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Synthesis and Property of Semicrystalline Anion Exchange Membrane with Well-Defined Ion Channel Structure

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Download Hi-Res ImageDownload to MS-PowerPointCite This:Macromolecules 2015, 48, 8, 2576-2584
    Article

    Synthesis and Property of Semicrystalline Anion Exchange Membrane with Well-Defined Ion Channel Structure
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    † Chemical Resources Laboratory, Tokyo Institute of Technology, 4259, Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
    ‡ Core Research for Evolutionary Science and Technology, Japan Science and Technology Agency (JST-CREST), Tokyo 102-0076, Japan
    *E-mail: [email protected] (T.Y.).
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    Macromolecules

    Cite this: Macromolecules 2015, 48, 8, 2576–2584
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    https://doi.org/10.1021/ma502448g
    Published April 15, 2015
    Copyright © 2015 American Chemical Society
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    Abstract

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    A new poly(3,4′-alkylbithiophene)-based anion exchange membrane was designed and synthesized. A well-defined crystalline bilayer lamellae structure with ion channel was constructed by self-organization of the polymer and maintained even in a hydrated state because of the semicrystalline nature of the materials. As a result, swelling of the membrane was effectively suppressed, and higher anion conductivity was obtained compared with a control polymer without ion channel. The synthesized polymer is a promising model system for further understanding of the relationship between solid-state structures and anion-conducting membrane properties.

    Copyright © 2015 American Chemical Society

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    Supporting Information

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    Synthesis, 1H NMR spectra, GPC chart, WAXRD, GISAXS, IEC data, Nyquist plot, PFG-NMR diffusion plot of synthesized compound, and OH– conductivity measurement setup. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cited By

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    This article is cited by 37 publications.

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    Macromolecules

    Cite this: Macromolecules 2015, 48, 8, 2576–2584
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ma502448g
    Published April 15, 2015
    Copyright © 2015 American Chemical Society
    Request reuse permissions

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