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Chemistry of the vanadium-carbon .sigma. bond. 2. Oxovanadium(IV) and oxovanadium(V) containing metal-to-carbon .sigma. bonds

Cite this: Organometallics 1993, 12, 5, 1802–1810
Publication Date (Print):May 1, 1993
https://doi.org/10.1021/om00029a042
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    26. C. Lorber. Vanadium Organometallics. 2007, 1-60. https://doi.org/10.1016/B0-08-045047-4/00066-2
    27. S. Kobayashi, M. Sugiura, U. Schneider, R. Matsubara, J. Fossey, Y. Yamashita. C–C Bond Formation Through Addition of C–M to CO, CN, and CN Bonds. 2007, 403-491. https://doi.org/10.1016/B0-08-045047-4/00131-X
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    30. Adam S. Veige, Troy S. Kleckley, Rebecca M. Chamberlin, David R. Neithamer, Christina E. Lee, Peter T. Wolczanski, Emil B. Lobkovsky, Wingfied V. Glassey. (Silox)3Nb(η2-N,C-4-picoline) as a source of (silox)3Nb: structure of [(silox)3Nb]2(μ-η2,η2-C6H6) (silox= Bu3SiO). Journal of Organometallic Chemistry 1999, 591 (1-2) , 194-203. https://doi.org/10.1016/S0022-328X(99)00524-0
    31. Aaron L. Odom, Christopher C. Cummins. Chromium(VI) nitrido complexes: reactions with Brønsted acids and synthesis of organometallic derivatives. Polyhedron 1998, 17 (5-6) , 675-688. https://doi.org/10.1016/S0277-5387(97)00402-6
    32. Paul J. Toscano. Reactions of Other Addenda. 1998, 208-215. https://doi.org/10.1002/9780470145296.ch191
    33. Christopher C. Cummins. Three‐Coordinate Complexes of “Hard” Ligands: Advances in Synthesis, Structure and Reactivity. 1997, 685-836. https://doi.org/10.1002/9780470166482.ch7
    34. Perdita Arndt, Claudia Lefeber, Rhett Kempe, Annegret Tillack, Uwe Rosenthal. Reactions of Lactams with Titanocene‐ and Zirconocene‐Alkyne Complexes as Elemental Steps in Catalytic Anionic Ring‐Opening Polymerization of Lactams. Chemische Berichte 1996, 129 (10) , 1281-1285. https://doi.org/10.1002/cber.19961291022
    35. Jane E. MacIntyre. V Vanadium. 1996, 296-298. https://doi.org/10.1007/978-1-4899-6848-7_60
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