Letter

Nanorice:  A Hybrid Plasmonic Nanostructure

Department of Chemistry, Department of Physics and Astronomy, Department of Electrical and Computer Engineering, and the Laboratory for Nanophotonics, Rice University, Houston, Texas 77005
Nano Lett., 2006, 6 (4), pp 827–832
DOI: 10.1021/nl060209w
Publication Date (Web): March 11, 2006
Copyright © 2006 American Chemical Society

Abstract

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We have designed and fabricated a new hybrid nanoparticle that combines the intense local fields of nanorods with the highly tunable plasmon resonances of nanoshells. This dielectric core−metallic shell prolate spheroid nanoparticle bears a remarkable resemblance to a grain of rice, inspiring the name “nanorice”. This geometry possesses far greater structural tunability than either a nanorod or a nanoshell, along with much larger local field intensity enhancements and far greater sensitivity as a surface plasmon resonance (SPR) nanosensor than any dielectric−metal nanostructures reported previously. Invoking the plasmon hybridization picture allows us to understand the plasmon resonances of this geometry, as arising from a hybridization of the primitive plasmons of a solid spheroid and an ellipsoidal cavity inside a continuous metal.

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Article Views: 7,709 Times
Received 27 January 2006
Published online 11 March 2006
Published in print 1 April 2006
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