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Heck Couplings at Room Temperature in Nanometer Aqueous Micelles

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Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106
Cite this: Org. Lett. 2008, 10, 7, 1329–1332
Publication Date (Web):March 12, 2008
https://doi.org/10.1021/ol702755g
Copyright © 2008 American Chemical Society

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    Abstract

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    A nonionic amphiphile such as Triton X-100 or the vitamin E-based PTS, both of which form nanomicelles in water, promotes Heck cross-couplings of non-water-soluble partners at ambient temperatures. These are the first examples of Heck reactions conducted in water (as the only solvent) at room temperature.

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     Dedicated with greatest respect and admiration to Professor E. J. Corey, Nobel Laureate, on the occasion of his 80th birthday.

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