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Hierarchical Self-Assembly and Dynamics of a Miktoarm Star chimera Composed of Poly(γ-benzyl-l-glutamate), Polystyrene, and Polyisoprene

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    Hierarchical Self-Assembly and Dynamics of a Miktoarm Star chimera Composed of Poly(γ-benzyl-l-glutamate), Polystyrene, and Polyisoprene
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    Department of Physics, University of Ioannina, P.O. Box 1186, GR-45110 Ioannina, Greece, and Foundation for Research and Technology-Hellas, Biomedical Research Institute (FORTH-BRI), P.O. Box 1385, GR-71110, Heraklion, Crete, Greece
    Max-Planck-Institut für Polymerforschung, D-55021 Mainz, Germany
    Department of Chemistry, University of Athens, Panepistimiopolis, Zografou, GR-15771 Athens, Greece
    Polymeric and Organic Materials Department, Graduate School of Science and Engineering, Tokyo Institute of Technology, Tokyo, 152-8552, Japan
    *To whom correspondence should be addressed. E-mail: [email protected]
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    Macromolecules

    Cite this: Macromolecules 2010, 43, 4, 1874–1881
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    https://doi.org/10.1021/ma902631e
    Published January 27, 2010
    Copyright © 2010 American Chemical Society
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    Abstract

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    The hierarchical self-assembly at the submicrometer, nanometer and α-helical length scales has been studied in a miktoarm star rod−coil chimera composed of poly(γ-benzyl-l-glutamate) (PBLG), polystyrene, and polyisoprene blocks by X-ray scattering, solid state NMR, and transmission electron microscopy. The propensity of the rod block toward α-helices that are further hexagonally packed gives rise to pure PBLG domains and induces the partial mixing of the two amorphous blocks. These structural results were confirmed by independent dynamic probes at the segmental and α-helical level by NMR and dielectric spectroscopy, respectively.

    Copyright © 2010 American Chemical Society

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    VT 13C CP NMR spectra of PBLG, PS, and PS-PI. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Macromolecules

    Cite this: Macromolecules 2010, 43, 4, 1874–1881
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ma902631e
    Published January 27, 2010
    Copyright © 2010 American Chemical Society
    Request reuse permissions

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