Debus–Radziszewski Reaction Inspired In Situ “One-Pot” Approach to Construct Luminescent Zirconium-Organic FrameworksClick to copy article linkArticle link copied!
- Zhen-Sha MaZhen-Sha MaHoffmann Institute of Advanced Materials, Shenzhen Polytechnic University, 7098 Liuxian Blvd, Nanshan District, Shenzhen 518055, P. R. ChinaSchool of Chemical Engineering, University of Science and Technology Liaoning, 185 Qianshan Zhong Road, Anshan 114051, P. R. ChinaMore by Zhen-Sha Ma
- Jian ZhangJian ZhangHoffmann Institute of Advanced Materials, Shenzhen Polytechnic University, 7098 Liuxian Blvd, Nanshan District, Shenzhen 518055, P. R. ChinaMore by Jian Zhang
- Kang ZhouKang ZhouHoffmann Institute of Advanced Materials, Shenzhen Polytechnic University, 7098 Liuxian Blvd, Nanshan District, Shenzhen 518055, P. R. ChinaMore by Kang Zhou
- Gonghao Lu*Gonghao Lu*Email: [email protected]School of Chemical Engineering, University of Science and Technology Liaoning, 185 Qianshan Zhong Road, Anshan 114051, P. R. ChinaMore by Gonghao Lu
- Xiao-Yuan Liu*Xiao-Yuan Liu*Email: [email protected]Hoffmann Institute of Advanced Materials, Shenzhen Polytechnic University, 7098 Liuxian Blvd, Nanshan District, Shenzhen 518055, P. R. ChinaMore by Xiao-Yuan Liu
Abstract

Metal–organic frameworks have received extensive development in the past three decades, which are generally constructed via the reaction between inorganic building units and commercially available or presynthesized organic linkers. However, the presynthesis of organic linkers is usually time-consuming and unsustainable due to multiple-step separation and purification. Therefore, methodology development of a new strategy is fundamentally important for the construction and further exploration of the applications of MOFs. Herein, we report an in situ “one-pot” strategy inspired by the Debus–Radziszewski reaction, in which the generation of organic linkers from three kinds of simple and commercially available precursors and sequential construction of MOFs are integrated into one solvothermal condition. Based on this method, two zirconium-tetracarboxylate frameworks (HIAM-4028-op and HIAM-4029-op) were successfully prepared, which exhibit bright blue and near-infrared emissions, respectively. Due to the coordinatively unsaturated metal sites and the low symmetry of HIAM-4028-op, the coordination modes in the single crystal can transfer from the pristine 8-connected Zr6 cluster to 8- and 9-connected and to 9- and 12-connected Zr6 cluster coexisting structures via secondary linker installation. To the best of our knowledge, the present work is the first time to construct MOFs using a Debus–Radziszewski reaction-inspired in situ “one-pot” strategy, which opens a new way to design and construct MOFs with specific properties and structures.
Cited By
This article has not yet been cited by other publications.
Article Views
Altmetric
Citations
Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.
Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.
The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.