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A New Tin-Free Source of Amidyl Radicals
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    A New Tin-Free Source of Amidyl Radicals
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    Laboratoire de Synthèse Organique associé au CNRS, Ecole Polytechnique, 91128 Palaiseau, France
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    Organic Letters

    Cite this: Org. Lett. 2002, 4, 16, 2707–2709
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    https://doi.org/10.1021/ol026221m
    Published July 4, 2002
    Copyright © 2002 American Chemical Society

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    The readily available N-(O-ethyl thiocarbonylsulfanyl)amides are powerful amidyl radical precursors that undergo 5-exo cyclization to give pyrrolidinone derivatives via a radical-chain reaction initiated by a small amount of lauroyl peroxide.

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    Detailed experimental procedures and spectra data for compounds 1ah, 2ah, 3ah, 6, 7, 8, 9, and 13. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Organic Letters

    Cite this: Org. Lett. 2002, 4, 16, 2707–2709
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ol026221m
    Published July 4, 2002
    Copyright © 2002 American Chemical Society

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