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Structured and Gradient Polymer Brushes from Biphenylthiol Self-Assembled Monolayers by Self-Initiated Photografting and Photopolymerization (SIPGP)

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    Structured and Gradient Polymer Brushes from Biphenylthiol Self-Assembled Monolayers by Self-Initiated Photografting and Photopolymerization (SIPGP)
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    Wacker-Lehrstuhl für Makromolekulare Chemie, Technische Universität München, Lichtenbergstraβe 4, 85747 Garching, Germany, and Lehrstuhl für Angewandte Physikalische Chemie, Universität Heidelberg, Im Neuenheimer Feld 253, 69120 Heidelberg, Germany
    * To whom correspondence should be addressed. Fax: +49-89 289 13562 (R.J.); +49-6221 54 6199 (M.G.). E-mail: [email protected] (R.J.); [email protected] (M.G.).
    †Technische Universität München.
    ‡Universität Heidelberg.
    §Current address: Professur für Makromolekulare Chemie, Department Chemie, Technische Universität Dresden, 01062 Dresden, Germany.
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    Cite this: Langmuir 2009, 25, 4, 2225–2231
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    https://doi.org/10.1021/la803386c
    Published January 13, 2009
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    The self-initiated photografting and photopolymerization (SIPGP) of styrene, methyl methacrylate, and tert-butyl methacrylate on structured self-assembled monolayers (SAMs) of electron beam cross-linked ω-functionalized biphenylthiols SAMs on gold was investigated. Polymer brushes with defined thickness can be prepared on cross-linked benzyl-, phenyl-, hydroxyl-, and amino-functionalized SAMs, whereas non-cross-linked SAM regions desorb from the surface during the SIPGP process. By the preparation of brush gradients on different functionalized SAMs, it was demonstrated that the resulting polymer brush layer thickness is determined by the locally applied electron beam dosage. Defined micro-nanostructured polymer brush patterns can be prepared down to a size of 50 nm. Finally, it was shown that polymer brushes obtained by the SIPGP process have a branched architecture.

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    Cite this: Langmuir 2009, 25, 4, 2225–2231
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