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    Mesoporous Amorphous FePO4 Nanospheres as High-Performance Cathode Material for Sodium-Ion Batteries
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    † Hubei Key Laboratory of Electrochemical Power Sources, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China
    ‡ College of Chemistry, Central China Normal University, Wuhan 430079, China
    *(Y.C.) E-mail: [email protected]. Phone: +86-027-68754526.
    *(L.X.) E-mail: [email protected]
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    Cite this: Nano Lett. 2014, 14, 6, 3539–3543
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    https://doi.org/10.1021/nl501152f
    Published May 23, 2014
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    Abstract

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    FePO4 nanospheres are synthesized successfully through a simple chemically induced precipitation method. The nanospheres present a mesoporous amorphous structure. Electrochemical experiments show that the FePO4/C electrode demonstrates a high initial discharging capacity of 151 mAh g–1 at 20 mA g–1, stable cyclablilty (94% capacity retention ratio over 160 cycles), as well as high rate capability (44 mAh g–1 at 1000 mA g–1) for Na-ion storage. The superior electrochemical performance of the FePO4/C nanocomposite is due to its particular mesoporous amorphous structure and close contact with the carbon framework, which significantly improve the ionic and electronic transport and intercalation kinetics of Na ions.

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    Experimental details, material characterizations, EDS spectrum of the FePO4 nanospheres, TEM images of the FePO4 nanospheres, Raman spectra of the FePO4 and FePO4/C, a typical Tyndall effect, N2 adsorption/desorption isotherms of the FePO4 nanospheres, electrochemical characterization of the FePO4 cathode, and ex situ XRD patterns of the FePO4/C cathodes. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cite this: Nano Lett. 2014, 14, 6, 3539–3543
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