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Synthesis and Reactivity of Hybrid Phosphido- and Thiolato-Bridged Diruthenium Complexes

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    Synthesis and Reactivity of Hybrid Phosphido- and Thiolato-Bridged Diruthenium Complexes
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    Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo 113-8656, Japan
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    Organometallics

    Cite this: Organometallics 2008, 27, 22, 6039–6042
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    https://doi.org/10.1021/om800749e
    Published October 23, 2008
    Copyright © 2008 American Chemical Society
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    Abstract

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    Reactions of the monophosphido-bridged diruthenium(III) complexes [Cp*RuCl(μ-PR2)(μ-Cl)RuClCp*] with a variety of (alkylthio)trimethylsilanes afford the hybrid phosphido- and thiolato-bridged diruthenium complexes [Cp*RuCl(μ-PR2)(μ-SR′)RuClCp*]. Although some newly prepared hybrid diruthenium complexes are found to work as catalysts toward propargylic substitution reactions of propargylic alcohols with nucleophiles, their catalytic activity is lower than that of the methanethiolato-bridged diruthenium complex.

    Copyright © 2008 American Chemical Society

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    CIF files giving X-ray crystallographic data for syn-6a and anti-6c. This material is available free of charge via the Internet at http://pubs.acs.org.

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    This article is cited by 27 publications.

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    2. Yoshihiro Miyake, Taichi Moriyama, Yoshiaki Tanabe, Satoshi Endo, and Yoshiaki Nishibayashi . Synthesis and Reactivity of Hybrid Phosphido- and Hydrosulfido-Bridged Diruthenium Complexes: Transformations into Diruthenium and Tetraruthenium Complexes Bridged by Phosphido and Sulfido Ligands. Organometallics 2012, 31 (8) , 3292-3299. https://doi.org/10.1021/om3001247
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    25. Victorio Cadierno, Sergio E. García-Garrido. All-Carbon-Substituted Allenylidene and Related Cumulenylidene Ligands. 2010, 151-218. https://doi.org/10.1007/978-3-642-04722-0_6
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    Organometallics

    Cite this: Organometallics 2008, 27, 22, 6039–6042
    Click to copy citationCitation copied!
    https://doi.org/10.1021/om800749e
    Published October 23, 2008
    Copyright © 2008 American Chemical Society
    Request reuse permissions

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