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Reconsideration of deuterium NMR observations of orientational coupling in polymer networks in light of motional heterogeneity in styrene-d8-styrene block copolymers

Cite this: Macromolecules 1992, 25, 17, 4442–4444
Publication Date (Print):August 1, 1992
https://doi.org/10.1021/ma00043a031
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    This article is cited by 21 publications.

    1. Fabián Vaca Chávez and Kay Saalwächter . Time-Domain NMR Observation of Entangled Polymer Dynamics: Universal Behavior of Flexible Homopolymers and Applicability of the Tube Model. Macromolecules 2011, 44 (6) , 1549-1559. https://doi.org/10.1021/ma1025708
    2. Geoffrey D. Genesky, T. M. Duncan and Claude Cohen. Effect of Precursor Molar Mass on the 2H NMR Line Shapes of End-Linked PDMS Elastomers. Macromolecules 2009, 42 (22) , 8882-8888. https://doi.org/10.1021/ma901712s
    3. Bernardo M. Aguilera-Mercado, Claude Cohen and Fernando A. Escobedo. Extraction of Segment Orientation Distributions in Polymer Networks by Inversion of 2H NMR Spectra through the Maximum-Entropy Method. Macromolecules 2009, 42 (22) , 8889-8898. https://doi.org/10.1021/ma9017179
    4. C. W. Yong and, P. G. Higgs. Chain Orientation in Polymer Networks:  Computer Simulations Using the Bond Fluctuation Model. Macromolecules 1999, 32 (15) , 5062-5071. https://doi.org/10.1021/ma981691a
    5. Toshikazu Miyoshi,, K. Takegoshi, and, Takehiko Terao. 13C High-Pressure CPMAS NMR Characterization of the Molecular Motion of Polystyrene Plasticized by CO2 Gas. Macromolecules 1997, 30 (21) , 6582-6585. https://doi.org/10.1021/ma961891r
    6. Kimberly McLoughlin,, J. K. Waldbieser,, Claude Cohen, and, T. M. Duncan. End-Linked Poly(dimethylsiloxane) Elastomers:  2H-Nuclear Magnetic Resonance Investigations of Compression-Induced Segment Anisotropy. Macromolecules 1997, 30 (4) , 1044-1052. https://doi.org/10.1021/ma961005c
    7. Kimberly McLoughlin,, Carol Szeto,, T. M. Duncan, and, Claude Cohen. End-Linked Poly(dimethylsiloxane) Elastomer Structure:  2H-NMR Transverse Dephasing Data Compared to Predictions of Statistical and Thermodynamic Models. Macromolecules 1996, 29 (16) , 5475-5483. https://doi.org/10.1021/ma9600320
    8. E. M. Pestryaev. Chain Heterogeneity in Simulated Polymer Melts: Segment Orientational Autocorrelation Function. Polymer Science, Series A 2020, 62 (6) , 766-778. https://doi.org/10.1134/S0965545X20060085
    9. E. M. Pestryaev. Chain Heterogeneity in Simulated Polymer Melts: NMR Free Induction Decay and Absorption Line. Polymer Science, Series A 2020, 62 (6) , 779-792. https://doi.org/10.1134/S0965545X20060097
    10. E. M. Pestryaev. Signature of Reptation in the Long-Time Behavior of the Simulated Free Induction Decay in High Molecular Mass Polymer Melt. Polymer Science, Series A 2019, 61 (3) , 392-396. https://doi.org/10.1134/S0965545X19030118
    11. E. M. Pestryaev. Oscillating Free Induction Decay in Polymer Systems: Theoretical Analysis. Polymer Science, Series A 2018, 60 (4) , 530-551. https://doi.org/10.1134/S0965545X18040090
    12. Е.М. Пестряев. ОСЦИЛЛИРУЮЩИЙ СПАД СВОБОДНОЙ ИНДУКЦИИ В ПОЛИМЕРНЫХ СИСТЕМАХ: ТЕОРЕТИЧЕСКИЙ АНАЛИЗ, "Высокомолекулярные соединения. Серия А". Высокомолекулярные соединения А 2018, (4) , 329-354. https://doi.org/10.7868/S2308112018040090
    13. Yohei Miwa, Osamu Urakawa, Shogo Nobukawa, Shoichi Kutsumizu. Selective determination of glass transition temperature and vibrational properties at the chain end of polystyrene by Fourier transform infrared measurement in combination with deuterium-labeling. Polymer 2015, 59 , 194-199. https://doi.org/10.1016/j.polymer.2015.01.021
    14. Kay Saalwächter, Berta Herrero, Miguel Angel López-Manchado. Chain Order and Cross-Link Density of Elastomers As Investigated by Proton Multiple-Quantum NMR. Macromolecules 2005, 38 (23) , 9650-9660. https://doi.org/10.1021/ma051238g
    15. Ronald C. Hedden, Evan McCaskey, Claude Cohen, T. M. Duncan. Effects of Molecular Structure on Segment Orientation in Siloxane Elastomers. 1. NMR Measurements from Compressed Samples. Macromolecules 2001, 34 (10) , 3285-3293. https://doi.org/10.1021/ma0017541
    16. H. Menge, S. Hotopf, U. Heuert, H. Schneider. Investigation of partially deuterated poly(butadiene) elastomers. Part 1. 1H and 2H nmr transverse relaxation data. Polymer 2000, 41 (8) , 3019-3027. https://doi.org/10.1016/S0032-3861(99)00457-7
    17. M. Topić, S. Valić, Y. Gallot. Relaxations in lamellar polystyrene–polybutadiene diblock copolymer. Thermally stimulated depolarization current study. Thermochimica Acta 1998, 316 (2) , 177-183. https://doi.org/10.1016/S0040-6031(98)00362-1
    18. P. Sotta. Local Order and Induced Orientation in PDMS Model Networks, Studied by 2 H NMR. Macromolecules 1998, 31 (12) , 3872-3879. https://doi.org/10.1021/ma970994m
    19. Kenneth A. Mauritz. Morphological theories. 1997, 95-157. https://doi.org/10.1007/978-94-009-1461-2_3
    20. Marly M. Jacobi, Volker Abetz, Reimund Stadler, Wolfram Gronski. Direct comparison of the segmental orientations of free oligomer and network chains in polybutadiene model networks. Polymer 1996, 37 (9) , 1669-1675. https://doi.org/10.1016/0032-3861(96)83717-7
    21. Bertrand Deloche. Chain segment ordering in uniaxially strained networks: A deuterium NMR investigation. Makromolekulare Chemie. Macromolecular Symposia 1993, 72 (1) , 29-45. https://doi.org/10.1002/masy.19930720105

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