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Preparation and reaction chemistry of trimethylsilyl derivatives of tantalum. X-ray structures of d0 (.eta.5-C5Me5)Ta(SiMe3)Cl3 and d1 (.eta.5-C5Me5)Ta(SiMe3)(PMe3)Cl2

Cite this: Organometallics 1986, 5, 10, 2037–2044
Publication Date (Print):October 1, 1986
https://doi.org/10.1021/om00141a017
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    Cited By

    This article is cited by 17 publications.

    1. Kyle D. J. Parker and Michael D. Fryzuk . Synthesis, Structure, and Reactivity of Niobium and Tantalum Alkyne Complexes. Organometallics 2015, 34 (11) , 2037-2047. https://doi.org/10.1021/om5010385
    2. John Gavenonis and, T. Don Tilley. Synthesis and Reactivity of Tris(imido)rhenium Complexes Containing Rhenium−Main Group Element Bonds. Silicon−Carbon Bond Activations of PhSiH3 by Silyl Complexes. Inorganic Chemistry 2004, 43 (14) , 4353-4362. https://doi.org/10.1021/ic030282e
    3. Zhongzhi Wu,, Hu Cai,, Xianghua Yu,, Jaime R. Blanton,, Jonathan B. Diminnie,, Hong-Jun Pan, and, Ziling Xue, , Jeffrey C. Bryan. Synthesis of Tantalum(V) Amido Silyl Complexes and the Unexpected Formation of (Me2N)3Ta(η2-ONMe2)[OSi(SiMe3)3] from the Reaction of (Me2N)4Ta[Si(SiMe3)3] with O2. Organometallics 2002, 21 (19) , 3973-3978. https://doi.org/10.1021/om020537g
    4. Zhongzhi Wu and, Ziling Xue. Synthesis and Characterization of Tantalum Silyl and Disilyl Imido Complexes That Do Not Contain Anionic π-Ligands. Organometallics 2000, 19 (21) , 4191-4192. https://doi.org/10.1021/om000503d
    5. Urs Burckhardt,, Gary L. Casty, and, T. Don Tilley, , Tom K. Woo and, Ursula Rothlisberger. Ditantalum Hydride Complexes with Bridging (2,6-iPr2C6H3)NSiHPh Silanimine Ligands Resulting from PhSiH3−Imido Ligand Coupling. A Combined Spectroscopic and Theoretical Investigation. Organometallics 2000, 19 (19) , 3830-3841. https://doi.org/10.1021/om000455x
    6. Joyce Y. Corey and, Janet Braddock-Wilking. Reactions of Hydrosilanes with Transition-Metal Complexes:  Formation of Stable Transition-Metal Silyl Compounds. Chemical Reviews 1999, 99 (1) , 175-292. https://doi.org/10.1021/cr9701086
    7. Liting Li,, Jonathan B. Diminnie,, Xiaozhan Liu,, Jonathan L. Pollitte, and, Ziling Xue. Synthesis and Characterization of (Me3ECH2)2Ta(CHEMe3)Si(SiMe3)3 (E = C, Si). Kinetic and Mechanistic Studies of the Formation of a Silyl Alkylidene Complex through Preferential Silane Elimination. Organometallics 1996, 15 (16) , 3520-3527. https://doi.org/10.1021/om960382a
    8. Makoto Tanabe, Kohtaro Osakada. Transition Metal Complexes of Silicon (Excluding Silylene Complexes). 2017, 31-67. https://doi.org/10.1016/B978-0-12-801981-8.00002-2
    9. Ana Conde, Rosa Fandos, Antonio Otero, Ana Rodríguez, Pilar Terreros. Synthesis and Reactivity of Monocyclopentadienyltantalum(V) Siloxide Complexes. European Journal of Inorganic Chemistry 2008, 2008 (19) , 3062-3067. https://doi.org/10.1002/ejic.200800229
    10. Ziling Xue. Early-Transition-Metal Silyl Complexes Free of Anionic π-Ligands. A Comparison of Alkyl and Silyl Ligands. Comments on Inorganic Chemistry 1996, 18 (4) , 223-247. https://doi.org/10.1080/02603599608032723
    11. Guillermo C. Bazan, George Rodriguez. Tantalum-borollide alkyl complexes. Polyhedron 1995, 14 (1) , 93-102. https://doi.org/10.1016/0277-5387(94)00353-G
    12. David E. Wigley, Steven D. Gray. Niobium and Tantalum. 1995, 57-153. https://doi.org/10.1016/B978-008046519-7.00039-3
    13. T. Don Tilley. Transition‐metal silyl derivatives. 1991, 245-308. https://doi.org/10.1002/9780470772447.ch9
    14. U. Schubert. Transition-metal silyl complexes. Transition Metal Chemistry 1991, 16 (1) , 136-144. https://doi.org/10.1007/BF01127889
    15. Malcolm L. H. Green, Andrew K. Hughes, Philip Mountford. Synthesis and reactivity of bis(η-cyclopentadienyl) trimethyltin derivatives of niobium: crystal and molecular structure of [{Nb(η-C 5 H 5 ) 2 (SnMe 3 )} 2 (µ-O)]. J. Chem. Soc., Dalton Trans. 1991, 89 (6) , 1407-1416. https://doi.org/10.1039/DT9910001407
    16. Frederick H. Elsner, T.Don Tilley, Arnold L. Rheingold, Steven J. Geib. Reactions of (η5-C5H5)(η5-C5Me5)Zr[Si(SiMe3)3]X (X  Cl, Me) complexes with carbon monoxide and the isocyanide 2,6-Me2C6H3NC. Crystal structure of (η5-C5H5)(η5-C5Me5)Zr[η2-C(N-2,6-Me2C6H3)Si(SiMe3)3]Cl. Journal of Organometallic Chemistry 1988, 358 (1-3) , 169-183. https://doi.org/10.1016/0022-328X(88)87078-5
    17. J. ARNOLD, D. N. SHINA, T. D. TILLEY, A. M. ARIF. ChemInform Abstract: Preparation and Reaction Chemistry of Trimethylsilyl Derivatives of Tantalum. X‐Ray Structures of d0 (η5‐C5Me5)Ta(SiMe3)Cl3 and d1 (η5‐C5Me5)Ta(SiMe3)(PMe3)Cl2.. ChemInform 1987, 18 (12) https://doi.org/10.1002/chin.198712281