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Synthesis and Structural Characterization of a TCNQ Based Organic Semi-Conducting Material with a 2:5 Stoichiometry

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    Synthesis and Structural Characterization of a TCNQ Based Organic Semi-Conducting Material with a 2:5 Stoichiometry
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    † †School of Chemistry and ‡School of Physics, Monash University, Clayton, VIC 3800, Australia
    § Institute for Superconducting and Electronic Materials Faculty of Engineering, The University of Wollongong, Wollongong, NSW 2522, Australia
    E-mail: [email protected]; [email protected]
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    The Journal of Organic Chemistry

    Cite this: J. Org. Chem. 2011, 76, 24, 10078–10082
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    https://doi.org/10.1021/jo2018334
    Published November 9, 2011
    Copyright © 2011 American Chemical Society
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    Abstract

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    The tetrabutylammonium complex with a 2:5 stoichiometry, (n-Bu4N)2(TCNQ)5, has been prepared and structurally characterized by X-ray crystallography. Diagnostic bands in the Raman spectrum and signature features in the electrochemistry confirm that the TCNQ moieties are partially charged in the solid state. EPR, magnetic susceptibility, and electrical conductivity measurements are all consistent with (n-Bu4N)2(TCNQ)5 behaving as a quasi-one-dimensional organic semiconductor.

    Copyright © 2011 American Chemical Society

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    1H NMR, UV–vis, XRD, and crystallographic information in CIF form for the complex (n-Bu4N)2(TCNQ)5. This material is available free of charge via the Internet at http://pubs.acs.org.

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    This article is cited by 20 publications.

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    The Journal of Organic Chemistry

    Cite this: J. Org. Chem. 2011, 76, 24, 10078–10082
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jo2018334
    Published November 9, 2011
    Copyright © 2011 American Chemical Society
    Request reuse permissions

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