Cobalt Bromide-Catalyzed Negishi-Type Cross-Coupling of AmidesClick to copy article linkArticle link copied!
- Céline DorvalCéline DorvalLCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, FranceMore by Céline Dorval
- Oleh StetsiukOleh StetsiukLCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, FranceMore by Oleh Stetsiuk
- Sylvaine GaillardSylvaine GaillardLCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, FranceMore by Sylvaine Gaillard
- Elodie DuboisElodie DuboisLCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, FranceMore by Elodie Dubois
- Corinne GosminiCorinne GosminiLCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, FranceMore by Corinne Gosmini
- Grégory Danoun*Grégory Danoun*Email: [email protected]LCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, FranceMore by Grégory Danoun
Abstract

Herein, we describe a novel Negishi-type cross-coupling of amides employing only cobalt bromide salt as the catalyst. This original reaction is highly tolerant to various glutarimide amides as well as organozinc coupling partners. These conditions also allow the performance of the cross-coupling reaction in an eco-compatible solvent such as ethyl acetate on a large scale.
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This article is cited by 6 publications.
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, 3399-3430. https://doi.org/10.1007/s11696-024-03369-7
- A. Haupt, I. Fleischer. Coupling Reactions Between sp3 and sp2 Carbon Centers. 2024https://doi.org/10.1016/B978-0-323-96025-0.00070-3
- Myeong Seong Park, Karthik Rajan Rajamanickam, Kwang Ho Song, Sunwoo Lee. 1,3‐Diketone‐Mediated Synthesis of Symmetrical Aryl Imides from Activated Amides. Asian Journal of Organic Chemistry 2023, 12
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- Pulluparambil Xavier Thresia Rinu, Rose Mary Philip, Gopinathan Anilkumar. Low-cost transition metal catalysed Negishi coupling: an update. Organic & Biomolecular Chemistry 2023, 21
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, 6438-6455. https://doi.org/10.1039/D3OB00784G
- Chengwei Liu, Michal Szostak. Amide N–C Bond Activation: A Graphical Overview of Acyl and Decarbonylative Coupling. SynOpen 2023, 07
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- Corinne Gosmini, Mengyu Gao. Co-catalyzed C–C Coupling Reactions with Csp2 Electrophiles. 2023, 145-179. https://doi.org/10.1007/3418_2023_89
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