A Ferrocenyldiphosphene−Platinum Complex: Structural Features and Theoretical Calculations
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Institute for Chemical Research and Institute of Sustainability Science, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan
* To whom correspondence should be addressed. Tel: +81-774-38-3200. Fax: +81-774-38-3209. E-mail: [email protected]
†Institute for Chemical Research.
‡Institute of Sustainability Science.
Abstract
The ligand exchange reaction of (E)-TbtP═PFc (Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Fc = ferrocenyl) and ethylenebis(triphenylphosphine)platinum(0) resulted in the formation of the corresponding η2-diphosphene−platinum complex in 82% yield. The molecular structure of the platinum complex was confirmed by spectroscopic and X-ray crystallographic analyses.
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