Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect
ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Synthesis and reactivity of the cationic organosamarium(III) complex [(C5Me5)2Sm(THF)2][BPh4], including the synthesis and structure of a metallocene with an alkoxy-tethered C5Me5 ring, (C5Me5)2Sm[O(CH2)4C5Me5](THF)

Cite this: Organometallics 1990, 9, 7, 2124–2130
Publication Date (Print):July 1, 1990
https://doi.org/10.1021/om00157a024
    ACS Legacy Archive

    Article Views

    536

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options
    Supporting Info (1)»

    Note: In lieu of an abstract, this is the article's first page.

    Free first page

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information


    Terms & Conditions

    Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machine-readable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 152 publications.

    1. Martin Bonath, Dorothea Schädle, Cäcilia Maichle-Mössmer, Reiner Anwander. The Alkylaluminate/Gallate Trap: Metalation of Benzene by Heterobimetallic Yttrocene Complexes [Cp*2Y(MMe3R)] (M = Al, Ga). Inorganic Chemistry 2021, 60 (19) , 14952-14968. https://doi.org/10.1021/acs.inorgchem.1c02349
    2. Selvan Demir, Monica D. Boshart, Jordan F. Corbey, David H. Woen, Miguel I. Gonzalez, Joseph W. Ziller, Katie R. Meihaus, Jeffrey R. Long, and William J. Evans . Slow Magnetic Relaxation in a Dysprosium Ammonia Metallocene Complex. Inorganic Chemistry 2017, 56 (24) , 15049-15056. https://doi.org/10.1021/acs.inorgchem.7b02390
    3. Nikolay A. Pushkarevsky, Igor Yu. Ilyin, Pavel A. Petrov, Denis G. Samsonenko, Maxim R. Ryzhikov, Peter W. Roesky, and Sergey N. Konchenko . Different Reductive Reactivities of SmCpx2(THF)n (Cpx = C5Me5 and C5H3tBu2) Samarocenes toward P2Ph4: THF Ring-Opening and Ligand-Exchange Pathways. Organometallics 2017, 36 (7) , 1287-1295. https://doi.org/10.1021/acs.organomet.7b00014
    4. Christopher M. Kotyk, Matthew R. MacDonald, Joseph W. Ziller, and William J. Evans . Reactivity of the Ln2+ Complexes [K(2.2.2-cryptand)][(C5H4SiMe3)3Ln]: Reduction of Naphthalene and Biphenyl. Organometallics 2015, 34 (11) , 2287-2295. https://doi.org/10.1021/om501063h
    5. Megan E. Fieser, Matthew R. MacDonald, Brandon T. Krull, Jefferson E. Bates, Joseph W. Ziller, Filipp Furche, and William J. Evans . Structural, Spectroscopic, and Theoretical Comparison of Traditional vs Recently Discovered Ln2+ Ions in the [K(2.2.2-cryptand)][(C5H4SiMe3)3Ln] Complexes: The Variable Nature of Dy2+ and Nd2+. Journal of the American Chemical Society 2015, 137 (1) , 369-382. https://doi.org/10.1021/ja510831n
    6. Jee Eon Kim, David S. Weinberger, Patrick J. Carroll, and Eric J. Schelter . Synthesis, Structural Characterization, and Carbonyl Addition Reactivity of a Terminal Cerium(III) Acetylide Complex. Organometallics 2014, 33 (21) , 5948-5951. https://doi.org/10.1021/om500899z
    7. Matthew R. MacDonald, Jefferson E. Bates, Joseph W. Ziller, Filipp Furche, and William J. Evans . Completing the Series of +2 Ions for the Lanthanide Elements: Synthesis of Molecular Complexes of Pr2+, Gd2+, Tb2+, and Lu2+. Journal of the American Chemical Society 2013, 135 (26) , 9857-9868. https://doi.org/10.1021/ja403753j
    8. Jeffrey K. Peterson, Matthew R. MacDonald, Joseph W. Ziller, and William J. Evans . Synthetic Aspects of (C5H4SiMe3)3Ln Rare-Earth Chemistry: Formation of (C5H4SiMe3)3Lu via [(C5H4SiMe3)2Ln]+ Metallocene Precursors. Organometallics 2013, 32 (9) , 2625-2631. https://doi.org/10.1021/om400116d
    9. Zhongbao Jian, Noa K. Hangaly, Weifeng Rong, Zehuai Mou, Dongtao Liu, Shihui Li, Alexander A. Trifonov, Jörg Sundermeyer, and Dongmei Cui . Yttrium Hydride Complex Bearing CpPN/Amidinate Heteroleptic Ligands: Synthesis, Structure, and Reactivity. Organometallics 2012, 31 (12) , 4579-4587. https://doi.org/10.1021/om3003703
    10. Tanja Sanden, Michael T. Gamer, Anatoly A. Fagin, Valentina A. Chudakova, Sergey N. Konchenko, Igor L. Fedushkin, and Peter W. Roesky . Synthesis of Unsupported Ln–Ga Bonds by Salt Metathesis and Ga–Ga Bond Reduction. Organometallics 2012, 31 (11) , 4331-4339. https://doi.org/10.1021/om300309b
    11. Weiyin Yi, Jie Zhang, Meng Li, Zhenxia Chen, and Xigeng Zhou . Synthesis, Structures, and Reactivity of Yttrium Alkyl and Alkynyl Complexes with Mixed TpMe2/Cp Ligands. Inorganic Chemistry 2011, 50 (22) , 11813-11824. https://doi.org/10.1021/ic2019499
    12. Ellen M. Matson, Phillip E. Fanwick, and Suzanne C. Bart . Formation of Trivalent U–C, U–N, and U–S Bonds and Their Reactivity toward Carbon Dioxide and Acetone. Organometallics 2011, 30 (21) , 5753-5762. https://doi.org/10.1021/om200612h
    13. Matthew R. MacDonald, Joseph W. Ziller, and William J. Evans . Coordination and Reductive Chemistry of Tetraphenylborate Complexes of Trivalent Rare Earth Metallocene Cations, [(C5Me5)2Ln][(μ-Ph)2BPh2]. Inorganic Chemistry 2011, 50 (9) , 4092-4106. https://doi.org/10.1021/ic2000409
    14. Thomas J. Mueller, Gregory W. Nyce, and William J. Evans . Defining Reactivity Differences in Sterically Crowded (η5-C5Me5)3M Complexes Based on Metal Size and Lanthanide vs Actinide Effects. Organometallics 2011, 30 (5) , 1231-1235. https://doi.org/10.1021/om101149z
    15. Kuburat O. Saliu, Jianhua Cheng, Robert McDonald, Michael J. Ferguson, and Josef Takats. Reactions of Scorpionate-Anchored Yttrium and Lutetium Dialkyls with Terminal Alkynes: From Bimetallic Complexes with Bridging Enynediyl Ligands to Monomeric Terminal Dialkynyl Complexes. Organometallics 2010, 29 (21) , 4950-4965. https://doi.org/10.1021/om100393w
    16. Yan Sun, Zhengxing Zhang, Xu Wang, Xiaoqing Li, Linhong Weng and Xigeng Zhou . Lanthanide-Induced Diinsertion of Isocyanates into the N−H Bond: Synthesis, Structure, and Reactivity of Organolanthanides Containing Diureido Ligands. Organometallics 2009, 28 (21) , 6320-6330. https://doi.org/10.1021/om900631j
    17. Vitalie Stavila, John H. Thurston and Kenton H. Whitmire . Selective Arylation Reactions of Bismuth−Transition Metal Salicylate Complexes. Inorganic Chemistry 2009, 48 (14) , 6945-6951. https://doi.org/10.1021/ic9010357
    18. William J. Evans, Thomas J. Mueller and Joseph W. Ziller. Reactivity of (C5Me5)3LaLx Complexes: Synthesis of a Tris(pentamethylcyclopentadienyl) Complex with Two Additional Ligands, (C5Me5)3La(NCCMe3)2. Journal of the American Chemical Society 2009, 131 (7) , 2678-2686. https://doi.org/10.1021/ja808763y
    19. Anthony G. M. Barrett, Mark R. Crimmin, Michael S. Hill, Peter B. Hitchcock, Sarah L. Lomas, Mary F. Mahon, Panayiotis A. Procopiou and Kogularamanan Suntharalingam. β-Diketiminato Calcium Acetylides: Synthesis, Solution Dimerization, and Catalytic Carbon−Carbon Bond Formation. Organometallics 2008, 27 (23) , 6300-6306. https://doi.org/10.1021/om800738r
    20. Christopher R. Graves, Brian L. Scott, David E. Morris and Jaqueline L. Kiplinger. Tetravalent and Pentavalent Uranium Acetylide Complexes Prepared by Oxidative Functionalization with CuC≡CPh. Organometallics 2008, 27 (14) , 3335-3337. https://doi.org/10.1021/om800466m
    21. Hui Zhou,, Huadong Guo,, Yingming Yao,, Liying Zhou,, Hongmei Sun,, Hongting Sheng,, Yong Zhang, and, Qi Shen. Ytterbium(II) Complex Bearing a Diaminobis(phenolate) Ligand:  Synthesis, Structure, and One-Electron-Transfer and ε-Caprolactone Polymerization Reactions. Inorganic Chemistry 2007, 46 (3) , 958-964. https://doi.org/10.1021/ic061805w
    22. William J. Evans,, Timothy M. Champagne, and, Joseph W. Ziller. Synthesis and Reactivity of Mono(pentamethylcyclopentadienyl) Tetraphenylborate Lanthanide Complexes of Ytterbium and Samarium:  Tris(ring) Precursors to (C5Me5)Ln Moieties. Organometallics 2007, 26 (5) , 1204-1211. https://doi.org/10.1021/om060963s
    23. Peter M. Zeimentz,, Stefan Arndt,, Benjamin R. Elvidge, and, Jun Okuda. Cationic Organometallic Complexes of Scandium, Yttrium, and the Lanthanoids. Chemical Reviews 2006, 106 (6) , 2404-2433. https://doi.org/10.1021/cr050574s
    24. Marco W. Bouwkamp,, Peter H. M. Budzelaar,, Jeroen Gercama,, Isabel Del Hierro Morales,, Jeanette de Wolf,, Auke Meetsma,, Sergei I. Troyanov,, Jan H. Teuben, and, Bart Hessen. Naked (C5Me5)2M Cations (M = Sc, Ti, and V) and Their Fluoroarene Complexes. Journal of the American Chemical Society 2005, 127 (41) , 14310-14319. https://doi.org/10.1021/ja054544i
    25. William J. Evans,, Jeremy M. Perotti,, Stosh A. Kozimor,, Timothy M. Champagne,, Benjamin L. Davis,, Gregory W. Nyce,, Cy H. Fujimoto,, Robert D. Clark,, Matthew A. Johnston, and, Joseph W. Ziller. Synthesis and Comparative η1-Alkyl and Sterically Induced Reduction Reactivity of (C5Me5)3Ln Complexes of La, Ce, Pr, Nd, and Sm. Organometallics 2005, 24 (16) , 3916-3931. https://doi.org/10.1021/om050402l
    26. William J. Evans,, Timothy M. Champagne,, Dimitrios G. Giarikos, and, Joseph W. Ziller. Lanthanide Metallocene Reactivity with Dialkyl Aluminum Chlorides:  Modeling Reactions Used to Generate Isoprene Polymerization Catalysts. Organometallics 2005, 24 (4) , 570-579. https://doi.org/10.1021/om049484o
    27. Thomas M. Cameron,, John C. Gordon, and, Brian L. Scott. Synthesis and Characterization of (Mono)pentamethylcyclopentadienyl Lutetium Complexes:  Formation of Bipyridyl-Stabilized Alkyls, Anilides, and Terminal Acetylides. Organometallics 2004, 23 (12) , 2995-3002. https://doi.org/10.1021/om0497700
    28. Masayoshi Nishiura,, Zhaomin Hou, and, Yasuo Wakatsuki. A Novel Binuclear Samarium(II) Complex Bearing Mixed Cyclopentadienide/Siloxide Ligands:  [(C5Me5)Sm{μ-OSi(OtBu)3}3Sm]. Synthesis, Structure, Electron-Transfer, and Unusual Metal-Coordination Reactions. Organometallics 2004, 23 (6) , 1359-1368. https://doi.org/10.1021/om0343418
    29. Garth R. Giesbrecht,, John C. Gordon,, David L. Clark, and, Brian L. Scott. Auto-ionization in Lutetium Iodide Complexes:  Effect of the Ionic Radius on Lanthanide−Iodide Binding. Inorganic Chemistry 2004, 43 (3) , 1065-1070. https://doi.org/10.1021/ic035090y
    30. William J. Evans,, Jeremy M. Perotti,, Jason C. Brady, and, Joseph W. Ziller. Tethered Olefin Studies of Alkene versus Tetraphenylborate Coordination and Lanthanide Olefin Interactions in Metallocenes. Journal of the American Chemical Society 2003, 125 (17) , 5204-5212. https://doi.org/10.1021/ja020957x
    31. William J. Evans and, Benjamin L. Davis. Chemistry of Tris(pentamethylcyclopentadienyl) f-Element Complexes, (C5Me5)3M. Chemical Reviews 2002, 102 (6) , 2119-2136. https://doi.org/10.1021/cr010298r
    32. William J. Evans,, Gregory W. Nyce,, Kevin J. Forrestal, and, Joseph W. Ziller. Multiple Syntheses of (C5Me5)3U. Organometallics 2002, 21 (6) , 1050-1055. https://doi.org/10.1021/om010831t
    33. Xi-geng Zhou,, Li-bei Zhang,, Ming Zhu,, Rui-fang Cai, and, Lin-hong Weng, , Zi-xiang Huang and, Qiang-jin Wu. Insertion Reaction of Phenyl Isocyanate into the Ln−C σ-Bond of Organolanthanide Complexes:  Synthesis, Characterization, and Crystal Structures of {(C5H4CH3)2Ln[μ-η1:η3-OC(R)NPh]}2 (Ln = Sm, Dy, Er, Ho; R = n-butyl, α-naphthyl). Organometallics 2001, 20 (26) , 5700-5706. https://doi.org/10.1021/om010346y
    34. Sophie M. Cendrowski-Guillaume,, Gildas Le Gland,, Martine Nierlich, and, Michel Ephritikhine. Lanthanide Borohydrides as Precursors to Organometallic Compounds. Mono(cyclooctatetraenyl) Neodymium Complexes. Organometallics 2000, 19 (26) , 5654-5660. https://doi.org/10.1021/om000558f
    35. Guanyang Lin,, Robert McDonald, and, Josef Takats. Steric Control of Lanthanide Coordination Environment:  (TpMe2)2Sm(C⋮CPh), a Monomeric, Base-Free Lanthanide Alkynide Complex, and Its Thermally Induced Transformation to (TpMe2){HB(Me2pz)2(C⋮CPh)}Sm(Me2pz). Organometallics 2000, 19 (10) , 1814-1816. https://doi.org/10.1021/om9906518
    36. Gary A. Molander and, Robert M. Rzasa. Hetero Diels−Alder Reactions Catalyzed by the Metallocenium Complex [Cp*2Ce][BPh4]. The Journal of Organic Chemistry 2000, 65 (4) , 1215-1217. https://doi.org/10.1021/jo9909195
    37. Elisa Campazzi,, Euro Solari,, Rosario Scopelliti, and, Carlo Floriani. Cyclopentadienyl Behavior of Pyrrolyl Anions within the meso-Octaethylporphyrinogen-Binding Lanthanides:  Carbon−Hydrogen and Metal−Carbon Bond Rearrangements. Inorganic Chemistry 1999, 38 (26) , 6240-6245. https://doi.org/10.1021/ic990742x
    38. William J. Evans,, Kevin J. Forrestal, and, Joseph W. Ziller. Reaction Chemistry of Sterically Crowded Tris(pentamethylcyclopentadienyl)samarium1. Journal of the American Chemical Society 1998, 120 (36) , 9273-9282. https://doi.org/10.1021/ja9809859
    39. William J. Evans,, Christopher A. Seibel, and, Joseph W. Ziller. Unsolvated Lanthanide Metallocene Cations [(C5Me5)2Ln][BPh4]:  Multiple Syntheses, Structural Characterization, and Reactivity Including the Formation of (C5Me5)3Nd1. Journal of the American Chemical Society 1998, 120 (27) , 6745-6752. https://doi.org/10.1021/ja980534o
    40. Sophie M. Cendrowski-Guillaume,, Martine Nierlich,, Monique Lance, and, Michel Ephritikhine. First Chemical Transformations of Lanthanide Borohydride Compounds:  Synthesis and Crystal Structures of [(η-C8H8)Nd(BH4)(THF)]2 and [(η-C8H8)Nd(THF)4][BPh4]. Organometallics 1998, 17 (5) , 786-788. https://doi.org/10.1021/om9709446
    41. Xuejing Song,, Mark Thornton-Pett, and, Manfred Bochmann. Synthesis, Structure, and Reactivity of (C5H4SiMe3)2Y{(μ-FC6F4)(μ-Me)B(C6F5)2}:  Tight Ion Pairing in a Cationic Lanthanide Complex. Organometallics 1998, 17 (6) , 1004-1006. https://doi.org/10.1021/om971044s
    42. Robbert Duchateau,, Edward A. C. Brussee,, Auke Meetsma, and, Jan H. Teuben. Synthesis and Reactivity of Bis(alkoxysilylamido)yttrium η2-Pyridyl and η2-α-Picolyl Compounds. Organometallics 1997, 16 (25) , 5506-5516. https://doi.org/10.1021/om970540d
    43. Christopher G. Pernin and, James A. Ibers. The New Octanuclear Europium Cluster Eu8(DMF)13(μ4-O)(μ3-OH)12(Se3)(Se4)2(Se5)2 Comprising Oxo, Hydroxo, and Polyselenido Ligands. Inorganic Chemistry 1997, 36 (18) , 3802-3803. https://doi.org/10.1021/ic970379z
    44. Robbert Duchateau,, Cornelis T. van Wee, and, Jan H. Teuben. Insertion and C−H Bond Activation of Unsaturated Substrates by Bis(benzamidinato)yttrium Alkyl, [PhC(NSiMe3)2]2YR (R = CH2Ph·THF, CH(SiMe3)2), and Hydrido, {[PhC(NSiMe3)2]2Y(μ-H)}2, Compounds. Organometallics 1996, 15 (9) , 2291-2302. https://doi.org/10.1021/om9508142
    45. Larry R. Avens,, David M. Barnhart,, Carol J. Burns, and, Steven D. McKee. Uranium-Mediated Ring Opening of Tetrahydrofuran. Crystal Structure of UI2(OCH2CH2CH2CH2I)2(Ph3PO)2. Inorganic Chemistry 1996, 35 (2) , 537-539. https://doi.org/10.1021/ic9505211
    46. David J. Evans, Zhifang Guo, Glen B. Deacon, Peter C. Junk. Synthesis of cationic lanthanoid tetraphenylborate crown ether complexes. Journal of Organometallic Chemistry 2024, 1013 , 123186. https://doi.org/10.1016/j.jorganchem.2024.123186
    47. David J. Evans, Zhifang Guo, Glen Deacon, Peter Junk. Synthesis of Cationic Lanthanoid Tetraphenylborate Crown Ether Complexes. 2024https://doi.org/10.2139/ssrn.4809388
    48. Sebastian Schäfer, Sebastian Kaufmann, Esther S. Rösch, Peter W. Roesky. Divalent metallocenes of the lanthanides – a guideline to properties and reactivity. Chemical Society Reviews 2023, 52 (12) , 4006-4045. https://doi.org/10.1039/D2CS00744D
    49. Si‐Jun Xie, Yun‐Shu Cui, Yi‐Fei Huang, Feng Liu, Dan‐Dan Zhai, Zhang‐Jie Shi. Mechanistic Studies on Programmed C―O/C―H Activation with Valence‐Adjusted Ti‐Complexes. Chinese Journal of Chemistry 2023, 41 (9) , 1015-1022. https://doi.org/10.1002/cjoc.202200793
    50. Miaomiao Zhu, Tianyu Li, Zhengqi Chai, Junnian Wei, Ze-Jie Lv, Wen-Xiong Zhang. Diversified two-electron reduction for trivalent scandium complexes with arene ligands. Inorganic Chemistry Frontiers 2023, 10 (2) , 630-637. https://doi.org/10.1039/D2QI02123D
    51. Wen Jiang, Lijun Zhang, Lixin Zhang. Reactivity of a mixed methyl–aminobenzyl guanidinate lutetium complex towards i PrNCN i Pr, CS 2 and Ph 2 PH. Dalton Transactions 2022, 51 (33) , 12650-12660. https://doi.org/10.1039/D2DT02008D
    52. Florian Benner, Francis Delano, Elizabeth R Pugliese, Selvan Demir. Cyclopentadienyls and Phospholyls of the Group 3 Metals and Lanthanides. 2022, 98-184. https://doi.org/10.1016/B978-0-12-820206-7.00064-0
    53. Song Xu, Laura A. Essex, Joseph Q. Nguyen, Phillip Farias, Joseph W. Ziller, W. Hill Harman, William J. Evans. Cooperative dinitrogen capture by a diboraanthracene/samarocene pair. Dalton Transactions 2021, 50 (42) , 15000-15002. https://doi.org/10.1039/D1DT03220H
    54. Martin Bonath, Verena M. Birkelbach, Christoph Stuhl, Cäcilia Maichle-Mössmer, Reiner Anwander. Rare-earth-metallocene alkylaluminates trigger distinct tetrahydrofuran activation. Chemical Communications 2021, 57 (64) , 7918-7921. https://doi.org/10.1039/D1CC03024H
    55. Zhijun Feng, Zeming Huang, Shaowu Wang, Yun Wei, Shuangliu Zhou, Xiancui Zhu. Synthesis and characterization of 2- t -butylimino-functionalized indolyl rare-earth metal amido complexes for the catalytic addition of terminal alkynes to carbodiimides: the dimeric complexes with the alkynide species in the μ–η 1 :η 2 bonding modes. Dalton Transactions 2019, 48 (29) , 11094-11102. https://doi.org/10.1039/C9DT01582E
    56. Fangjun Zhang, Weiyin Yi, Jie Zhang, Qing You, Linhong Weng, Xigeng Zhou. Oxidation and chalcogenylative disproportionation of anionic phosphide ligands in yttrium complexes with elemental sulfur and selenium. Dalton Transactions 2019, 48 (28) , 10596-10603. https://doi.org/10.1039/C9DT01537J
    57. Daniel Werner, Xuefei Zhao, Stephen P. Best, Laurent Maron, Peter C. Junk, Glen B. Deacon. Bulky Ytterbium Formamidinates Stabilise Complexes with Radical Ligands, and Related Samarium “Tetracyclone” Chemistry. Chemistry – A European Journal 2017, 23 (9) , 2084-2102. https://doi.org/10.1002/chem.201604203
    58. Alexander F. R. Kilpatrick, F. Geoffrey N. Cloke. A base-free synthetic route to anti-bimetallic lanthanide pentalene complexes. Dalton Transactions 2017, 46 (17) , 5587-5597. https://doi.org/10.1039/C6DT04475A
    59. Jordan F. Corbey, David H. Woen, Joseph W. Ziller, William J. Evans. Synthesis and structure of nitrile-solvated rare earth metallocene cations [Cp2Ln(NCR)3][BPh4] (Cp = C5Me5, C5H4SiMe3; R = Me, Bu, Ph). Polyhedron 2016, 103 , 44-50. https://doi.org/10.1016/j.poly.2015.09.002
    60. Christoph Schoo, Sebastian Bestgen, Monika Schmidt, Sergey N. Konchenko, Manfred Scheer, Peter W. Roesky. Sterically induced reductive linkage of iron polypnictides with bulky lanthanide complexes by ring-opening of THF. Chemical Communications 2016, 52 (90) , 13217-13220. https://doi.org/10.1039/C6CC07367K
    61. Yu‐Chang Chang, Chia‐Ming Weng, Tanveer M. Shaikh, Fung‐E Hong. Magnesium Halide‐promoted Ring‐opening Reaction of Cyclic Ether in the Presence of Phosphine Halide. Journal of the Chinese Chemical Society 2015, 62 (8) , 703-711. https://doi.org/10.1002/jccs.201500154
    62. Zhanghai Gu, Li Li, Qianwen Bao, Fugen Yuan. Lanthanocene Diolate Complexes: Synthesis, Structures and Catalytic Property for ε ‐Caprolactone Polymerization. Chinese Journal of Chemistry 2015, 33 (5) , 563-567. https://doi.org/10.1002/cjoc.201400826
    63. Jianfeng Li, Jingjun Hao, Chunming Cui. Reactivity of ytterbium( ii ) silylamide supported by a pyrrolyl–cyclopentadienyl ligand. Dalton Transactions 2015, 44 (2) , 767-772. https://doi.org/10.1039/C4DT03008G
    64. Heather A. Spinney, Christopher R. Clough, Christopher C. Cummins. The titanium tris-anilide cation [Ti(N[ t Bu]Ar) 3 ] + stabilized as its perfluoro-tetra-phenylborate salt: structural characterization and synthesis in connection with redox activity of 4,4′-bipyridine dititanium complexes. Dalton Transactions 2015, 44 (15) , 6784-6796. https://doi.org/10.1039/C5DT00105F
    65. Anja Nieland, Jan‐Hendrik Lamm, Andreas Mix, Beate Neumann, Hans‐Georg Stammler, Norbert W. Mitzel. Alkynyl Compounds of the Rare‐earth Metals. Zeitschrift für anorganische und allgemeine Chemie 2014, 640 (12-13) , 2484-2491. https://doi.org/10.1002/zaac.201400158
    66. Ravikumar R. Gowda, Eugene Y.‐X. Chen. Sustainable Polymers from Biomass‐Derived α‐Methylene‐γ‐Butyrolactones. 2013https://doi.org/10.1002/0471440264.pst606
    67. Anja Nieland, Andreas Mix, Beate Neumann, Hans‐Georg Stammler, Norbert W. Mitzel. Rare‐Earth‐Metal Dialkynyl Dimethyl Aluminates. Chemistry – A European Journal 2013, 19 (25) , 8268-8275. https://doi.org/10.1002/chem.201300465
    68. Ruiting Liu, Xigeng Zhou. Selective transformations of cyclopentadienyl ligands of transition-metal and rare-earth metal complexes. Chemical Communications 2013, 49 (31) , 3171. https://doi.org/10.1039/c2cc35637f
    69. Michael K. Takase, Joseph W. Ziller, William J. Evans. The Importance of a Single Methyl Group in Determining the Reaction Chemistry of Pentamethylcyclopentadienyl Cyclooctatetraenyl Uranium Metallocenes. Chemistry – A European Journal 2011, 17 (17) , 4871-4878. https://doi.org/10.1002/chem.201002857
    70. Selvan Demir, Thomas J. Mueller, Joseph W. Ziller, William J. Evans. Tris(polyalkylcyclopentadienyl) Complexes: The Elusive [(η 5 ‐C 5 R 5 ) 2 M(η 1 ‐C 5 R 5 )] Structure and Trihapto Cyclopentadienyl Coordination Involving a Methyl Substituent. Angewandte Chemie 2011, 123 (2) , 535-538. https://doi.org/10.1002/ange.201005898
    71. Selvan Demir, Thomas J. Mueller, Joseph W. Ziller, William J. Evans. Tris(polyalkylcyclopentadienyl) Complexes: The Elusive [(η 5 ‐C 5 R 5 ) 2 M(η 1 ‐C 5 R 5 )] Structure and Trihapto Cyclopentadienyl Coordination Involving a Methyl Substituent. Angewandte Chemie International Edition 2011, 50 (2) , 515-518. https://doi.org/10.1002/anie.201005898
    72. Yunjie LUO, Xiaoying FENG. Synthesis and crystal structure of [Y(C5Me4SiMe3){μ-O(CH2)3CH3}{N(SiHMe2)2}]2. Journal of Rare Earths 2011, 29 (1) , 24-27. https://doi.org/10.1016/S1002-0721(10)60400-0
    73. Yan Sun, Zhengxing Zhang, Xu Wang, Xiaoqing Li, Linhong Weng, Xigeng Zhou. Isocyanate diinsertion into the N–H bond of the 2-pyridylamino ligand of organolanthanides. Dalton Trans. 2010, 39 (1) , 221-226. https://doi.org/10.1039/B918181D
    74. Garret M. Miyake, Stacie E. Newton, Wesley R. Mariott, Eugene Y.-X. Chen. Coordination polymerization of renewable butyrolactone-based vinyl monomers by lanthanide and early metal catalysts. Dalton Transactions 2010, 39 (29) , 6710. https://doi.org/10.1039/c001909g
    75. Abhilasha Verma, Marites Guino‐o, Miriam Gillett‐Kunnath, Weijie Teng, Karin Ruhlandt‐Senge. Ion Association Trends in Alkaline Earth‐Metal Tetraphenylborates. Zeitschrift für anorganische und allgemeine Chemie 2009, 635 (6-7) , 903-913. https://doi.org/10.1002/zaac.200900081
    76. Fanny Bonnet, Cristina Da Costa Violante, Pascal Roussel, André Mortreux, Marc Visseaux. Unprecedented dual behaviour of a half-sandwich scandium-based initiator for both highly selective isoprene and styrene polymerisation. Chemical Communications 2009, 103 (23) , 3380. https://doi.org/10.1039/b903403j
    77. Igor L. Fedushkin, Anton N. Lukoyanov, Markus Hummert, Herbert Schumann. C‐O Bond Cleavage of Diethyl Ether and Tetrahydrofurane by [(dpp‐BIAN)AlI(Et 2 O)] [dpp‐BIAN = 1,2‐bis[(2,6‐di‐iso‐propylphenyl)‐imino]acenaphthene]. Zeitschrift für anorganische und allgemeine Chemie 2008, 634 (2) , 357-361. https://doi.org/10.1002/zaac.200700411
    78. Marcus L. Cole, Glen B. Deacon, Craig M. Forsyth, Peter C. Junk, Kristina Konstas, Jun Wang. Steric Modulation of Coordination Number and Reactivity in the Synthesis of Lanthanoid(III) Formamidinates. Chemistry – A European Journal 2007, 13 (29) , 8092-8110. https://doi.org/10.1002/chem.200700963
    79. Ruiting Liu, Xigeng Zhou. Reactivity of the metal–cyclopentadienyl (indenyl, fluorenyl and cycloheptatrienyl) bonds. Journal of Organometallic Chemistry 2007, 692 (21) , 4424-4435. https://doi.org/10.1016/j.jorganchem.2007.05.033
    80. Glen B. Deacon, David J. Evans, Craig M. Forsyth, Peter C. Junk. Lanthanoid(II) tetraphenylborate complexes: From discrete ions to pseudo metallocenes. Coordination Chemistry Reviews 2007, 251 (13-14) , 1699-1706. https://doi.org/10.1016/j.ccr.2006.11.005
    81. Hong-Ting Sheng, Hui Zhou, Hua-Dong Guo, Hong-Mei Sun, Ying-Ming Yao, Jun-Feng Wang, Yong Zhang, Qi Shen. Synthesis and molecular structure of the cationic samarium phenoxide complex [(ArO)2Sm(DME)2][BPh4]·THF and its catalytic activity for the polymerization of ε-caprolactone. Journal of Organometallic Chemistry 2007, 692 (5) , 1118-1124. https://doi.org/10.1016/j.jorganchem.2006.11.013
    82. Marc D. Walter, Dirk Bentz, Frank Weber, Oliver Schmitt, Gotthelf Wolmershäuser, Helmut Sitzmann. Cation size dependent reactivity of lanthanide trihalides with bulky alkylcyclopentadienyl anions. New J. Chem. 2007, 31 (2) , 305-318. https://doi.org/10.1039/B603701A
    83. Ewan E. Delbridge, Divine T. Dugah, Chassidy R. Nelson, Brian W. Skelton, Allan H. White. Synthesis, structure and oxidation of new ytterbium( ii ) bis(phenolate) compounds and their catalytic activity towards ε-caprolactone. Dalton Trans. 2007, 47 (1) , 143-153. https://doi.org/10.1039/B613409B
    84. Stephen T. Liddle, Polly L. Arnold. Synthesis and characterisation of yttrium complexes supported by the β-diketiminate ligand {ArNC(CH3)CHC(CH3)NAr}– (Ar = 2,6-Pri2C6H3). Dalton Transactions 2007, 347 (30) , 3305. https://doi.org/10.1039/b706971e
    85. Robert A. Flowers, Edamana Prasad. Chapter 230 Samarium (II) based reductants. 2006, 393-473. https://doi.org/10.1016/S0168-1273(06)36004-7
    86. Glen B. Deacon, Gary D. Fallon, Craig M. Forsyth, Stuart C. Harris, Peter C. Junk, Brian W. Skelton, Allan H. White. Manipulation of reaction pathways in redox transmetallation–ligand exchange syntheses of lanthanoid( ii )/( iii ) aryloxide complexes. Dalton Trans. 2006, 122 (6) , 802-812. https://doi.org/10.1039/B511609K
    87. Stefan Arndt, Klaus Beckerle, Peter M. Zeimentz, Thomas P. Spaniol, Jun Okuda. Kationische Yttrium‐Methyl‐Komplexe als funktionale Modelle für Katalysatoren zur Polymerisation von 1,3‐Dienen. Angewandte Chemie 2005, 117 (45) , 7640-7644. https://doi.org/10.1002/ange.200502915
    88. Stefan Arndt, Klaus Beckerle, Peter M. Zeimentz, Thomas P. Spaniol, Jun Okuda. Cationic Yttrium Methyl Complexes as Functional Models for Polymerization Catalysts of 1,3‐Dienes. Angewandte Chemie International Edition 2005, 44 (45) , 7473-7477. https://doi.org/10.1002/anie.200502915
    89. Hiroyuki Kawaguchi, Tsukasa Matsuo. Complexes of tantalum with triaryloxides: Ligand and solvent effects on formation of hydride derivatives. Journal of Organometallic Chemistry 2005, 690 (23) , 5333-5345. https://doi.org/10.1016/j.jorganchem.2005.05.002
    90. William J Evans, David S Lee. Early developments in lanthanide-based dinitrogen reduction chemistry. Canadian Journal of Chemistry 2005, 83 (4) , 375-384. https://doi.org/10.1139/v05-014
    91. Stefan Arndt, Jun Okuda. Cationic Alkyl Complexes of the Rare‐Earth Metals: Synthesis, Structure, and Reactivity. Advanced Synthesis & Catalysis 2005, 347 (2-3) , 339-354. https://doi.org/10.1002/adsc.200404269
    92. Marcus L. Cole, Glen B. Deacon, Peter C. Junk, Kristina Konstas. Steric engineering of C–F activation with lanthanoid formamidinates. Chem. Commun. 2005, 94 (12) , 1581-1583. https://doi.org/10.1039/B419047E
    93. Sergey M. Dibrov, James A. Ibers. [TeSe3]2– as a tridentate ligand: syntheses and crystal structures of [PPh4][(CpM(μ2–Se2))3(μ3–O)(μ3–TeSe3)] (M = Zr, Hf). Comptes Rendus. Chimie 2005, 8 (6-7) , 993-997. https://doi.org/10.1016/j.crci.2004.10.028
    94. Glen B. Deacon, Craig M. Forsyth. Synthesis and Structures of the First Cationic Perfluoroaryllanthanoid( II ) Complexes. Chemistry – A European Journal 2004, 10 (7) , 1798-1804. https://doi.org/10.1002/chem.200306010
    95. Kurt Dehnicke, Andreas Greiner. Ungewöhnliche Komplexchemie der Seltenerdelemente: große Ionenradien – kleine Koordinationszahlen. Angewandte Chemie 2003, 115 (12) , 1378-1392. https://doi.org/10.1002/ange.200390318
    96. Kurt Dehnicke, Andreas Greiner. Unusual Complex Chemistry of Rare‐Earth Elements: Large Ionic Radii—Small Coordination Numbers. Angewandte Chemie International Edition 2003, 42 (12) , 1340-1354. https://doi.org/10.1002/anie.200390346
    97. Grigori B. Nikiforov, Herbert W. Roesky, Thomas Labahn, Denis Vidovic, Dante Neculai. Synthesis and Structure of the First Holmium and Erbium Diiodide Complexes of Composition LLnI 2 (Ln = Ho, Er). European Journal of Inorganic Chemistry 2003, 2003 (3) , 433-436. https://doi.org/10.1002/ejic.200390060
    98. William J. Evans, Matthew A. Johnston, Michael A. Greci, Tammy S. Gummersheimer, Joseph W. Ziller. Divalent lanthanide complexes free of coordinating anions: facile synthesis of fully solvated dicationic [LnLx]2+ compounds. Polyhedron 2003, 22 (1) , 119-126. https://doi.org/10.1016/S0277-5387(02)01257-3
    99. Sophie M. Cendrowski-Guillaume, Gildas Le Gland, Monique Lance, Martine Nierlich, Michel Ephritikhine. Neodymium and uranium borohydride complexes, precursors to cationic derivatives: comparison of 4f and 5f element complexes. Comptes Rendus. Chimie 2002, 5 (2) , 73-80. https://doi.org/10.1016/S1631-0748(02)01325-5
    100. Guanyang Lin, Robert McDonald, Josef Takats. Synthesis and structure of [Sm(η5-CpPPh2)(κ3-TpMe2)(I)(THF)]; a samarium complex with four different ligands. Journal of Organometallic Chemistry 2001, 626 (1-2) , 76-81. https://doi.org/10.1016/S0022-328X(01)00660-X
    Load all citations