Synthesis and Properties of a Rhodium Complex Having a Novel β-Ketophosphenato Ligand, a Heavier Congener of a β-Ketoiminato Ligand#
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Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan
Abstract
The first stable rhodium complex having a β-ketophosphenato ligand, which is a heavier congener of a β-ketoiminato ligand, has been synthesized and characterized. Comparison of properties between rhodium β-ketophosphenates 2 and rhodium β-ketoiminate 4 revealed the unique character of the β-ketophosphenato ligand, where the trans influence of the phosphorus atom should be stronger than the nitrogen atom of the β-ketoiminato ligand.
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Dedicated to the late Prof. Yoshihiko Itoh.
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Present address: Department of Chemistry and Chemical Biology, Graduate School of Engineering, Gunma University, 1-5-1, Tenjin-cho, Kiryu, Gunma 376-8515, Japan.
*
To whom correspondence should be addressed. Phone: +81-774-38-3200. Fax: +81-774-38-3209. E-mail: [email protected]
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