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    Organometal Perovskite Light Absorbers Toward a 20% Efficiency Low-Cost Solid-State Mesoscopic Solar Cell
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    School of Chemical Engineering and Department of Energy Science, Sungkyunkwan University, Suwon 440-746, Republic of Korea
    *E-mail: [email protected]. Tel: 82-31-290-7241. Fax: 82-31-290-7272
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    Cite this: J. Phys. Chem. Lett. 2013, 4, 15, 2423–2429
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    https://doi.org/10.1021/jz400892a
    Published July 11, 2013
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    Recently, perovskite CH3NH3PbI3 sensitizer has attracted great attention due to its superb light-harvesting characteristics. Organometallic or organic materials were mostly used as sensitizers for solid-state dye-sensitized solar cells at early stages. Inorganic nanocrystals have lately received attention as light harvesters due to their high light-absorbing properties. Metal chalcogenides have been investigated with solid-state dye-sensitized solar cells; however, the best power conversion efficiency was reported to be around 6%. CH3NH3PbX3 (X = Cl, Br, or I) perovskite sensitizer made a breakthrough in solid-state mescoscopic solar cells, where the first record efficiency of around 10% was reported in 2012 using submicrometer-thick TiO2 film sensitized with CH3NH3PbI3. A rapid increase in efficiency approaching 14% followed shortly. In this Perspective, recent progress in perovskite-sensitized solid-state mesoscopic solar cells is reviewed. On the basis of the recent achievements, a power conversion efficiency as high as 20% is expected based on optimized perovskite-based solid-state solar cells.

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    69. Chun-Ho Lin, Bin Cheng, Ting-You Li, José Ramón Durán Retamal, Tzu-Chiao Wei, Hui-Chun Fu, Xiaosheng Fang, Jr-Hau He. Orthogonal Lithography for Halide Perovskite Optoelectronic Nanodevices. ACS Nano 2019, 13 (2) , 1168-1176. https://doi.org/10.1021/acsnano.8b05859
    70. Ying Zhang, Haiou Zhu, Jilin Zheng, Guangyue Chai, Zongpeng Song, Yanping Chen, Yuanhai Liu, Siyu He, Yongqiang Shi, Yumin Tang, Meng Wang, Wenwen Liu, Lingfeng Jiang, Shuangchen Ruan. Performance Enhancement of All-Inorganic Perovskite Quantum Dots (CsPbX3) by UV-NIR Laser Irradiation. The Journal of Physical Chemistry C 2019, 123 (7) , 4502-4511. https://doi.org/10.1021/acs.jpcc.8b11353
    71. Karen Valadez-Villalobos, Jesús Idígoras, Lilian P. Delgado, David Meneses-Rodríguez, Juan A. Anta, Gerko Oskam. Correlation between the Effectiveness of the Electron-Selective Contact and Photovoltaic Performance of Perovskite Solar Cells. The Journal of Physical Chemistry Letters 2019, 10 (4) , 877-882. https://doi.org/10.1021/acs.jpclett.8b03834
    72. Han Liu, Xiangfeng Wei, Zhixiang Zhang, Xunyong Lei, Wenchao Xu, Linbao Luo, Hualing Zeng, Ruifeng Lu, Jiehua Liu. Microconcave MAPbBr3 Single Crystal for High-Performance Photodetector. The Journal of Physical Chemistry Letters 2019, 10 (4) , 786-792. https://doi.org/10.1021/acs.jpclett.9b00038
    73. Qiuyang Li, Tianquan Lian. Ultrafast Charge Separation in Two-Dimensional CsPbBr3 Perovskite Nanoplatelets. The Journal of Physical Chemistry Letters 2019, 10 (3) , 566-573. https://doi.org/10.1021/acs.jpclett.8b03610
    74. Kai Liu, Yingying Jiang, Yaqian Jiang, Yunlong Guo, Yunqi Liu, Eiichi Nakamura. Chemical Formation and Multiple Applications of Organic–Inorganic Hybrid Perovskite Materials. Journal of the American Chemical Society 2019, 141 (4) , 1406-1414. https://doi.org/10.1021/jacs.8b09532
    75. Lingling Mao, Constantinos C. Stoumpos, Mercouri G. Kanatzidis. Two-Dimensional Hybrid Halide Perovskites: Principles and Promises. Journal of the American Chemical Society 2019, 141 (3) , 1171-1190. https://doi.org/10.1021/jacs.8b10851
    76. Jinlu He, Run Long. Lead Vacancy Can Explain the Suppressed Nonradiative Electron–Hole Recombination in FAPbI3 Perovskite under Iodine-Rich Conditions: A Time-Domain Ab Initio Study. The Journal of Physical Chemistry Letters 2018, 9 (22) , 6489-6495. https://doi.org/10.1021/acs.jpclett.8b03095
    77. Biplab Ghosh, Bo Wu, Hemant Kumar Mulmudi, Claude Guet, Klaus Weber, Tze Chien Sum, Subodh Mhaisalkar, Nripan Mathews. Limitations of Cs3Bi2I9 as Lead-Free Photovoltaic Absorber Materials. ACS Applied Materials & Interfaces 2018, 10 (41) , 35000-35007. https://doi.org/10.1021/acsami.7b14735
    78. Jinlu He, Wei-Hai Fang, Run Long, Oleg V. Prezhdo. Increased Lattice Stiffness Suppresses Nonradiative Charge Recombination in MAPbI3 Doped with Larger Cations: Time-Domain Ab Initio Analysis. ACS Energy Letters 2018, 3 (9) , 2070-2076. https://doi.org/10.1021/acsenergylett.8b01191
    79. Vladimir S. Chirvony, Juan P. Martínez-Pastor. Trap-Limited Dynamics of Excited Carriers and Interpretation of the Photoluminescence Decay Kinetics in Metal Halide Perovskites. The Journal of Physical Chemistry Letters 2018, 9 (17) , 4955-4962. https://doi.org/10.1021/acs.jpclett.8b01241
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    81. Jing Ma, Xing Guo, Long Zhou, Zhenhua Lin, Chunfu Zhang, Zhou Yang, Gang Lu, Jingjing Chang, Yue Hao. Enhanced Planar Perovskite Solar Cell Performance via Contact Passivation of TiO2/Perovskite Interface with NaCl Doping Approach. ACS Applied Energy Materials 2018, 1 (8) , 3826-3834. https://doi.org/10.1021/acsaem.8b00602
    82. Zhe Xu, Jihuai Wu, Yuqian Yang, Zhang Lan, Jianming Lin. High-Efficiency Planar Hybrid Perovskite Solar Cells Using Indium Sulfide as Electron Transport Layer. ACS Applied Energy Materials 2018, 1 (8) , 4050-4056. https://doi.org/10.1021/acsaem.8b00726
    83. Nam-Gyu Park, Hiroshi Segawa. Research Direction toward Theoretical Efficiency in Perovskite Solar Cells. ACS Photonics 2018, 5 (8) , 2970-2977. https://doi.org/10.1021/acsphotonics.8b00124
    84. Chuan-Jia Tong, Linqiu Li, Li-Min Liu, Oleg V. Prezhdo. Long Carrier Lifetimes in PbI2-Rich Perovskites Rationalized by Ab Initio Nonadiabatic Molecular Dynamics. ACS Energy Letters 2018, 3 (8) , 1868-1874. https://doi.org/10.1021/acsenergylett.8b00961
    85. Ludmila Cojocaru, Karl Wienands, Tae Woong Kim, Satoshi Uchida, Alexander J. Bett, Saeid Rafizadeh, Jan Christoph Goldschmidt, Stefan W. Glunz. Detailed Investigation of Evaporated Perovskite Absorbers with High Crystal Quality on Different Substrates. ACS Applied Materials & Interfaces 2018, 10 (31) , 26293-26302. https://doi.org/10.1021/acsami.8b07999
    86. Francesco Cordero, Floriana Craciun, Francesco Trequattrini, Patrizia Imperatori, Anna Maria Paoletti, Giovanna Pennesi. Competition between Polar and Antiferrodistortive Modes and Correlated Dynamics of the Methylammonium Molecules in MAPbI3 from Anelastic and Dielectric Measurements. The Journal of Physical Chemistry Letters 2018, 9 (15) , 4401-4406. https://doi.org/10.1021/acs.jpclett.8b01761
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    88. Puru Jena, Qiang Sun. Super Atomic Clusters: Design Rules and Potential for Building Blocks of Materials. Chemical Reviews 2018, 118 (11) , 5755-5870. https://doi.org/10.1021/acs.chemrev.7b00524
    89. Philip Schulz. Interface Design for Metal Halide Perovskite Solar Cells. ACS Energy Letters 2018, 3 (6) , 1287-1293. https://doi.org/10.1021/acsenergylett.8b00404
    90. Minghua Li, Xiaoqin Yan, Zhuo Kang, Yahuan Huan, Yong Li, Ruxiao Zhang, Yue Zhang. Hydrophobic Polystyrene Passivation Layer for Simultaneously Improved Efficiency and Stability in Perovskite Solar Cells. ACS Applied Materials & Interfaces 2018, 10 (22) , 18787-18795. https://doi.org/10.1021/acsami.8b04776
    91. Chintam Hanmandlu, Chi-Ching Liu, Chien-Yu Chen, Karunakara Moorthy Boopathi, Shang-Hsuan Wu, Mriganka Singh, Anisha Mohapatra, Hao-Wu Lin, Yia-Chung Chang, Yun-Chorng Chang, Chao-Sung Lai, Chih-Wei Chu. Top Illuminated Hysteresis-Free Perovskite Solar Cells Incorporating Microcavity Structures on Metal Electrodes: A Combined Experimental and Theoretical Approach. ACS Applied Materials & Interfaces 2018, 10 (21) , 17973-17984. https://doi.org/10.1021/acsami.8b04329
    92. Yaoguang Rong, Yue Ming, Wenxian Ji, Da Li, Anyi Mei, Yue Hu, Hongwei Han. Toward Industrial-Scale Production of Perovskite Solar Cells: Screen Printing, Slot-Die Coating, and Emerging Techniques. The Journal of Physical Chemistry Letters 2018, 9 (10) , 2707-2713. https://doi.org/10.1021/acs.jpclett.8b00912
    93. Wenna Du, Shuai Zhang, Jia Shi, Jie Chen, Zhiyong Wu, Yang Mi, Zhixiong Liu, Yuanzheng Li, Xinyu Sui, Rui Wang, Xiaohui Qiu, Tom Wu, Yunfeng Xiao, Qing Zhang, Xinfeng Liu. Strong Exciton–Photon Coupling and Lasing Behavior in All-Inorganic CsPbBr3 Micro/Nanowire Fabry-Pérot Cavity. ACS Photonics 2018, 5 (5) , 2051-2059. https://doi.org/10.1021/acsphotonics.7b01593
    94. Jianming Yang, Zhongcheng Yuan, Xianjie Liu, Slawomir Braun, Yanqing Li, Jianxin Tang, Feng Gao, Chungang Duan, Mats Fahlman, Qinye Bao. Oxygen- and Water-Induced Energetics Degradation in Organometal Halide Perovskites. ACS Applied Materials & Interfaces 2018, 10 (18) , 16225-16230. https://doi.org/10.1021/acsami.8b04182
    95. SeongSik Nam, Cuc Thi Kim Mai, Ilwhan Oh. Ultrastable Photoelectrodes for Solar Water Splitting Based on Organic Metal Halide Perovskite Fabricated by Lift-Off Process. ACS Applied Materials & Interfaces 2018, 10 (17) , 14659-14664. https://doi.org/10.1021/acsami.8b00686
    96. Zhaosheng Zhang, Wei-Hai Fang, Marina V. Tokina, Run Long, Oleg V. Prezhdo. Rapid Decoherence Suppresses Charge Recombination in Multi-Layer 2D Halide Perovskites: Time-Domain Ab Initio Analysis. Nano Letters 2018, 18 (4) , 2459-2466. https://doi.org/10.1021/acs.nanolett.8b00035
    97. Qinjun Sun, Shaolong Zhou, Xiaolei Shi, Xiaochun Wang, Liyan Gao, Zhanfeng Li, Yuying Hao. Efficiency Enhancement of Perovskite Solar Cells via Electrospun CuO Nanowires as Buffer Layers. ACS Applied Materials & Interfaces 2018, 10 (13) , 11289-11296. https://doi.org/10.1021/acsami.7b19335
    98. Jayanta Dana, Partha Maity, Biswajit Jana, Sourav Maiti, Hirendra N. Ghosh. Concurrent Ultrafast Electron- and Hole-Transfer Dynamics in CsPbBr3 Perovskite and Quantum Dots. ACS Omega 2018, 3 (3) , 2706-2714. https://doi.org/10.1021/acsomega.8b00276
    99. Satyawan Nagane, Dibyajyoti Ghosh, Robert L. Z. Hoye, Baodan Zhao, Shahab Ahmad, Alison B. Walker, M. Saiful Islam, Satishchandra Ogale, Aditya Sadhanala. Lead-Free Perovskite Semiconductors Based on Germanium–Tin Solid Solutions: Structural and Optoelectronic Properties. The Journal of Physical Chemistry C 2018, 122 (11) , 5940-5947. https://doi.org/10.1021/acs.jpcc.8b00480
    100. Lin Xie, An-Na Cho, Nam-Gyu Park, Kyungkon Kim. Efficient and Reproducible CH3NH3PbI3 Perovskite Layer Prepared Using a Binary Solvent Containing a Cyclic Urea Additive. ACS Applied Materials & Interfaces 2018, 10 (11) , 9390-9397. https://doi.org/10.1021/acsami.7b18761
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    Cite this: J. Phys. Chem. Lett. 2013, 4, 15, 2423–2429
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