Letter

Chirality Changes in Carbon Nanotubes Studied with Near-Field Raman Spectroscopy

The Institute of Optics, University of Rochester, Rochester, New York 14627, and Department Chemie und Biochemie, Ludwig-Maximilians Universitaet Muenchen, Butenandtstrasse 11, 81377 Muenchen, Germany
Nano Lett., 2007, 7 (3), pp 577–582
DOI: 10.1021/nl0622496
Publication Date (Web): February 27, 2007
Copyright © 2007 American Chemical Society

Abstract

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We report on the direct visualization of chirality changes in carbon nanotubes by mapping local changes in resonant RBM phonon frequencies with an optical resolution of 40 nm using near-field Raman spectroscopy. We observe the transition from semiconducting-to-metal and metal-to-metal chiralities at the single nanotube level. Our experimental findings, based on detecting changes in resonant RBM frequencies, are complemented by measuring changes in the G-band frequency and line shape. In addition, we observe increased Raman scattering due to local defects associated with the structural transition. From our results, we determine the spatial extent of the transition region to be Ltrans ∼ 40−100 nm.

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Article Views: 981 Times
Received 23 September 2006
Published online 27 February 2007
Published in print 1 March 2007
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