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Debus–Radziszewski Reaction Inspired In Situ “One-Pot” Approach to Construct Luminescent Zirconium-Organic Frameworks
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    Debus–Radziszewski Reaction Inspired In Situ “One-Pot” Approach to Construct Luminescent Zirconium-Organic Frameworks
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    • Zhen-Sha Ma
      Zhen-Sha Ma
      Hoffmann Institute of Advanced Materials, Shenzhen Polytechnic University, 7098 Liuxian Blvd, Nanshan District, Shenzhen 518055, P. R. China
      School of Chemical Engineering, University of Science and Technology Liaoning, 185 Qianshan Zhong Road, Anshan 114051, P. R. China
      More by Zhen-Sha Ma
    • Jian Zhang
      Jian Zhang
      Hoffmann Institute of Advanced Materials, Shenzhen Polytechnic University, 7098 Liuxian Blvd, Nanshan District, Shenzhen 518055, P. R. China
      More by Jian Zhang
    • Kang Zhou
      Kang Zhou
      Hoffmann Institute of Advanced Materials, Shenzhen Polytechnic University, 7098 Liuxian Blvd, Nanshan District, Shenzhen 518055, P. R. China
      More by Kang Zhou
    • Gonghao Lu*
      Gonghao Lu
      School of Chemical Engineering, University of Science and Technology Liaoning, 185 Qianshan Zhong Road, Anshan 114051, P. R. China
      *Email: [email protected]
      More by Gonghao Lu
    • Xiao-Yuan Liu*
      Xiao-Yuan Liu
      Hoffmann Institute of Advanced Materials, Shenzhen Polytechnic University, 7098 Liuxian Blvd, Nanshan District, Shenzhen 518055, P. R. China
      *Email: [email protected]
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2025, 64, 3, 1604–1610
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    https://doi.org/10.1021/acs.inorgchem.4c05128
    Published January 11, 2025
    Copyright © 2025 American Chemical Society

    Abstract

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    Metal–organic frameworks have received extensive development in the past three decades, which are generally constructed via the reaction between inorganic building units and commercially available or presynthesized organic linkers. However, the presynthesis of organic linkers is usually time-consuming and unsustainable due to multiple-step separation and purification. Therefore, methodology development of a new strategy is fundamentally important for the construction and further exploration of the applications of MOFs. Herein, we report an in situ “one-pot” strategy inspired by the Debus–Radziszewski reaction, in which the generation of organic linkers from three kinds of simple and commercially available precursors and sequential construction of MOFs are integrated into one solvothermal condition. Based on this method, two zirconium-tetracarboxylate frameworks (HIAM-4028-op and HIAM-4029-op) were successfully prepared, which exhibit bright blue and near-infrared emissions, respectively. Due to the coordinatively unsaturated metal sites and the low symmetry of HIAM-4028-op, the coordination modes in the single crystal can transfer from the pristine 8-connected Zr6 cluster to 8- and 9-connected and to 9- and 12-connected Zr6 cluster coexisting structures via secondary linker installation. To the best of our knowledge, the present work is the first time to construct MOFs using a Debus–Radziszewski reaction-inspired in situ “one-pot” strategy, which opens a new way to design and construct MOFs with specific properties and structures.

    Copyright © 2025 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.inorgchem.4c05128.

    • Single-crystal data and 1H NMR spectra for digested MOFs and crystallographic data for HIAM-4028-op, HIAM-4029-op, HIAM-4028-op-BDC, HIAM-4028-op-BPDCc, and HIAM-4028-op-NDC (PDF)

    Accession Codes

    Deposition Numbers 24051192405123 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via the joint Cambridge Crystallographic Data Centre (CCDC) and Fachinformationszentrum Karlsruhe Access Structures service.

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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2025, 64, 3, 1604–1610
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.4c05128
    Published January 11, 2025
    Copyright © 2025 American Chemical Society

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