ACS Publications. Most Trusted. Most Cited. Most Read
Ultraflexible Neural Electrodes Enabled Synchronized Long-Term Dopamine Detection and Wideband Chronic Recording Deep in Brain
My Activity
    Article

    Ultraflexible Neural Electrodes Enabled Synchronized Long-Term Dopamine Detection and Wideband Chronic Recording Deep in Brain
    Click to copy article linkArticle link copied!

    • Xueying Wang
      Xueying Wang
      State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
      School of Graduate Study, University of Chinese Academy of Sciences, Beijing 100049, China
      More by Xueying Wang
    • Mingliang Xu
      Mingliang Xu
      Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China
      School of Physical Sciences, University of Science and Technology of China, Hefei 230026, China
      More by Mingliang Xu
    • Huiran Yang
      Huiran Yang
      State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
      School of Graduate Study, University of Chinese Academy of Sciences, Beijing 100049, China
      More by Huiran Yang
    • Wanqi Jiang
      Wanqi Jiang
      State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
      School of Graduate Study, University of Chinese Academy of Sciences, Beijing 100049, China
      More by Wanqi Jiang
    • Jianbo Jiang
      Jianbo Jiang
      State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
      School of Graduate Study, University of Chinese Academy of Sciences, Beijing 100049, China
      More by Jianbo Jiang
    • Dujuan Zou
      Dujuan Zou
      School of Graduate Study, University of Chinese Academy of Sciences, Beijing 100049, China
      2020 X-Lab, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
      More by Dujuan Zou
    • Ziyi Zhu
      Ziyi Zhu
      State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
      School of Graduate Study, University of Chinese Academy of Sciences, Beijing 100049, China
      More by Ziyi Zhu
    • Chen Tao
      Chen Tao
      State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
      School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China
      More by Chen Tao
    • Siyuan Ni
      Siyuan Ni
      State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
      School of Graduate Study, University of Chinese Academy of Sciences, Beijing 100049, China
      More by Siyuan Ni
    • Zhitao Zhou
      Zhitao Zhou
      State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
      School of Graduate Study, University of Chinese Academy of Sciences, Beijing 100049, China
      More by Zhitao Zhou
    • Liuyang Sun
      Liuyang Sun
      School of Graduate Study, University of Chinese Academy of Sciences, Beijing 100049, China
      2020 X-Lab, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
      More by Liuyang Sun
    • Meng Li
      Meng Li
      State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
      School of Graduate Study, University of Chinese Academy of Sciences, Beijing 100049, China
      More by Meng Li
    • Yanyan Nie
      Yanyan Nie
      Shanghai Laboratory Animal Research Center, Shanghai 201203, China
      More by Yanyan Nie
    • Ying Zhao
      Ying Zhao
      Shanghai Laboratory Animal Research Center, Shanghai 201203, China
      More by Ying Zhao
    • Fei He*
      Fei He
      Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China
      *Email: [email protected]
      More by Fei He
    • Tiger H. Tao*
      Tiger H. Tao
      State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
      School of Graduate Study, University of Chinese Academy of Sciences, Beijing 100049, China
      Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
      2020 X-Lab, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
      School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China
      Center for Excellence in Brain Science and Intelligence Technology, Chinese Academy of Sciences, Shanghai 200031, China
      Neuroxess Co., Ltd. (Jiangxi), Nanchang, Jiangxi 330029, China
      Guangdong Institute of Intelligence Science and Technology, Hengqin, Zhuhai, Guangdong 519031, China
      Tianqiao and Chrissy Chen Institute for Translational Research, Shanghai 200031, China
      *Email: [email protected]
      More by Tiger H. Tao
    • Xiaoling Wei*
      Xiaoling Wei
      State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
      School of Graduate Study, University of Chinese Academy of Sciences, Beijing 100049, China
      *Email: [email protected]
      More by Xiaoling Wei
    Other Access OptionsSupporting Information (2)

    ACS Nano

    Cite this: ACS Nano 2024, 18, 50, 34272–34287
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsnano.4c12429
    Published December 4, 2024
    Copyright © 2024 American Chemical Society

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    Ultraflexible neural electrodes have shown superior stability compared with rigid electrodes in long-term in vivo recordings, owing to their low mechanical mismatch with brain tissue. It is desirable to detect neurotransmitters as well as electrophysiological signals for months in brain science. This work proposes a stable electronic interface that can simultaneously detect neural electrical activity and dopamine concentration deep in the brain. This ultraflexible electrode is modified by a nanocomposite of reduced graphene oxide (rGO) and poly(3,4-ethylenedioxythiophene):poly(sodium 4-styrenesulfonate) (rGO/PEDOT:PSS), enhancing the electrical stability of the coating and increasing its specific surface area, thereby improving the sensitivity to dopamine response with 15 pA/μM. This electrode can detect dopamine fluctuations and can conduct long-term, stable recordings of local field potentials (LFPs), spiking activities, and amplitudes with high spatial and temporal resolution across multiple regions, especially in deep brain areas. The electrodes were implanted into the brains of rodent models to monitor the changes in neural and electrochemical signals across different brain regions during the administration of nomifensine. Ten minutes after drug injection, enhanced neuronal firing activity and increased LFP power were detected in the motor cortex and deeper cortical layers, accompanied by a gradual rise in dopamine levels with 192 ± 29 nM. The in vivo recording consistently demonstrates chronic high-quality neural signal monitoring with electrochemical signal stability for up to 6 weeks. These findings highlight the high quality and stability of our electrophysiological/electrochemical codetection neural electrodes, underscoring their tremendous potential for applications in neuroscience research and brain–machine interfaces.

    Copyright © 2024 American Chemical Society

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsnano.4c12429.

    • Additional information on fabrication, electrochemical tests, and animal experiments (PDF)

    • Video S1: flexible electrode array viewed in water (AVI)

    Terms & Conditions

    Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machine-readable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!

    This article has not yet been cited by other publications.

    ACS Nano

    Cite this: ACS Nano 2024, 18, 50, 34272–34287
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsnano.4c12429
    Published December 4, 2024
    Copyright © 2024 American Chemical Society

    Article Views

    910

    Altmetric

    -

    Citations

    -
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.