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Disilenyllithium from Tetrasila-1,3-butadiene:  A Silicon Analogue of a Vinyllithium

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Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan
Cite this: Organometallics 2004, 23, 13, 3088–3090
Publication Date (Web):May 20, 2004
https://doi.org/10.1021/om040056s
Copyright © 2004 American Chemical Society
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Abstract

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The reaction of dilithiosilane, (tBu2MeSi)2SiLi2 (2), with 1,1,2,2-tetrachloro-1,2-dimesityldisilane produced the tetrasila-1,3-butadiene derivative (tBu2MeSi)2SiSi(Mes)(Mes)SiSi(SiMetBu2)2 (3; Mes = 2,4,6-trimethylphenyl) as reddish purple crystals. The reaction of 3 with tBuLi in THF produced 1,1-bis(di-tert-butylmethylsilyl)-2-lithio-2-mesityldisilene (4) as red crystals, which is an sp2-type silyllithium species, by the reductive cleavage of the central Si−Si bond in 3.

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Tables giving the details of the X-ray structure determination, thermal ellipsoid plots, fractional atomic coordinates, anisotropic thermal parameters, bond lengths, and bond angles for 3 and 4. This material is available free of charge via the Internet at http://pubs.acs.org.

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  3. Naohiko Akasaka, Kentaro Fujieda, Eleonora Garoni, Kenji Kamada, Hiroshi Matsui, Masayoshi Nakano, and Takeaki Iwamoto . Synthesis and Functionalization of a 1,4-Bis(trimethylsilyl)tetrasila-1,3-diene through the Selective Cleavage of Si(sp2)–Si(sp3) Bonds under Mild Reaction Conditions. Organometallics 2018, 37 (2) , 172-175. https://doi.org/10.1021/acs.organomet.7b00864
  4. Cem B. Yildiz and David Scheschkewitz . Reactivity of Heavier Vinyl Anions [(CH3)2E═E′(CH3)]− (E, E′ = C, Si, Ge) toward Carbon Monoxide: A Computational Study. Organometallics 2017, 36 (16) , 3035-3042. https://doi.org/10.1021/acs.organomet.7b00327
  5. Yu-Liang Shan, Bi-Xiang Leong, Yongxin Li, Rakesh Ganguly, and Cheuk-Wai So . Donor–Acceptor Stabilized Tetra(silanimine). Inorganic Chemistry 2017, 56 (3) , 1609-1615. https://doi.org/10.1021/acs.inorgchem.6b02727
  6. Tomoyuki Kosai, Shintaro Ishida, and Takeaki Iwamoto . Pentasila-1,4-diene: Homoconjugation between Si═Si Double Bonds via a SiMe2 Unit. Journal of the American Chemical Society 2017, 139 (1) , 99-102. https://doi.org/10.1021/jacs.6b11912
  7. Zhendong Wang, Jianying Zhang, Jianfeng Li, and Chunming Cui . NHC-Stabilized Silicon–Carbon Mixed Cumulene. Journal of the American Chemical Society 2016, 138 (33) , 10421-10424. https://doi.org/10.1021/jacs.6b06960
  8. Marius I. Arz, Martin Straßmann, Daniel Geiß, Gregor Schnakenburg, and Alexander C. Filippou . Addition of Small Electrophiles to N-Heterocyclic-Carbene-Stabilized Disilicon(0): A Revisit of the Isolobal Concept in Low-Valent Silicon Chemistry. Journal of the American Chemical Society 2016, 138 (13) , 4589-4600. https://doi.org/10.1021/jacs.6b01018
  9. Hiroshi Matsui, Kotaro Fukuda, Soichi Ito, Takanori Nagami, and Masayoshi Nakano . Open-Shell Singlet Nature and σ-/π-Conjugation Effects on the Third-Order Nonlinear Optical Properties of Si Chains: Polysilane and Poly(disilene-1,2-diyl). The Journal of Physical Chemistry A 2016, 120 (6) , 948-955. https://doi.org/10.1021/acs.jpca.5b11895
  10. Yuzhong Wang and Gregory H. Robinson . N-Heterocyclic Carbene—Main-Group Chemistry: A Rapidly Evolving Field. Inorganic Chemistry 2014, 53 (22) , 11815-11832. https://doi.org/10.1021/ic502231m
  11. Vladimir Ya. Lee, Shinji Aoki, Manami Kawai, Takahiko Meguro, and Akira Sekiguchi . Stibasilene Sb═Si and Its Lighter Homologues: A Comparative Study. Journal of the American Chemical Society 2014, 136 (17) , 6243-6246. https://doi.org/10.1021/ja5026084
  12. Antje Meltzer, Moumita Majumdar, Andrew J. P. White, Volker Huch, and David Scheschkewitz . Potential Protecting Group Strategy for Disila Analogues of Vinyllithiums: Synthesis and Reactivity of a 2,4,6-Trimethoxyphenyl-Substituted Disilene. Organometallics 2013, 32 (22) , 6844-6850. https://doi.org/10.1021/om400545w
  13. Lieby Zborovsky, Roman Dobrovetsky, Mark Botoshansky, Dmitry Bravo-Zhivotovskii, and Yitzhak Apeloig . Synthesis of Silenyllithiums Li(R′3Si)Si═C(SiR3)(1-Ad) via Transient Silyne–Silylidene Intermediates. Journal of the American Chemical Society 2012, 134 (44) , 18229-18232. https://doi.org/10.1021/ja308777v
  14. Sakya S. Sen, Shabana Khan, Selvarajan Nagendran, and Herbert W. Roesky . Interconnected Bis-Silylenes: A New Dimension in Organosilicon Chemistry. Accounts of Chemical Research 2012, 45 (4) , 578-587. https://doi.org/10.1021/ar2002073
  15. Katsuhiko Takeuchi, Masaaki Ichinohe, and Akira Sekiguchi . A New Disilene with π-Accepting Groups from the Reaction of Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]) with Isocyanides. Journal of the American Chemical Society 2012, 134 (6) , 2954-2957. https://doi.org/10.1021/ja212065a
  16. Vladimir Ya. Lee and Akira Sekiguchi . Novel Organometallic Reagents: Geminal Dianionic Derivatives of the Heavy Group 14 Elements. Inorganic Chemistry 2011, 50 (24) , 12303-12314. https://doi.org/10.1021/ic2006106
  17. Jonathan Jeck, Iulia Bejan, Andrew J. P. White, Dominik Nied, Frank Breher, and David Scheschkewitz . Transfer of a Disilenyl Moiety to Aromatic Substrates and Lateral Functional Group Transformation in Aryl Disilenes. Journal of the American Chemical Society 2010, 132 (48) , 17306-17315. https://doi.org/10.1021/ja107547s
  18. Roland C. Fischer and Philip P. Power . π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium. Chemical Reviews 2010, 110 (7) , 3877-3923. https://doi.org/10.1021/cr100133q
  19. Hiroaki Tanaka, Shigeyoshi Inoue, Masaaki Ichinohe and Akira Sekiguchi. An (η3-Disilaallyl)lithium Derivative: Interconversion of π-Allyl-Type Bonding and η1 Coordination to a Silyllithium Fragment. Organometallics 2009, 28 (23) , 6625-6628. https://doi.org/10.1021/om900861z
  20. Baolin Li, Tsukasa Matsuo, Daisuke Hashizume, Hiroyuki Fueno, Kazuyoshi Tanaka and Kohei Tamao. π-Conjugated Phosphasilenes Stabilized by Fused-Ring Bulky Groups. Journal of the American Chemical Society 2009, 131 (37) , 13222-13223. https://doi.org/10.1021/ja9051153
  21. Hiroyuki Yasuda, Vladimir Ya. Lee and Akira Sekiguchi. Si3C2-Rings: From a Nonconjugated Trisilacyclopentadiene to an Aromatic Trisilacyclopentadienide and Cyclic Disilenide. Journal of the American Chemical Society 2009, 131 (18) , 6352-6353. https://doi.org/10.1021/ja901881z
  22. Takeaki Iwamoto, Maiko Kobayashi, Kei Uchiyama, Shin Sasaki, Selvarajan Nagendran, Hiroyuki Isobe and Mitsuo Kira. Anthryl-Substituted Trialkyldisilene Showing Distinct Intramolecular Charge-Transfer Transition. Journal of the American Chemical Society 2009, 131 (9) , 3156-3157. https://doi.org/10.1021/ja8093313
  23. Young Mook Lim, Myong Euy Lee, Junseong Lee and Youngkyu Do . Reactivity of Bromodilithiosilane to Naphthalene and Anthracene. Organometallics 2008, 27 (23) , 6375-6378. https://doi.org/10.1021/om800596t
  24. Jun Hsiao and Ming-Der Su. A Quantum Mechanical Study of the Abstraction Reactions of Fused Bicyclic Dimetallenes. The Journal of Physical Chemistry A 2008, 112 (40) , 10064-10070. https://doi.org/10.1021/jp806086y
  25. Kai Abersfelder and, David Scheschkewitz. Syntheses of Trisila Analogues of Allyl Chlorides and Their Transformations to Chlorocyclotrisilanes, Cyclotrisilanides, and a Trisilaindane. Journal of the American Chemical Society 2008, 130 (12) , 4114-4121. https://doi.org/10.1021/ja711169w
  26. Aiko Fukazawa,, Yongming Li,, Shigehiro Yamaguchi,, Hayato Tsuji, and, Kohei Tamao. Coplanar Oligo(p-phenylenedisilenylene)s Based on the Octaethyl-Substituted s-Hydrindacenyl Groups. Journal of the American Chemical Society 2007, 129 (46) , 14164-14165. https://doi.org/10.1021/ja0764207
  27. Kei Uchiyama,, Selvarajan Nagendran,, Shintaro Ishida,, Takeaki Iwamoto, and, Mitsuo Kira. Thermal and Photochemical Cleavage of SiSi Double Bond in Tetrasila-1,3-diene. Journal of the American Chemical Society 2007, 129 (35) , 10638-10639. https://doi.org/10.1021/ja0741473
  28. Vladimir Ya. Lee and Akira Sekiguchi. Stable Silyl, Germyl, and Stannyl Cations, Radicals, and Anions: Heavy Versions of Carbocations, Carbon Radicals, and Carbanions. Accounts of Chemical Research 2007, 40 (6) , 410-419. https://doi.org/10.1021/ar6000473
  29. Thi-loan Nguyen and, David Scheschkewitz. Activation of a SiSi Bond by η-Coordination to a Transition Metal. Journal of the American Chemical Society 2005, 127 (29) , 10174-10175. https://doi.org/10.1021/ja052593p
  30. Paresh Kumar Majhi, Volker Huch, David Scheschkewitz. Ein gemischtes, schwereres Si=Ge Analogon eines Vinylanions. Angewandte Chemie 2021, 133 (1) , 246-250. https://doi.org/10.1002/ange.202009406
  31. Paresh Kumar Majhi, Volker Huch, David Scheschkewitz. A Mixed Heavier Si=Ge Analogue of a Vinyl Anion. Angewandte Chemie International Edition 2021, 60 (1) , 242-246. https://doi.org/10.1002/anie.202009406
  32. Lukas Klemmer, Yvonne Kaiser, Volker Huch, Michael Zimmer, David Scheschkewitz. Persistent Digermenes with Acyl and α‐Chlorosilyl Functionalities. Chemistry – A European Journal 2019, 25 (52) , 12187-12195. https://doi.org/10.1002/chem.201902553
  33. Lukas Klemmer, Volker Huch, Anukul Jana, David Scheschkewitz. An anionic heterosiliconoid with two germanium vertices. Chemical Communications 2019, 55 (68) , 10100-10103. https://doi.org/10.1039/C9CC04576G
  34. Daniel Pinchuk, Yosi Kratish, Jomon Mathew, Lieby Zborovsky, Dmitry Bravo‐Zhivotovskii, Boris Tumanskii, Yitzhak Apeloig. Generation and EPR Spectroscopy of the First Silenyl Radicals, R 2 C=Si . −R: Experiment and Theory. Angewandte Chemie 2019, 131 (22) , 7513-7517. https://doi.org/10.1002/ange.201901772
  35. Daniel Pinchuk, Yosi Kratish, Jomon Mathew, Lieby Zborovsky, Dmitry Bravo‐Zhivotovskii, Boris Tumanskii, Yitzhak Apeloig. Generation and EPR Spectroscopy of the First Silenyl Radicals, R 2 C=Si . −R: Experiment and Theory. Angewandte Chemie International Edition 2019, 58 (22) , 7435-7439. https://doi.org/10.1002/anie.201901772
  36. Ross F. Koby, Timothy P. Hanusa. Lithium, Sodium, Potassium, Rubidium, and Cesium. 2019,,https://doi.org/10.1016/B978-0-12-409547-2.14700-6
  37. . Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. 2019,,https://doi.org/
  38. Tsukasa Matsuo, Naoki Hayakawa. π-Electron systems containing Si=Si double bonds. Science and Technology of Advanced Materials 2018, 19 (1) , 108-129. https://doi.org/10.1080/14686996.2017.1414552
  39. Andreas Rammo, David Scheschkewitz. Functional Disilenes in Synthesis. Chemistry - A European Journal 2018, 24 (27) , 6866-6885. https://doi.org/10.1002/chem.201704090
  40. Naohiko Akasaka, Kaho Tanaka, Shintaro Ishida, Takeaki Iwamoto. Synthesis and Functionalization of a 1,2-Bis(trimethylsilyl)-1,2-disilacyclohexene That Can Serve as a Unit of cis-1,2-Dialkyldisilene. Inorganics 2018, 6 (1) , 21. https://doi.org/10.3390/inorganics6010021
  41. J. Teichmann, M. Wagner. Silicon chemistry in zero to three dimensions: from dichlorosilylene to silafullerane. Chemical Communications 2018, 54 (12) , 1397-1412. https://doi.org/10.1039/C7CC09063C
  42. Terrance J. Hadlington, Tibor Szilvási, Matthias Driess. Synthesis of a Metallo-Iminosilane via a Silanone-Metal π-Complex. Angewandte Chemie 2017, 129 (45) , 14470-14474. https://doi.org/10.1002/ange.201708923
  43. Terrance J. Hadlington, Tibor Szilvási, Matthias Driess. Synthesis of a Metallo-Iminosilane via a Silanone-Metal π-Complex. Angewandte Chemie International Edition 2017, 56 (45) , 14282-14286. https://doi.org/10.1002/anie.201708923
  44. Vitaly Nesterov, Nora C. Breit, Shigeyoshi Inoue. Advances in Phosphasilene Chemistry. Chemistry - A European Journal 2017, 23 (50) , 12014-12039. https://doi.org/10.1002/chem.201700829
  45. Yoshiyuki Mizuhata, Shiori Fujimori, Takahiro Sasamori, Norihiro Tokitoh. Germabenzenylpotassium: A Germanium Analogue of a Phenyl Anion. Angewandte Chemie 2017, 129 (16) , 4659-4663. https://doi.org/10.1002/ange.201700801
  46. Yoshiyuki Mizuhata, Shiori Fujimori, Takahiro Sasamori, Norihiro Tokitoh. Germabenzenylpotassium: A Germanium Analogue of a Phenyl Anion. Angewandte Chemie International Edition 2017, 56 (16) , 4588-4592. https://doi.org/10.1002/anie.201700801
  47. Christoph Marschner. Silicon-Centered Anions. 2017,,, 295-360. https://doi.org/10.1016/B978-0-12-801981-8.00007-1
  48. . Organosilicon Compounds. 2017,,https://doi.org/
  49. Antoine Baceiredo, Tsuyoshi Kato. Multiple Bonds to Silicon (Recent Advances in the Chemistry of Silicon Containing Multiple Bonds). 2017,,, 533-618. https://doi.org/10.1016/B978-0-12-801981-8.00009-5
  50. . Organosilicon Compounds. 2017,,https://doi.org/
  51. Tomoyuki Kosai, Shintaro Ishida, Takeaki Iwamoto. Heteroaryldisilenes: heteroaryl groups serve as electron acceptors for SiSi double bonds in intramolecular charge transfer transitions. Dalton Transactions 2017, 46 (34) , 11271-11281. https://doi.org/10.1039/C7DT02357J
  52. Daniel Pinchuk, Jomon Mathew, Alexander Kaushansky, Dmitry Bravo-Zhivotovskii, Yitzhak Apeloig. Isolation and Characterization, Including by X-ray Crystallography, of Contact and Solvent-Separated Ion Pairs of Silenyl Lithium Species. Angewandte Chemie 2016, 128 (35) , 10414-10418. https://doi.org/10.1002/ange.201603640
  53. Daniel Pinchuk, Jomon Mathew, Alexander Kaushansky, Dmitry Bravo-Zhivotovskii, Yitzhak Apeloig. Isolation and Characterization, Including by X-ray Crystallography, of Contact and Solvent-Separated Ion Pairs of Silenyl Lithium Species. Angewandte Chemie International Edition 2016, 55 (35) , 10258-10262. https://doi.org/10.1002/anie.201603640
  54. Michael Seidl, Gábor Balázs, Alexey Y. Timoshkin, Manfred Scheer. Stufenweise Bildung eines 1,3-Butadien-Analogons aus gemischten schwereren Elementen der Gruppe 15. Angewandte Chemie 2016, 128 (1) , 442-446. https://doi.org/10.1002/ange.201507355
  55. Michael Seidl, Gábor Balázs, Alexey Y. Timoshkin, Manfred Scheer. Stepwise Formation of a 1,3-Butadiene Analogue of Mixed Heavier Group 15 Elements. Angewandte Chemie International Edition 2016, 55 (1) , 431-435. https://doi.org/10.1002/anie.201507355
  56. Akihiro Tsurusaki, Soichiro Kyushin. The Radical Anion of Cyclopentasilane‐Fused Hexasilabenzvalene. Chemistry – A European Journal 2016, 22 (1) , 134-137. https://doi.org/10.1002/chem.201504449
  57. S.U. Ahmad, S. Inoue. Radicals, Anions, and Cations of Silicon and Silylenes. 2016,,, 27-72. https://doi.org/10.1016/B978-0-12-803530-6.00006-8
  58. . Efficient Methods for Preparing Silicon Compounds. 2016,,https://doi.org/
  59. Carsten Präsang, David Scheschkewitz. Reactivity in the periphery of functionalised multiple bonds of heavier group 14 elements. Chemical Society Reviews 2016, 45 (4) , 900-921. https://doi.org/10.1039/C5CS00720H
  60. Kai Abersfelder, Hui Zhao, Andrew J. P. White, Carsten Praesang, David Scheschkewitz. Synthesis of the First Homoleptic Trisilaallyl Chloride: ­3-Chloro-1, 1,2, 3,3-pentakis(2′,4′,6′-triisopropylphenyl)trisil-1-ene. Zeitschrift für anorganische und allgemeine Chemie 2015, 641 (12-13) , 2051-2055. https://doi.org/10.1002/zaac.201500561
  61. Hunter P. Hickox, Yuzhong Wang, Yaoming Xie, Mingwei Chen, Pingrong Wei, Henry F. Schaefer, Gregory H. Robinson. Transition-Metal-Mediated Cleavage of a SiSi Double Bond. Angewandte Chemie 2015, 127 (35) , 10405-10408. https://doi.org/10.1002/ange.201503069
  62. Hunter P. Hickox, Yuzhong Wang, Yaoming Xie, Mingwei Chen, Pingrong Wei, Henry F. Schaefer, Gregory H. Robinson. Transition-Metal-Mediated Cleavage of a SiSi Double Bond. Angewandte Chemie International Edition 2015, 54 (35) , 10267-10270. https://doi.org/10.1002/anie.201503069
  63. Vladimir Ya. Lee, Akira Sekiguchi. 1,1-Dilithiosilanes, 1,1-dilithiogermanes, 1,1-dilithiostannanes and related compounds: Organometallic reagents of the new generation. Mendeleev Communications 2015, 25 (3) , 161-167. https://doi.org/10.1016/j.mencom.2015.05.001
  64. Anukul Jana, Isabell Omlor, Volker Huch, Henry S. Rzepa, David Scheschkewitz. Durch ein N-heterocyclisches Carben koordinierte neutrale und kationische schwere Cyclopropylidenanaloga. Angewandte Chemie 2014, 126 (37) , 10112-10116. https://doi.org/10.1002/ange.201405238
  65. Anukul Jana, Isabell Omlor, Volker Huch, Henry S. Rzepa, David Scheschkewitz. N-Heterocyclic Carbene Coordinated Neutral and Cationic Heavier Cyclopropylidenes. Angewandte Chemie International Edition 2014, 53 (37) , 9953-9956. https://doi.org/10.1002/anie.201405238
  66. Mingwei Chen, Yuzhong Wang, Yaoming Xie, Pingrong Wei, Robert J. Gilliard, Nichole A. Schwartz, Henry F. Schaefer, Paul von R. Schleyer, Gregory H. Robinson. Dynamic Complexation of Copper(I) Chloride by Carbene-Stabilized Disilicon. Chemistry - A European Journal 2014, 20 (30) , 9208-9211. https://doi.org/10.1002/chem.201403095
  67. Megumi Kobayashi, Naoki Hayakawa, Koichi Nakabayashi, Tsukasa Matsuo, Daisuke Hashizume, Hiroyuki Fueno, Kazuyoshi Tanaka, Kohei Tamao. Highly Coplanar ( E )-1,2-Di(1-naphthyl)disilene Involving a Distinct CH–π Interaction with the Perpendicularly Oriented Protecting Eind Group. Chemistry Letters 2014, 43 (4) , 432-434. https://doi.org/10.1246/cl.131043
  68. S. Marutheeswaran, Pattath D. Pancharatna, Musiri M. Balakrishnarajan. Preference for a propellane motif in pure silicon nanosheets. Phys. Chem. Chem. Phys. 2014, 16 (23) , 11186-11190. https://doi.org/10.1039/C4CP01286K
  69. Carsten Präsang, David Scheschkewitz. Silyl Anions. 2013,,, 1-47. https://doi.org/10.1007/430_2013_104
  70. . Functional Molecular Silicon Compounds II. 2014,,https://doi.org/10.1007/978-3-319-03734-9
  71. Takeaki Iwamoto, Shintaro Ishida. Multiple Bonds with Silicon: Recent Advances in Synthesis, Structure, and Functions of Stable Disilenes. 2013,,, 125-202. https://doi.org/10.1007/430_2013_119
  72. . Functional Molecular Silicon Compounds II. 2014,,https://doi.org/10.1007/978-3-319-03734-9
  73. V.Ya. Lee, A. Sekiguchi. Multiply Bonded Compounds of Group 14 Elements. 2013,,, 289-324. https://doi.org/10.1016/B978-0-08-097774-4.00113-3
  74. . Comprehensive Inorganic Chemistry II. 2013,,https://doi.org/
  75. Jeng-Horng Sheu, Ming-Der Su. Theoretical Investigations of Mechanisms of Thermal Cleavage of E=E Bonds in Heavy Butadiene Systems (E = C, Si, Ge, Sn, and Pb). European Journal of Inorganic Chemistry 2012, 2012 (2) , 272-281. https://doi.org/10.1002/ejic.201100939
  76. Michael J. Cowley, Kai Abersfelder, Andrew J. P. White, Moumita Majumdar, David Scheschkewitz. Transmetallation reactions of a lithium disilenide. Chemical Communications 2012, 48 (52) , 6595. https://doi.org/10.1039/c2cc33047d
  77. Mitsuo KIRA. Bonding and structure of disilenes and related unsaturated group-14 element compounds. Proceedings of the Japan Academy, Series B 2012, 88 (5) , 167-191. https://doi.org/10.2183/pjab.88.167
  78. Heinrich Christian Marsmann. Silicon-29 NMR. 2011,,https://doi.org/10.1002/9780470034590.emrstm0505.pub2
  79. . Encyclopedia of Magnetic Resonance. 2007,,https://doi.org/
  80. David Scheschkewitz. The Versatile Chemistry of Disilenides: Disila Analogues of Vinyl Anions as Synthons in Low-valent Silicon Chemistry. Chemistry Letters 2011, 40 (1) , 2-11. https://doi.org/10.1246/cl.2011.2
  81. Tsukasa Matsuo, Baolin Li, Kohei Tamao. π-conjugated phosphasilenes stabilized by fused-ring bulky “Rind” groups. Comptes Rendus Chimie 2010, 13 (8-9) , 1104-1110. https://doi.org/10.1016/j.crci.2010.07.005
  82. . Heavy Analogs of Carbanions: Si-, Ge-, Sn- and Pb-Centered Anions. 2010,,, 89-138. https://doi.org/10.1002/9780470669266.ch3
  83. Vladimir Ya. Lee, Akira Sekiguchi. Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb. 2010,,https://doi.org/
  84. . Heavy Analogs of Alkenes, 1,3-Dienes, Allenes and Alkynes: Multiply Bonded Derivatives of Si, Ge, Sn and Pb. 2010,,, 199-334. https://doi.org/10.1002/9780470669266.ch5
  85. Vladimir Ya. Lee, Akira Sekiguchi. Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb. 2010,,https://doi.org/
  86. Claudia Gerdes, Thomas Müller. Neuigkeiten vom Silicium - ein Isomer des Hexasilabenzols und eine Metall-Silicium-Dreifachbindung. Angewandte Chemie 2010, 122 (29) , 4978-4981. https://doi.org/10.1002/ange.201001558
  87. Claudia Gerdes, Thomas Müller. News from Silicon: An Isomer of Hexasilabenzene and A Metal-Silicon Triple Bond. Angewandte Chemie International Edition 2010, 49 (29) , 4860-4862. https://doi.org/10.1002/anie.201001558
  88. Naokazu Kano, Hideaki Miyake, Keishi Sasaki, Takayuki Kawashima, Naomi Mizorogi, Shigeru Nagase. Dianionic species with a bond consisting of two pentacoordinated silicon atoms. Nature Chemistry 2010, 2 (2) , 112-116. https://doi.org/10.1038/nchem.513
  89. Mitsuo Kira. An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds. Chemical Communications 2010, 46 (17) , 2893. https://doi.org/10.1039/c002806a
  90. Tsukasa Matsuo, Megumi Kobayashi, Kohei Tamao. π-Conjugated disilenes stabilized by fused-ring bulky “Rind” groups. Dalton Transactions 2010, 39 (39) , 9203. https://doi.org/10.1039/c0dt00287a
  91. Torahiko Yamaguchi, Masaaki Ichinohe, Akira Sekiguchi. Addition of methyllithium to disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]), giving a disilenyllithium, and its unexpected isomerization to a disilacyclopropylsilyllithium. New Journal of Chemistry 2010, 34 (8) , 1544. https://doi.org/10.1039/c0nj00027b
  92. Kai Abersfelder, Thi-loan Nguyen, David Scheschkewitz. Stannyl-substituted Disilenes and a Disilastannirane. Zeitschrift für anorganische und allgemeine Chemie 2009, 635 (13-14) , 2093-2098. https://doi.org/10.1002/zaac.200900234
  93. Annemarie Schäfer, Manfred Weidenbruch, Thomas Müller, Kendrekar Pravinkumar, James Y. Becker. Electrochemical Properties of a Disilene, a Tetrasila-1,3-butadiene, and Their Germanium Analogues. Chemistry - A European Journal 2009, 15 (34) , 8424-8428. https://doi.org/10.1002/chem.200901001
  94. David Scheschkewitz. Anionic Reagents with Silicon-Containing Double Bonds. Chemistry - A European Journal 2009, 15 (11) , 2476-2485. https://doi.org/10.1002/chem.200801968
  95. Shigeyoshi Inoue, Masaaki Ichinohe, Akira Sekiguchi. An Isolable Boryl-substituted Disilene from the Reaction of an sp 2 -type Silyl Anion with Haloboranes: Synthesis and Characterization. Chemistry Letters 2008, 37 (10) , 1044-1045. https://doi.org/10.1246/cl.2008.1044
  96. Iulia Bejan, Shigeyoshi Inoue, Masaaki Ichinohe, Akira Sekiguchi, David Scheschkewitz. 1,2-Disilacyclobut-2-enes: Donor-Free Four-Membered Cyclic Silenes from Reaction of Disilenides with Vinylbromides. Chemistry - A European Journal 2008, 14 (24) , 7119-7122. https://doi.org/10.1002/chem.200800919
  97. Dmitry Bravo-Zhivotovskii, Roman Dobrovetsky, Dmitry Nemirovsky, Victoria Molev, Michael Bendikov, Gregory Molev, Mark Botoshansky, Yitzhak Apeloig. The Synthesis and Isolation of a Metal-Substituted Bis-silene. Angewandte Chemie 2008, 120 (23) , 4415-4417. https://doi.org/10.1002/ange.200800973
  98. Dmitry Bravo-Zhivotovskii, Roman Dobrovetsky, Dmitry Nemirovsky, Victoria Molev, Michael Bendikov, Gregory Molev, Mark Botoshansky, Yitzhak Apeloig. The Synthesis and Isolation of a Metal-Substituted Bis-silene. Angewandte Chemie International Edition 2008, 47 (23) , 4343-4345. https://doi.org/10.1002/anie.200800973
  99. Iulia Bejan, David Scheschkewitz. Phenylenverbrückung zwischen zwei Si-Si-Doppelbindungen. Angewandte Chemie 2007, 119 (30) , 5885-5888. https://doi.org/10.1002/ange.200701744
  100. Iulia Bejan, David Scheschkewitz. Two SiSi Double Bonds Connected by a Phenylene Bridge. Angewandte Chemie International Edition 2007, 46 (30) , 5783-5786. https://doi.org/10.1002/anie.200701744

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