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Adsorption of Aldehydes on a Graphite Substrate: Combined Thermodynamic Study of C6−C13 Homologues with a Structural and Dynamical Study of Dodecanal

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BP Institute and Department of Chemistry, University of Cambridge, Madingley Rise, Madingley Road, Cambridge CB3 0HE, United Kingdom
Division of Molecular and Nanomaterials and INPAC-Institute for Nanoscale Physics and Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200 F, B-3001 Heverlee, Belgium
* To whom correspondence should be addressed. E-mail: [email protected]
Cite this: J. Phys. Chem. C 2010, 114, 13, 6027–6034
Publication Date (Web):March 4, 2010
https://doi.org/10.1021/jp911069t
Copyright © 2010 American Chemical Society
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    Abstract

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    In this work we present a study on the adsorption of linear alkyl aldehydes physisorbed from their bulk liquid onto a graphite substrate combining calorimetry for all homologues from C6 to C13, with more detailed diffraction, incoherent neutron scattering, and scanning tunneling microscopy techniques for one (C12) representative member. We identify solid monolayer formation for some of these species for alkyl chain lengths of 6 to 13 carbons at high surface coverages. The C12 monolayer structure is determined to be most likely Pgg and this structure is discussed in terms of the importance of dipolar interactions.

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