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    Sulfur–Carbon Nano Fiber Composite Solid Electrolyte for All-Solid-State Li–S Batteries
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    • Nguyen Huu Huy Phuc*
      Nguyen Huu Huy Phuc
      Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku, Toyohashi, Aichi 441-8580, Japan
      *E-mail: [email protected] (N.H.H.P.).
      More by Nguyen Huu Huy Phuc
      Orcidhttp://orcid.org/0000-0001-8793-6132
    • Maeda Takaki
      Maeda Takaki
      Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku, Toyohashi, Aichi 441-8580, Japan
      More by Maeda Takaki
    • Hiroyuki Muto
      Hiroyuki Muto
      Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku, Toyohashi, Aichi 441-8580, Japan
      More by Hiroyuki Muto
    • Matsuda Reiko
      Matsuda Reiko
      Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku, Toyohashi, Aichi 441-8580, Japan
      More by Matsuda Reiko
    • Hikima Kazuhiro
      Hikima Kazuhiro
      Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku, Toyohashi, Aichi 441-8580, Japan
      More by Hikima Kazuhiro
    • Atsunori Matsuda*
      Atsunori Matsuda
      Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku, Toyohashi, Aichi 441-8580, Japan
      *E-mail: [email protected] (A.M.).
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    ACS Applied Energy Materials

    Cite this: ACS Appl. Energy Mater. 2020, 3, 2, 1569–1573
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    https://doi.org/10.1021/acsaem.9b02062
    Published January 24, 2020
    Copyright © 2020 American Chemical Society
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    Abstract

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    In the present study, the formation of sulfur nano sheets on the surface of positively charged carbon nano fiber (CNF) from Na2S3 precursor was investigated, and a two-step mechanism for this reaction was proposed for the first time. An S–CNF–solid electrolyte composite was successfully prepared and employed in an all-solid-state Li–S cell. Full sulfur capacity was obtained when the cell was cycled at 0.1C (0.177 mA cm–2), and a sulfur capacity of ∼600 mA h g–1S was maintained at 1C (1.77 mA cm–2).

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    ACS Applied Energy Materials

    Cite this: ACS Appl. Energy Mater. 2020, 3, 2, 1569–1573
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsaem.9b02062
    Published January 24, 2020
    Copyright © 2020 American Chemical Society
    Request reuse permissions

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