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    Magnesium Borohydride Ammonia Borane as a Magnesium Ionic Conductor
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    • Kazuaki Kisu*
      Kazuaki Kisu
      Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan
      *(K.K.) E-mail: [email protected]
      More by Kazuaki Kisu
      Orcidhttp://orcid.org/0000-0002-1693-4225
    • Sangryun Kim
      Sangryun Kim
      Institute for Materials Research (IMR), Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan
      More by Sangryun Kim
      Orcidhttp://orcid.org/0000-0001-8617-3022
    • Munehiro Inukai
      Munehiro Inukai
      Graduate School of Technology, Industrial and Social Sciences, Tokushima University, 2-1 Minami-Josanjima-Cho, Tokushima 770-8506, Japan
      More by Munehiro Inukai
    • Hiroyuki Oguchi
      Hiroyuki Oguchi
      Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan
      More by Hiroyuki Oguchi
    • Shigeyuki Takagi
      Shigeyuki Takagi
      Institute for Materials Research (IMR), Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan
      More by Shigeyuki Takagi
    • Shin-ichi Orimo*
      Shin-ichi Orimo
      Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan
      Institute for Materials Research (IMR), Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan
      *(S.O.) Email: [email protected]
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    Cite this: ACS Appl. Energy Mater. 2020, 3, 4, 3174–3179
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    https://doi.org/10.1021/acsaem.0c00113
    Published March 31, 2020
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    Abstract

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    Magnesium borohydride ammonia borane, Mg(BH4)2(NH3BH3)2, was electrochemically investigated. Impedance measurements of the mechanochemically synthesized Mg(BH4)2(NH3BH3)2 exhibited an ionic conductivity of 1.3 × 10–5 S cm–1 at 30 °C. Electrochemical cells fabricated with Mg(BH4)2(NH3BH3)2 as the solid electrolyte demonstrated reversible Mg migration through the material, indicating its potential for use as a Mg ionic conductor in all-solid-state Mg-ion batteries.

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    • Experimental section including material synthesis, characterization, and electrochemical analysis; figures showing temperature dependence of impedance; ionic conductivity; Nyquist plots and simulated curves; cyclic voltammograms; SEM image and elemental EDS maps; discharge and charge curves (PDF)

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    Cite this: ACS Appl. Energy Mater. 2020, 3, 4, 3174–3179
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