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Metamagnetic Behavior in a Quadruple Perovskite Oxide
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    Metamagnetic Behavior in a Quadruple Perovskite Oxide
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    • Yuichi Okazaki
      Yuichi Okazaki
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
    • Yuta Kato
      Yuta Kato
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
      More by Yuta Kato
    • Yuta Kizawa
      Yuta Kizawa
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
      More by Yuta Kizawa
    • Seiji Oda
      Seiji Oda
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
      More by Seiji Oda
    • Kai Uemura
      Kai Uemura
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
      More by Kai Uemura
    • Takuya Nishio
      Takuya Nishio
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
    • Fuminari Fujii
      Fuminari Fujii
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
    • Shintaro Fujinari
      Shintaro Fujinari
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
    • Masaya Kinoshita
      Masaya Kinoshita
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
    • Takao Odake
      Takao Odake
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
      More by Takao Odake
    • Hayato Togano
      Hayato Togano
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
    • Takashi Kamegawa
      Takashi Kamegawa
      Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
    • Shogo Kawaguchi
      Shogo Kawaguchi
      Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan
    • Hajime Yamamoto
      Hajime Yamamoto
      Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577, Japan
    • Hidekazu Ikeno
      Hidekazu Ikeno
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
      Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST), 4-1-8 Honcho Kawaguchi, Saitama 332-0012, Japan
    • Shunsuke Yagi
      Shunsuke Yagi
      Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan
    • Kouhei Wada
      Kouhei Wada
      Fuji Die Co., Ltd., 36-1 Hirasawa, Hadano, Kanagawa 257-0015, Japan
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    • Kyo-Hoon Ahn
      Kyo-Hoon Ahn
      Institute of Physics of the Czech Academy of Sciences, Cukrovarnická 10, 162 00 Prague 6, Czech Republic
      Division of Display and Semiconductor Physics, Korea University, Sejong 30019, Korea
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    • Atsushi Hariki
      Atsushi Hariki
      Department of Physics and Electrons, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
    • Ikuya Yamada*
      Ikuya Yamada
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan
      *Email: [email protected]
      More by Ikuya Yamada
    Other Access OptionsSupporting Information (1)

    Inorganic Chemistry

    Cite this: Inorg. Chem. 2021, 60, 10, 7023–7030
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.0c03432
    Published April 27, 2021
    Copyright © 2021 American Chemical Society

    Abstract

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    A cubic quadruple perovskite oxide CeMn3Cr4O12 has been synthesized under high-pressure and high-temperature conditions of 8 GPa and 1273 K. The X-ray absorption spectroscopy reveals that the Ce ions are in a trivalent state, as represented by the ionic model of Ce3+Mn3+3Cr3+4O12. The magnetic study demonstrates three independent antiferromagnetic transitions attributed to Ce (∼10 K), Mn (46 K), and Cr (133 K) ions. Furthermore, a magnetic field-induced antiferromagnetic-to-ferromagnetic (metamagnetic) transition of Ce3+ 4f moments is observed at low temperatures below 20 K, exhibiting a rare example of metamagnetism in the Ce3+-oxides. This finding represents that the 3d-electron magnetic sublattices play a role in the metamagnetism of 4f-electron magnetic moments, demonstrating a new aspect of the 3d–4f complex electron systems.

    Copyright © 2021 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c03432.

    • Additional SXRD profile, Rietveld refinement results, magnetic measurements data, and specific heat plots (PDF)

    Accession Codes

    CCDC 2045590 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

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    Cited By

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    This article is cited by 6 publications.

    1. Ikuya Yamada, Manami Goto, Yuta Kato, Yuta Kizawa, Hajime Yamamoto, Shintaro Kobayashi, Shogo Kawaguchi, Yuki Mori, Kenta Kimura. Switching of Intermetallic Charge Transfer and Negative Thermal Expansion in Mn-Doped CaCu3Fe4O12. The Journal of Physical Chemistry C 2023, 127 (38) , 19213-19219. https://doi.org/10.1021/acs.jpcc.3c04427
    2. Hongping Li, Yaoming Zhang, An Sun, Baochang Guo, Yi Tian. Semiconductor to half-metal transition in magnetic Ce cation incorporated A-site-ordered quadruple perovskite CeMn3Mn4O12. Journal of Alloys and Compounds 2023, 960 , 170577. https://doi.org/10.1016/j.jallcom.2023.170577
    3. Ikuya Yamada, Yuta Kato, Hiroshi Nakajima, Hidekazu Ikeno, Shigeo Mori, Shogo Kawaguchi. A Novel Diamagnetic Insulating Quadruple Perovskite Oxide YCu3Rh4O12. MATERIALS TRANSACTIONS 2023, 64 (9) , 2077-2081. https://doi.org/10.2320/matertrans.MT-MG2022005
    4. Jordan C. Scalia, Matthias Zeller, Curtis M. Zaleski. Synthesis and Crystal Structure of an Adjoined Metallacrown: An Archetypal 12-Metallacrown-4 Connected to a Collapsed 11-Metallacrown-4. Journal of Chemical Crystallography 2023, 53 (2) , 307-320. https://doi.org/10.1007/s10870-022-00968-8
    5. Yuta Kato, Hiroshi Nakajima, Shogo Kawaguchi, Shigeo Mori, Ikuya Yamada. High‐pressure synthesis, crystal structure, and properties of a novel quadruple perovskite CeMn 3 Rh 4 O 12. International Journal of Ceramic Engineering & Science 2022, 4 (4) , 249-256. https://doi.org/10.1002/ces2.10133
    6. 湧一 岡崎, 幾也 山田. 大阪公立大学 大学院工学研究科 物質化学生命系専攻 マテリアル工学分野 多機能性セラミックス材料研究グループ (無機固体化学). The Review of High Pressure Science and Technology 2022, 32 (2) , 102-103. https://doi.org/10.4131/jshpreview.32.102

    Inorganic Chemistry

    Cite this: Inorg. Chem. 2021, 60, 10, 7023–7030
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.0c03432
    Published April 27, 2021
    Copyright © 2021 American Chemical Society

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