Metamagnetic Behavior in a Quadruple Perovskite OxideClick to copy article linkArticle link copied!
- Yuichi OkazakiYuichi OkazakiDepartment of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanMore by Yuichi Okazaki
- Yuta KatoYuta KatoDepartment of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanMore by Yuta Kato
- Yuta KizawaYuta KizawaDepartment of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanMore by Yuta Kizawa
- Seiji OdaSeiji OdaDepartment of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanMore by Seiji Oda
- Kai UemuraKai UemuraDepartment of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanMore by Kai Uemura
- Takuya NishioTakuya NishioDepartment of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanMore by Takuya Nishio
- Fuminari FujiiFuminari FujiiDepartment of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanMore by Fuminari Fujii
- Shintaro FujinariShintaro FujinariDepartment of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanMore by Shintaro Fujinari
- Masaya KinoshitaMasaya KinoshitaDepartment of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanMore by Masaya Kinoshita
- Takao OdakeTakao OdakeDepartment of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanMore by Takao Odake
- Hayato ToganoHayato ToganoDepartment of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanMore by Hayato Togano
- Takashi KamegawaTakashi KamegawaDepartment of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanMore by Takashi Kamegawa
- Shogo KawaguchiShogo KawaguchiJapan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, JapanMore by Shogo Kawaguchi
- Hajime YamamotoHajime YamamotoInstitute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577, JapanMore by Hajime Yamamoto
- Hidekazu IkenoHidekazu IkenoDepartment of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanPrecursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST), 4-1-8 Honcho Kawaguchi, Saitama 332-0012, JapanMore by Hidekazu Ikeno
- Shunsuke YagiShunsuke YagiInstitute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, JapanMore by Shunsuke Yagi
- Kouhei Wada
- Kyo-Hoon AhnKyo-Hoon AhnInstitute of Physics of the Czech Academy of Sciences, Cukrovarnická 10, 162 00 Prague 6, Czech RepublicDivision of Display and Semiconductor Physics, Korea University, Sejong 30019, KoreaMore by Kyo-Hoon Ahn
- Atsushi HarikiAtsushi HarikiDepartment of Physics and Electrons, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanMore by Atsushi Hariki
- Ikuya Yamada*Ikuya Yamada*Email: [email protected]Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, JapanMore by Ikuya Yamada
Abstract
A cubic quadruple perovskite oxide CeMn3Cr4O12 has been synthesized under high-pressure and high-temperature conditions of 8 GPa and 1273 K. The X-ray absorption spectroscopy reveals that the Ce ions are in a trivalent state, as represented by the ionic model of Ce3+Mn3+3Cr3+4O12. The magnetic study demonstrates three independent antiferromagnetic transitions attributed to Ce (∼10 K), Mn (46 K), and Cr (133 K) ions. Furthermore, a magnetic field-induced antiferromagnetic-to-ferromagnetic (metamagnetic) transition of Ce3+ 4f moments is observed at low temperatures below 20 K, exhibiting a rare example of metamagnetism in the Ce3+-oxides. This finding represents that the 3d-electron magnetic sublattices play a role in the metamagnetism of 4f-electron magnetic moments, demonstrating a new aspect of the 3d–4f complex electron systems.
Cited By
This article is cited by 6 publications.
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- Yuta Kato, Hiroshi Nakajima, Shogo Kawaguchi, Shigeo Mori, Ikuya Yamada. High‐pressure synthesis, crystal structure, and properties of a novel quadruple perovskite CeMn
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- 湧一 岡崎, 幾也 山田. 大阪公立大学 大学院工学研究科 物質化学生命系専攻 マテリアル工学分野 多機能性セラミックス材料研究グループ (無機固体化学). The Review of High Pressure Science and Technology 2022, 32
(2)
, 102-103. https://doi.org/10.4131/jshpreview.32.102
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