Bassil, Rami Al-Oweini, Ulrich Kortz. Diethyltin-Containing Tungstoarsenate(V), [{Sn(C2H5)2}3(H2O)6(A–α–AsVW9O34)]3−. Journal of Cluster Science 2012, 23 (3) , 939-951. https://doi.org/10.1007/s10876-012-0501-z
  29. Hongjin Lv, Yurii V. Geletii, Chongchao Zhao, James W. Vickers, Guibo Zhu, Zhen Luo, Jie Song, Tianquan Lian, Djamaladdin G. Musaev, Craig L. Hill. Polyoxometalate water oxidation catalysts and the production of green fuel. Chemical Society Reviews 2012, 41 (22) , 7572. https://doi.org/10.1039/c2cs35292c

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

OOPS

You have to login with your ACS ID befor you can login with your Mendeley account.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect

This website uses cookies to improve your user experience. By continuing to use the site, you are accepting our use of cookies. Read the ACS privacy policy.

CONTINUE