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Preparation of Calcium Oxalate by Vesicle Modification in the Catanionic Surfactant System CDS/TTABr/H2O

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    Preparation of Calcium Oxalate by Vesicle Modification in the Catanionic Surfactant System CDS/TTABr/H2O
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    Key Laboratory of Colloid and Interface Chemistry of Ministry of Education, Shandong University, Jinan 250100, P. R. China
    * To whom correspondence should be addressed. E-mail: [email protected]. Fax: +86-531-88366074.
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    The Journal of Physical Chemistry B

    Cite this: J. Phys. Chem. B 2010, 114, 6, 2131–2139
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    https://doi.org/10.1021/jp908736d
    Published January 22, 2010
    Copyright © 2010 American Chemical Society
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    Abstract

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    In conventional cationic−anionic (catanionic) surfactant mixtures with excess monovalent salt, two lamellar phase (Lα) regions are usually observed in both the cation-rich and anion-rich solutions, and precipitates form when there is an equal molar ratio of the cationic and anionic surfactants. The phase- and temperature-dependent behavior of the calcium dodecyl sulfate (CDS)−tetradecyltrimethylammonium bromide (TTABr)−water system with excess CaBr2 is reported. A birefringent Lα-phase is observed in the cation-rich solution while the precipitates in both the anion-rich and the cation-rich regions. The introduction of the Ca2+ ion is proposed to alter the electrostatic shielding of the surfactant headgroups. Stable vesicles were characterized by TEM and rheology. The formation of the vesicles is driven by electrostatic and hydrophobic interactions between the cationic and anionic surfactants. The results from TEM show that the temperature markedly influences the molecular interactions and changes the structure of molecular bilayers, leading to the instability of the vesicles. The vesicles were used to prepare microcrystals of calcium oxalate monohydrate (CaC2O4·H2O) by adding dimethyl oxalate to Lα solution. X-ray diffraction and scanning electron microscopy indicate that the vesicle phases play an important role in affecting the formation and growth of the CaC2O4 crystals. Namely, the microcrystals formed in the reaction are mainly bricklike (dodecahedrons) and starlike (icositetrahedrons). The two morphologies have not been previously observed in COM. Furthermore, they are larger than those prepared without surfactant, which may also explain a role for surfactants in calcium oxalate biomineralization.

    Copyright © 2010 American Chemical Society

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    Supporting Information

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    The identification of calcium dodecyl sulfate (CDS) is given, including FT-IR (Figure S1) and 1H NMR (Figure S2) spectra of CDS, and polarizers of birefringent Lα-phase solution. This material is available free of charge via the Internet at http://pubs.acs.org.

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    The Journal of Physical Chemistry B

    Cite this: J. Phys. Chem. B 2010, 114, 6, 2131–2139
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jp908736d
    Published January 22, 2010
    Copyright © 2010 American Chemical Society
    Request reuse permissions

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