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Heterocoronenes Containing Pyridine and 1,2-Azaborine Units

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    Heterocoronenes Containing Pyridine and 1,2-Azaborine Units
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    Organic Letters

    Cite this: Org. Lett. 2024, 26, 50, 11028–11033
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    https://doi.org/10.1021/acs.orglett.4c04211
    Published December 9, 2024
    Copyright © 2024 American Chemical Society
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    Abstract

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    Several coronenes containing pyridine and azaborine units have been readily prepared and structurally confirmed by X-ray crystallographic analysis. The codoping results in interesting findings and properties such as the first observation of BN-H---NPy hydrogen bonds in crystals of BN-PAHs, short π–π stacking distances, lowered HOMO–LUMO levels, narrow band gap, and unique dual response to fluoride ion and proton in solution.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.orglett.4c04211.

    • Full details of synthetic procedures for 1a–1d, NMR and HRMS spectra, absorption and emission spectra, X-ray crystallographic data, and theoretical calculations (PDF)

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    Deposition Number 2375631 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via the joint Cambridge Crystallographic Data Centre (CCDC) and Fachinformationszentrum Karlsruhe Access Structures service.

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    Organic Letters

    Cite this: Org. Lett. 2024, 26, 50, 11028–11033
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.orglett.4c04211
    Published December 9, 2024
    Copyright © 2024 American Chemical Society
    Request reuse permissions

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