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Synthesis and reactivity of the cationic organosamarium(III) complex [(C5Me5)2Sm(THF)2][BPh4], including the synthesis and structure of a metallocene with an alkoxy-tethered C5Me5 ring, (C5Me5)2Sm[O(CH2)4C5Me5](THF)

Cite this: Organometallics 1990, 9, 7, 2124–2130
Publication Date (Print):July 1, 1990
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    14. Thomas J. Mueller, Gregory W. Nyce, and William J. Evans . Defining Reactivity Differences in Sterically Crowded (η5-C5Me5)3M Complexes Based on Metal Size and Lanthanide vs Actinide Effects. Organometallics 2011, 30 (5) , 1231-1235.
    15. Kuburat O. Saliu, Jianhua Cheng, Robert McDonald, Michael J. Ferguson, and Josef Takats. Reactions of Scorpionate-Anchored Yttrium and Lutetium Dialkyls with Terminal Alkynes: From Bimetallic Complexes with Bridging Enynediyl Ligands to Monomeric Terminal Dialkynyl Complexes. Organometallics 2010, 29 (21) , 4950-4965.
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    64. Heather A. Spinney, Christopher R. Clough, Christopher C. Cummins. The titanium tris-anilide cation [Ti(N[ t Bu]Ar) 3 ] + stabilized as its perfluoro-tetra-phenylborate salt: structural characterization and synthesis in connection with redox activity of 4,4′-bipyridine dititanium complexes. Dalton Transactions 2015, 44 (15) , 6784-6796.
    65. Anja Nieland, Jan‐Hendrik Lamm, Andreas Mix, Beate Neumann, Hans‐Georg Stammler, Norbert W. Mitzel. Alkynyl Compounds of the Rare‐earth Metals. Zeitschrift für anorganische und allgemeine Chemie 2014, 640 (12-13) , 2484-2491.
    66. Ravikumar R. Gowda, Eugene Y.‐X. Chen. Sustainable Polymers from Biomass‐Derived α‐Methylene‐γ‐Butyrolactones. 2013
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    68. Ruiting Liu, Xigeng Zhou. Selective transformations of cyclopentadienyl ligands of transition-metal and rare-earth metal complexes. Chemical Communications 2013, 49 (31) , 3171.
    69. Michael K. Takase, Joseph W. Ziller, William J. Evans. The Importance of a Single Methyl Group in Determining the Reaction Chemistry of Pentamethylcyclopentadienyl Cyclooctatetraenyl Uranium Metallocenes. Chemistry – A European Journal 2011, 17 (17) , 4871-4878.
    70. Selvan Demir, Thomas J. Mueller, Joseph W. Ziller, William J. Evans. Tris(polyalkylcyclopentadienyl) Complexes: The Elusive [(η 5 ‐C 5 R 5 ) 2 M(η 1 ‐C 5 R 5 )] Structure and Trihapto Cyclopentadienyl Coordination Involving a Methyl Substituent. Angewandte Chemie 2011, 123 (2) , 535-538.
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    72. Yunjie LUO, Xiaoying FENG. Synthesis and crystal structure of [Y(C5Me4SiMe3){μ-O(CH2)3CH3}{N(SiHMe2)2}]2. Journal of Rare Earths 2011, 29 (1) , 24-27.
    73. Yan Sun, Zhengxing Zhang, Xu Wang, Xiaoqing Li, Linhong Weng, Xigeng Zhou. Isocyanate diinsertion into the N–H bond of the 2-pyridylamino ligand of organolanthanides. Dalton Trans. 2010, 39 (1) , 221-226.
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    78. Marcus L. Cole, Glen B. Deacon, Craig M. Forsyth, Peter C. Junk, Kristina Konstas, Jun Wang. Steric Modulation of Coordination Number and Reactivity in the Synthesis of Lanthanoid(III) Formamidinates. Chemistry – A European Journal 2007, 13 (29) , 8092-8110.
    79. Ruiting Liu, Xigeng Zhou. Reactivity of the metal–cyclopentadienyl (indenyl, fluorenyl and cycloheptatrienyl) bonds. Journal of Organometallic Chemistry 2007, 692 (21) , 4424-4435.
    80. Glen B. Deacon, David J. Evans, Craig M. Forsyth, Peter C. Junk. Lanthanoid(II) tetraphenylborate complexes: From discrete ions to pseudo metallocenes. Coordination Chemistry Reviews 2007, 251 (13-14) , 1699-1706.
    81. Hong-Ting Sheng, Hui Zhou, Hua-Dong Guo, Hong-Mei Sun, Ying-Ming Yao, Jun-Feng Wang, Yong Zhang, Qi Shen. Synthesis and molecular structure of the cationic samarium phenoxide complex [(ArO)2Sm(DME)2][BPh4]·THF and its catalytic activity for the polymerization of ε-caprolactone. Journal of Organometallic Chemistry 2007, 692 (5) , 1118-1124.
    82. Marc D. Walter, Dirk Bentz, Frank Weber, Oliver Schmitt, Gotthelf Wolmershäuser, Helmut Sitzmann. Cation size dependent reactivity of lanthanide trihalides with bulky alkylcyclopentadienyl anions. New J. Chem. 2007, 31 (2) , 305-318.
    83. Ewan E. Delbridge, Divine T. Dugah, Chassidy R. Nelson, Brian W. Skelton, Allan H. White. Synthesis, structure and oxidation of new ytterbium( ii ) bis(phenolate) compounds and their catalytic activity towards ε-caprolactone. Dalton Trans. 2007, 47 (1) , 143-153.
    84. Stephen T. Liddle, Polly L. Arnold. Synthesis and characterisation of yttrium complexes supported by the β-diketiminate ligand {ArNC(CH3)CHC(CH3)NAr}– (Ar = 2,6-Pri2C6H3). Dalton Transactions 2007, 347 (30) , 3305.
    85. Robert A. Flowers, Edamana Prasad. Chapter 230 Samarium (II) based reductants. 2006, 393-473.
    86. Glen B. Deacon, Gary D. Fallon, Craig M. Forsyth, Stuart C. Harris, Peter C. Junk, Brian W. Skelton, Allan H. White. Manipulation of reaction pathways in redox transmetallation–ligand exchange syntheses of lanthanoid( ii )/( iii ) aryloxide complexes. Dalton Trans. 2006, 122 (6) , 802-812.
    87. Stefan Arndt, Klaus Beckerle, Peter M. Zeimentz, Thomas P. Spaniol, Jun Okuda. Kationische Yttrium‐Methyl‐Komplexe als funktionale Modelle für Katalysatoren zur Polymerisation von 1,3‐Dienen. Angewandte Chemie 2005, 117 (45) , 7640-7644.
    88. Stefan Arndt, Klaus Beckerle, Peter M. Zeimentz, Thomas P. Spaniol, Jun Okuda. Cationic Yttrium Methyl Complexes as Functional Models for Polymerization Catalysts of 1,3‐Dienes. Angewandte Chemie International Edition 2005, 44 (45) , 7473-7477.
    89. Hiroyuki Kawaguchi, Tsukasa Matsuo. Complexes of tantalum with triaryloxides: Ligand and solvent effects on formation of hydride derivatives. Journal of Organometallic Chemistry 2005, 690 (23) , 5333-5345.
    90. William J Evans, David S Lee. Early developments in lanthanide-based dinitrogen reduction chemistry. Canadian Journal of Chemistry 2005, 83 (4) , 375-384.
    91. Stefan Arndt, Jun Okuda. Cationic Alkyl Complexes of the Rare‐Earth Metals: Synthesis, Structure, and Reactivity. Advanced Synthesis & Catalysis 2005, 347 (2-3) , 339-354.
    92. Marcus L. Cole, Glen B. Deacon, Peter C. Junk, Kristina Konstas. Steric engineering of C–F activation with lanthanoid formamidinates. Chem. Commun. 2005, 94 (12) , 1581-1583.
    93. Sergey M. Dibrov, James A. Ibers. [TeSe3]2– as a tridentate ligand: syntheses and crystal structures of [PPh4][(CpM(μ2–Se2))3(μ3–O)(μ3–TeSe3)] (M = Zr, Hf). Comptes Rendus. Chimie 2005, 8 (6-7) , 993-997.
    94. Glen B. Deacon, Craig M. Forsyth. Synthesis and Structures of the First Cationic Perfluoroaryllanthanoid( II ) Complexes. Chemistry – A European Journal 2004, 10 (7) , 1798-1804.
    95. Kurt Dehnicke, Andreas Greiner. Ungewöhnliche Komplexchemie der Seltenerdelemente: große Ionenradien – kleine Koordinationszahlen. Angewandte Chemie 2003, 115 (12) , 1378-1392.
    96. Kurt Dehnicke, Andreas Greiner. Unusual Complex Chemistry of Rare‐Earth Elements: Large Ionic Radii—Small Coordination Numbers. Angewandte Chemie International Edition 2003, 42 (12) , 1340-1354.
    97. Grigori B. Nikiforov, Herbert W. Roesky, Thomas Labahn, Denis Vidovic, Dante Neculai. Synthesis and Structure of the First Holmium and Erbium Diiodide Complexes of Composition LLnI 2 (Ln = Ho, Er). European Journal of Inorganic Chemistry 2003, 2003 (3) , 433-436.
    98. William J. Evans, Matthew A. Johnston, Michael A. Greci, Tammy S. Gummersheimer, Joseph W. Ziller. Divalent lanthanide complexes free of coordinating anions: facile synthesis of fully solvated dicationic [LnLx]2+ compounds. Polyhedron 2003, 22 (1) , 119-126.
    99. Sophie M. Cendrowski-Guillaume, Gildas Le Gland, Monique Lance, Martine Nierlich, Michel Ephritikhine. Neodymium and uranium borohydride complexes, precursors to cationic derivatives: comparison of 4f and 5f element complexes. Comptes Rendus. Chimie 2002, 5 (2) , 73-80.
    100. Guanyang Lin, Robert McDonald, Josef Takats. Synthesis and structure of [Sm(η5-CpPPh2)(κ3-TpMe2)(I)(THF)]; a samarium complex with four different ligands. Journal of Organometallic Chemistry 2001, 626 (1-2) , 76-81.
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