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A Strategic High Yield Synthesis of 2,5-Dihydroxy-1,4-benzoquinone Based MOFs

Cite this: Inorg. Chem. 2019, 58, 16, 10756–10760
Publication Date (Web):August 7, 2019
https://doi.org/10.1021/acs.inorgchem.9b00903
Copyright © 2019 American Chemical Society

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    Abstract

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    Metal organic frameworks (MOFs) of the type NBu4M(DHBQ)1.5 (M = Ni2+, Fe2+, and Co2+; DHBQ = 2,5-dihydroxy-1,4-benzoquinone) were prepared with improved yield up to 100% via a simple benchtop aqueous addition reaction. For the first time, the crystalline phase of this formula polymer was synthesized without in situ generation of the DHBQ ligand from 2, 5-diamino-1,4-benzoquinone (DABQ). Powder X-ray diffraction and elemental analysis confirm the crystalline phase and composition of products. Infrared and electron dispersive spectroscopy further confirm that the materials are homologous to the reported single crystalline polymers. The present MOF synthesis can be extended to halide-substituted ligands, i.e., 3,6-dichloro-2,5-dihydroxy-1,4-benzoquinone (chloranilic acid, CAN) and 3,6-difluoro-2,5-dihydroxy-1,4-benzoquinone (fluoranilic acid, FAN).

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    • Reaction schemes, FT-IR results, additional PXRD results, NMR results of digested samples, and price comparison of starting reagents (PDF)

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