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    Functional Inorganic Materials and Devices

    Roll-to-Roll Manufactured Sensors for Nitroaromatic Organophosphorus Pesticides Detection
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    • Ana M. Ulloa
      Ana M. Ulloa
      Department of Materials Engineering, Purdue University, West Lafayette, Indiana 47907, United States
      More by Ana M. Ulloa
    • Nicholas Glassmaker
      Nicholas Glassmaker
      Birck Nanotechnology Center, Purdue University, West Lafayette, Indiana 47907, United States
      More by Nicholas Glassmaker
    • Muhammed R. Oduncu
      Muhammed R. Oduncu
      Department of Materials Engineering, Purdue University, West Lafayette, Indiana 47907, United States
      More by Muhammed R. Oduncu
    • Pengyu Xu
      Pengyu Xu
      Department of Materials Engineering, Purdue University, West Lafayette, Indiana 47907, United States
      More by Pengyu Xu
    • Alexander Wei
      Alexander Wei
      Department of Materials Engineering, Purdue University, West Lafayette, Indiana 47907, United States
      Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, United States
      More by Alexander Wei
      Orcidhttps://orcid.org/0000-0002-8587-1037
    • Mukerrem Cakmak
      Mukerrem Cakmak
      Department of Materials Engineering, Purdue University, West Lafayette, Indiana 47907, United States
      Birck Nanotechnology Center, Purdue University, West Lafayette, Indiana 47907, United States
      Department of Mechanical Engineering, Purdue University, West Lafayette, Indiana 47907, United States
      More by Mukerrem Cakmak
      Orcidhttps://orcid.org/0000-0001-9128-7833
    • Lia Stanciu*
      Lia Stanciu
      Department of Materials Engineering, Purdue University, West Lafayette, Indiana 47907, United States
      Birck Nanotechnology Center, Purdue University, West Lafayette, Indiana 47907, United States
      *Email: [email protected]
      More by Lia Stanciu
      Orcidhttps://orcid.org/0000-0001-6059-0346
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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2021, 13, 30, 35961–35971
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    https://doi.org/10.1021/acsami.1c08700
    Published July 27, 2021
    Copyright © 2021 American Chemical Society
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    Abstract

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    A fully roll-to-roll manufactured electrochemical sensor with high sensing and manufacturing reproducibility has been developed for the detection of nitroaromatic organophosphorus pesticides (NOPPs). This sensor is based on a flexible, screen-printed silver electrode modified with a graphene nanoplatelet (GNP) coating and a zirconia (ZrO2) coating. The combination of the metal oxide and the 2-D material provided advantageous electrocatalytic activity toward NOPPs. Manufacturing, scanning electron microscopy–scanning transmission electron microscopy image analysis, electrochemical surface characterization, and detection studies illustrated high sensitivity, selectivity, and stability (∼89% current signal retention after 30 days) of the platform. The enzymeless sensor enabled rapid response time (10 min) and noncomplex detection of NOPPs through voltammetry methods. Furthermore, the proposed platform was highly group-sensitive toward NOPPs (e.g., methyl parathion (MP) and fenitrothion) with a detection limit as low as 1 μM (0.2 ppm). The sensor exhibited a linear correlation between MP concentration and current response in a range from 1 μM (0.2 ppm) to 20 μM (4.2 ppm) and from 20 to 50 μM with an R2 of 0.992 and 0.991, respectively. Broadly, this work showcases the first application of GNPs/ZrO2 complex on flexible silver screen-printed electrodes fabricated by entirely roll-to-roll manufacturing for the detection of NOPPs.

    Copyright © 2021 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsami.1c08700.

    • Designs of silver screen-printed electrodes on PET substrate; Illustrations of Mirwec Min-Labo Deluxe coating machine and Maxwell roll-to roll system; Graphene nanoplatelets suspension-synthesis process; optimization of the electro-spraying parameters through experimental trials; zeta potential measurements; AgGNPsZrO2 electrode-FIB sample thinning prepared for STEM; CV of Ag/GNPs/ZrO 2 electrode in 80 μM MP in 0.1 M KCl at different scan rates (left) and Ipc vs (scan rate) 1/2 for the irreversible reduction of MP; Optimization of preconditioning (a) potential and (b) time for the detection of 80 μM methyl parathion in 0.1 M KCl: calibration curve data of MP detection; and Linear Fitting MP concentration and vs I delta response. The following file is available free of charge (PDF)

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    Cited By

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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2021, 13, 30, 35961–35971
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsami.1c08700
    Published July 27, 2021
    Copyright © 2021 American Chemical Society
    Request reuse permissions

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