Heteronuclear Heavy Alkenes E
E‘ (E, E‘ = Group 14 Elements): Germasilenes, Silastannenes, Germastannenes...Next Stop?
Abstract

Recent advances in the chemistry of stable heteronuclear heavy alkenes >E
E‘< (E, E‘ = group 14 elements) are reviewed, covering silenes (>Si
C<), germenes (>Ge
C<), stannenes (>Sn
C<), germasilenes (>Ge
Si<), silastannenes (>Si
Sn<), and germastannenes (>Ge
Sn<). Their unique structures, bonding modes, and reactivities have been shown to be different from those of the homonuclear species, primarily due to the polarity of the >E
E‘< bond resulting from the difference in the electronegativities of the doubly bonded atoms.
*
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