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Sorting of Double-Walled Carbon Nanotubes According to Their Outer Wall Electronic Type via a Gel Permeation Method

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Centre for Nanoscale Science and Technology, School of Chemical and Physical Sciences, Flinders University, Adelaide 5042, Australia
Institute of Nanotechnology, Karlsruhe Institute of Technology, 76021 Karlsruhe, Germany
§ Institute for Materials Science, Technische Universität Darmstadt, 64287 Darmstadt, Germany
Helmholtz Institute Ulm Electrochemical Energy Storage, 89081 Ulm, Germany
Karlsruhe Nano Micro Facility, Karlsruhe Institute of Technology, 76021 Karlsruhe, Germany
*Address correspondence to [email protected]
Cite this: ACS Nano 2015, 9, 4, 3849–3857
Publication Date (Web):March 10, 2015
https://doi.org/10.1021/nn506869h
Copyright © 2015 American Chemical Society
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Abstract

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In this work, we demonstrate the application of the gel permeation technique to the sorting of double-walled carbon nanotubes (DWCNTs) according to their outer wall electronic type. Our method uses Sephacryl S-200 gel and yields sorted fractions of DWCNTs with impurities removed and highly enriched in nanotubes with either metallic (M) or semiconducting (S) outer walls. The prepared fractions are fully characterized using optical absorption spectroscopy, transmission electron microscopy, and atomic force microscopy, and the entire procedure is monitored in real time using process Raman analysis. The sorted DWCNTs are then integrated into single nanotube field effect transistors, allowing detailed electronic measurement of the transconductance properties of the four unique [email protected] wall combinations of [email protected], [email protected], [email protected], and [email protected]

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Supporting absorbance spectra, AFM statistics, Raman characterization, and TEM data. This material is available free of charge via the Internet at http://pubs.acs.org.

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This article is cited by 16 publications.

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  3. Ye Liu, Mirko Nitschke, Lukas Stepien, Vyacheslav Khavrus, Viktor Bezugly, Gianaurelio Cuniberti. Ammonia Plasma-Induced n-Type Doping of Semiconducting Carbon Nanotube Films: Thermoelectric Properties and Ambient Effects. ACS Applied Materials & Interfaces 2019, 11 (24) , 21807-21814. https://doi.org/10.1021/acsami.9b02918
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  6. Steingrimur Stefansson, Rodrigo Lazo-Portugal, Saeyoung Ahn, and Martha Knight . Spiral Countercurrent Chromatography Enrichment, Characterization, and Assays of Carbon Nanotube Chiralities for Use in Biosensors. ACS Omega 2017, 2 (3) , 1156-1162. https://doi.org/10.1021/acsomega.6b00536
  7. Laura Wieland, Han Li, Christian Rust, Jianhui Chen, Benjamin S. Flavel. Carbon Nanotubes for Photovoltaics: From Lab to Industry. Advanced Energy Materials 2021, 11 (3) , 2002880. https://doi.org/10.1002/aenm.202002880
  8. Lei Shi, Jinquan Wei, Kazuhiro Yanagi, Takeshi Saito, Kecheng Cao, Ute Kaiser, Paola Ayala, Thomas Pichler. Templated direct growth of ultra-thin double-walled carbon nanotubes. Nanoscale 2018, 10 (45) , 21254-21261. https://doi.org/10.1039/C8NR06925E
  9. Jeffrey L. Blackburn, Andrew J. Ferguson, Chungyeon Cho, Jaime C. Grunlan. Carbon‐Nanotube‐Based Thermoelectric Materials and Devices. Advanced Materials 2018, 30 (11) , 1704386. https://doi.org/10.1002/adma.201704386
  10. Dawid Janas. Towards monochiral carbon nanotubes: a review of progress in the sorting of single-walled carbon nanotubes. Materials Chemistry Frontiers 2018, 2 (1) , 36-63. https://doi.org/10.1039/C7QM00427C
  11. Han Li, Georgy Gordeev, Sören Wasserroth, Venkata Sai Kiran Chakravadhanula, Shyam Kumar Chethala Neelakandhan, Frank Hennrich, Ado Jorio, Stephanie Reich, Ralph Krupke, Benjamin Scott Flavel. Inner- and outer-wall sorting of double-walled carbon nanotubes. Nature Nanotechnology 2017, 12 (12) , 1176-1182. https://doi.org/10.1038/nnano.2017.207
  12. Martha Knight, Rodrigo Lazo-Portugal, Saeyoung Nate Ahn, Steingrimur Stefansson. Purification of semiconducting single-walled carbon nanotubes by spiral counter-current chromatography. Journal of Chromatography A 2017, 1483 , 93-100. https://doi.org/10.1016/j.chroma.2016.12.070
  13. J. K. Streit, S. Lam, Y. Piao, A. R. Hight Walker, J. A. Fagan, M. Zheng. Separation of double-wall carbon nanotubes by electronic type and diameter. Nanoscale 2017, 9 (7) , 2531-2540. https://doi.org/10.1039/C6NR09257H
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  15. O. S. Zueva, O. N. Makshakova, B. Z. Idiyatullin, D. A. Faizullin, N. N. Benevolenskaya, A. O. Borovskaya, E. A. Sharipova, Yu. N. Osin, V. V. Salnikov, Yu. F. Zuev. Structure and properties of aqueous dispersions of sodium dodecyl sulfate with carbon nanotubes. Russian Chemical Bulletin 2016, 65 (5) , 1208-1215. https://doi.org/10.1007/s11172-016-1437-5
  16. Nan Wei, Huixin Huang, Yang Liu, Leijing Yang, Fanglin Wang, Huanhuan Xie, Yingying Zhang, Fei Wei, Sheng Wang, Lianmao Peng. Nanoscale color sensors made on semiconducting multi-wall carbon nanotubes. Nano Research 2016, 9 (5) , 1470-1479. https://doi.org/10.1007/s12274-016-1043-8

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