ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES
ADDITION / CORRECTIONThis article has been corrected. View the notice.

Photoconductive Coordination Polymer with a Lead–Sulfur Two-Dimensional Coordination Sheet Structure

  • Yoshinobu Kamakura
    Yoshinobu Kamakura
    Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan
  • Chinatsu Sakura
    Chinatsu Sakura
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
  • Akinori Saeki
    Akinori Saeki
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
  • Shigeyuki Masaoka
    Shigeyuki Masaoka
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
  • Akito Fukui
    Akito Fukui
    Department of Physics and Electronics, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai-shi, Osaka 599- 8531, Japan
    More by Akito Fukui
  • Daisuke Kiriya
    Daisuke Kiriya
    Department of Physics and Electronics, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai-shi, Osaka 599- 8531, Japan
  • Kazuyoshi Ogasawara
    Kazuyoshi Ogasawara
    Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan
  • Hirofumi Yoshikawa
    Hirofumi Yoshikawa
    Department of Nanotechnology for Sustainable Energy, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan
  • , and 
  • Daisuke Tanaka*
    Daisuke Tanaka
    Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan
    Japan Science and Technology Agency (JST) PRESTO, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan
    *Email: [email protected] (D.T.).
Cite this: Inorg. Chem. 2021, 60, 8, 5436–5441
Publication Date (Web):April 8, 2021
https://doi.org/10.1021/acs.inorgchem.0c03801
Copyright © 2021 American Chemical Society

    Article Views

    2128

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options
    Supporting Info (1)»

    Abstract

    Abstract Image

    Coordination polymers with metal–sulfur (M–S) bonds in their nodes have interesting optical properties and can be used as photocatalysts for water splitting. A wide range of inorganic–organic hybrid materials with M–S bonds have been prepared in recent years. However, there is a dearth of structural information because of their low crystallinity, which has hampered the understanding of their underlying chemistry and physics. Thus, we conducted a structural study of a novel, highly crystalline coordination polymer with M–S bonds. Theoretical calculations were performed to elucidate its photoconductivity mechanism. The photoconductive, three-dimensional coordination polymer [Pb(tadt)]n (denoted as KGF-9; tadt = 1,3,4-thiadiazole-2,5-dithiolate) was synthesized and confirmed to have a three-dimensional structure containing a two-dimensional Pb–S framework by single-crystal X-ray diffraction. We also performed diffuse-reflectance ultraviolet–visible–near-infrared spectroscopy, time-resolved microwave conductivity, and photoelectron yield spectroscopy measurements on the bulk powder samples, as well as first-principles calculations. Additionally, direct-current photoconductivity measurements were conducted on a single-crystal sample.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c03801.

    • Experimental section, SEM image, fluorescence spectrum, crystallographic data, PXRD patterns, TGA and DTA curves, UV–vis spectrum, and PYS results (PDF)

    Accession Codes

    CCDC 2046612 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

    Terms & Conditions

    Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machine-readable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 3 publications.

    1. Anirban Ghosh, Sanjib Shyamal, Arnab Palui, Rabindra Nath Manna, Sujan Mondal, Manish Jana, Aswini Ghosh, Asim Bhaumik. Photoelectrochemical Water Oxidation over Novel Semiconducting Zinc-Based Metal–Thiolate Framework. ACS Applied Materials & Interfaces 2022, 14 (33) , 37699-37708. https://doi.org/10.1021/acsami.2c07737
    2. Yoshinobu Kamakura, Shuhei Yasuda, Naoki Hosokawa, Shunta Nishioka, Sawa Hongo, Toshiyuki Yokoi, Daisuke Tanaka, Kazuhiko Maeda. Selective CO2-to-Formate Conversion Driven by Visible Light over a Precious-Metal-Free Nonporous Coordination Polymer. ACS Catalysis 2022, 12 (16) , 10172-10178. https://doi.org/10.1021/acscatal.2c02177
    3. Ryohei Akiyoshi, Akinori Saeki, Kazuyoshi Ogasawara, Hirofumi Yoshikawa, Yuiga Nakamura, Daisuke Tanaka. Selective synthesis of two-dimensional semiconductive coordination polymers with silver–sulfur network. CrystEngComm 2023, 25 (20) , 2990-2994. https://doi.org/10.1039/D3CE00106G

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect