Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Your Mendeley pairing has expired. Please reconnect
ACS Publications. Most Trusted. Most Cited. Most Read
My Activity

Figure 1Loading Img

Chemistry of the vanadium-carbon .sigma. bond. 2. Oxovanadium(IV) and oxovanadium(V) containing metal-to-carbon .sigma. bonds

Cite this: Organometallics 1993, 12, 5, 1802–1810
Publication Date (Print):May 1, 1993
    ACS Legacy Archive

    Article Views





    Other access options
    Supporting Info (1)»

    Note: In lieu of an abstract, this is the article's first page.

    Free first page

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.


    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    Terms & Conditions

    Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machine-readable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at

    Cited By

    This article is cited by 36 publications.

    1. Brittney E. Petel, William W. Brennessel, Ellen M. Matson. Oxygen-Atom Vacancy Formation at Polyoxovanadate Clusters: Homogeneous Models for Reducible Metal Oxides. Journal of the American Chemical Society 2018, 140 (27) , 8424-8428.
    2. Vladimir V. Zhivonitko, Ivan V. Skovpin, Kai C. Szeto, Mostafa Taoufik, Igor V. Koptyug. Parahydrogen-Induced Polarization Study of the Silica-Supported Vanadium Oxo Organometallic Catalyst. The Journal of Physical Chemistry C 2018, 122 (9) , 4891-4900.
    3. Mei Ding, Mathieu Rouzières, Yaroslav Losovyj, Maren Pink, Rodolphe Clérac, and Jeremy M. Smith . Partial Nitrogen Atom Transfer: A New Synthetic Tool to Design Single-Molecule Magnets. Inorganic Chemistry 2015, 54 (18) , 9075-9080.
    4. Chung-Yang (Dennis) Huang and Abigail G. Doyle . The Chemistry of Transition Metals with Three-Membered Ring Heterocycles. Chemical Reviews 2014, 114 (16) , 8153-8198.
    5. Kai C. Szeto, Björn Loges, Nicolas Merle, Nicolas Popoff, Alessandra Quadrelli, Hongpeng Jia, Elise Berrier, Aimery De Mallmann, Laurent Delevoye, Régis M. Gauvin, and Mostafa Taoufik . Vanadium Oxo Organometallic Species Supported on Silica for the Selective Non-oxidative Dehydrogenation of Propane. Organometallics 2013, 32 (21) , 6452-6460.
    6. Alexander G. Tskhovrebov, Euro Solari, Matthew D. Wodrich, Rosario Scopelliti, and Kay Severin . Sequential N–O and N–N Bond Cleavage of N-Heterocyclic Carbene-Activated Nitrous Oxide with a Vanadium Complex. Journal of the American Chemical Society 2012, 134 (3) , 1471-1473.
    7. Staci L. Wegener, Hacksung Kim, Tobin J. Marks, and Peter C. Stair . Precursor Nuclearity Effects in Supported Vanadium Oxides Prepared by Organometallic Grafting. The Journal of Physical Chemistry Letters 2011, 2 (3) , 170-175.
    8. Uriah J. Kilgore, Caitlin A. Sengelaub, Hongjun Fan, John Tomaszewski, Jonathan A. Karty, Mu-Hyun Baik and Daniel J. Mindiola. A Transient Vanadium(III) Neopentylidene Complex. Redox Chemistry and Reactivity of the V═CHtBu Functionality. Organometallics 2009, 28 (3) , 843-852.
    9. Gareth R. Owen,, Ramón Vilar,, Andrew J. P. White, and, David J. Williams. Synthesis and Structural Characterization of a Novel Dipalladium Complex with an Unprecedented PdCN Bonding Motif. Organometallics 2003, 22 (15) , 3025-3027.
    10. Tristram Chivers,, Andrew Downard,, Masood Parvez, and, Gabriele Schatte. Hexameric and Tetrameric Copper(I) Thioamidates. Organometallics 2001, 20 (4) , 727-733.
    11. George E. Greco,, Myra B. O'Donoghue,, Scott W. Seidel,, William M. Davis, and, Richard R. Schrock. Synthesis of [(Me3SiNCH2CH2)3N]3- and [(C6F5NCH2CH2)3N]3- Complexes of Molybdenum and Tungsten That Contain CO, Isocyanides, or Ethylene. Organometallics 2000, 19 (6) , 1132-1149.
    12. Barbara Castellano,, Euro Solari,, Carlo Floriani, and, Rosario Scopelliti, , Nazzareno Re. Reactivity of a Vanadium(III) Center over an Oxo Surface Modeled by Calix[4]arene. Inorganic Chemistry 1999, 38 (14) , 3406-3413.
    13. Tristram Chivers,, Andrew Downard, and, Glenn P. A. Yap. Paddle-Wheel and Trilobate Isomers of the Hexagonal Prisms {Li[CE(Nt-Bu)(n-Bu)]}6 (E = S, O). Inorganic Chemistry 1998, 37 (22) , 5708-5709.
    14. Barbara Castellano,, Euro Solari, and, Carlo Floriani, , Nazzareno Re, , Angiola Chiesi-Villa and, Corrado Rizzoli. The Chemistry of Vanadium−Carbon Bond Functionalities over an Oxo-Surface Defined by the Calix[4]arene Skeleton:  The Redox Relationship between Vanadium(III) and Vanadium(IV) Assisted by Carbon−Oxygen Bond Cleavage. Organometallics 1998, 17 (11) , 2328-2336.
    15. Richard Ferguson,, Euro Solari,, Carlo Floriani,, Domenico Osella,, Mauro Ravera,, Nazzareno Re,, Angiola Chiesi-Villa, and, Corrado Rizzoli. Stepwise Reduction of Dinitrogen Occurring on a Divanadium Model Compound:  A Synthetic, Structural, Magnetic, Electrochemical, and Theoretical Investigation on the [VNNV]n+ [n = 4−6] Based Complexes. Journal of the American Chemical Society 1997, 119 (42) , 10104-10115.
    16. Jan Karel F. Buijink,, K. Richard Kloetstra,, Auke Meetsma, and, Jan H. Teuben, , Wilberth J. J. Smeets and, Anthony L. Spek. Structure and Reactivity of Mono(cyclopentadienyl)vanadium Alkynyl and Aryne Complexes. Organometallics 1996, 15 (10) , 2523-2533.
    17. Jonas C. Peters,, Adam R. Johnson,, Aaron L. Odom,, Paulus W. Wanandi,, William M. Davis, and, Christopher C. Cummins. Assembly of Molybdenum/Titanium μ-Oxo Complexes via Radical Alkoxide C−O Cleavage. Journal of the American Chemical Society 1996, 118 (42) , 10175-10188.
    18. Muhammad Farhan Hanif, Hasan Mahmood, Mazhar Hussain, Zohaib Siddique. On analysis of entropy measures for vanadium III chloride via line fit method. The European Physical Journal Plus 2023, 138 (6)
    19. Jindi Guo, Wangyang Zhang, Xianglong Yang, Yan Peng, Xiaobo Hu, Xiangang Xu, Duo Liu. The effect of doping on the hardness of silicon carbide single crystal and its first principles calculations. 2020, 4-7.
    20. Fatemeh Abyar, Leila Tabrizi. Experimental and theoretical investigations of novel oxidovanadium(IV) juglone complex: DNA/HSA interaction and cytotoxic activity. Journal of Biomolecular Structure and Dynamics 2020, 38 (2) , 474-487.
    21. C. Lorber. Vanadium Organometallics☆. 2016
    22. Jillian A. Hatnean, Samuel A. Johnson. Diamagnetic molybdenum nitride complexes supported by diligating tripodal triamido-phosphine ligands as precursors to paramagnetic phosphine donors. Dalton Transactions 2015, 44 (33) , 14925-14936.
    23. Jussi Kauppila, Liisa Lund, Taina Laiho, Mikko Salomäki, Jouko Kankare, Jukka Lukkari. Effective low temperature reduction of graphene oxide with vanadium(iii). Journal of Materials Chemistry C 2014, 2 (18) , 3602.
    24. David Elorriaga, Fernando Carrillo‐Hermosilla, Antonio Antiñolo, Isabel López‐Solera, Rafael Fernández‐Galán, Amparo Serrano, Elena Villaseñor. Synthesis, Characterization and Reactivity of New Dinuclear Guanidinate Diimidoniobium Complexes. European Journal of Inorganic Chemistry 2013, 2013 (16) , 2940-2946.
    25. Matthew B. Jones, Kenneth I. Hardcastle, Cora E. MacBeth. Synthetic, spectral and structural studies of mononuclear tris(κ2-amidate) aluminium complexes supported by tripodal ligands. Polyhedron 2010, 29 (1) , 116-119.
    26. C. Lorber. Vanadium Organometallics. 2007, 1-60.
    27. S. Kobayashi, M. Sugiura, U. Schneider, R. Matsubara, J. Fossey, Y. Yamashita. C–C Bond Formation Through Addition of C–M to CO, CN, and CN Bonds. 2007, 403-491.
    28. Fabien Wolff, Robert Choukroun, Christian Lorber, Bruno Donnadieu. Reactivity of B(C 6 F 5 ) 3 with Oxovanadium( V ) Complexes VOL 3 (L = OCH 2 CF 3 , NEt 2 ): Formation of the Organometallic Vanadium( V ) Complex [VO(μ‐OCH 2 CF 3 )(OCH 2 CF 3 )(C 6 F 5 )] 2 and the Lewis Acid Adduct [(Et 2 N) 3 VO·B(C 6 F 5 ) 3 ]. European Journal of Inorganic Chemistry 2003, 2003 (4) , 628-632.
    29. John D. Schupp, Stan A. Duraj, Robert M. Richman, Aloysius F. Hepp, Phillip E. Fanwick. The Crystal and Molecular Structure of Acetatochlorobis(4-methylpyridine) oxovanadium (IV). Journal of Coordination Chemistry 2002, 55 (9) , 1045-1051.
    30. Adam S. Veige, Troy S. Kleckley, Rebecca M. Chamberlin, David R. Neithamer, Christina E. Lee, Peter T. Wolczanski, Emil B. Lobkovsky, Wingfied V. Glassey. (Silox)3Nb(η2-N,C-4-picoline) as a source of (silox)3Nb: structure of [(silox)3Nb]2(μ-η2,η2-C6H6) (silox= Bu3SiO). Journal of Organometallic Chemistry 1999, 591 (1-2) , 194-203.
    31. Aaron L. Odom, Christopher C. Cummins. Chromium(VI) nitrido complexes: reactions with Brønsted acids and synthesis of organometallic derivatives. Polyhedron 1998, 17 (5-6) , 675-688.
    32. Paul J. Toscano. Reactions of Other Addenda. 1998, 208-215.
    33. Christopher C. Cummins. Three‐Coordinate Complexes of “Hard” Ligands: Advances in Synthesis, Structure and Reactivity. 1997, 685-836.
    34. Perdita Arndt, Claudia Lefeber, Rhett Kempe, Annegret Tillack, Uwe Rosenthal. Reactions of Lactams with Titanocene‐ and Zirconocene‐Alkyne Complexes as Elemental Steps in Catalytic Anionic Ring‐Opening Polymerization of Lactams. Chemische Berichte 1996, 129 (10) , 1281-1285.
    35. Jane E. MacIntyre. V Vanadium. 1996, 296-298.
    36. James M. Mayer. Not solely a spectator: Exploring the chemistry of the CO bond in alkoxide and related ligands. Polyhedron 1995, 14 (22) , 3273-3292.