ACS Publications. Most Trusted. Most Cited. Most Read
A New Type of Hybrid Copper Iodide as Nontoxic and Ultrastable LED Emissive Layer Material

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:ACS Energy Lett. 2021, 6, 7, 2565-2574
    Letter

    A New Type of Hybrid Copper Iodide as Nontoxic and Ultrastable LED Emissive Layer Material
    Click to copy article linkArticle link copied!

    • Kun Zhu
      Kun Zhu
      Department of Chemistry and Chemical Biology, Rutgers University, 123 Bevier Road, Piscataway, New Jersey 08854, United States
      More by Kun Zhu
      Orcidhttps://orcid.org/0000-0001-9059-513X
    • Zhongkai Cheng
      Zhongkai Cheng
      Department of Chemistry and Chemical Biology, Rutgers University, 123 Bevier Road, Piscataway, New Jersey 08854, United States
      Department of Materials Science and Engineering, Rutgers University, 607 Taylor Road, Piscataway, New Jersey 08854, United States
      More by Zhongkai Cheng
    • Sylvie Rangan
      Sylvie Rangan
      Department of Physics and Astronomy, Rutgers University, 136 Frelinghuysen Road, Piscataway Township, New Jersey 08854, United States
      More by Sylvie Rangan
      Orcidhttps://orcid.org/0000-0002-2367-5356
    • Mircea Cotlet
      Mircea Cotlet
      Center for Functional Nanomaterials, Brookhaven National Laboratory, 98 Rochester Street, Upton, New York 11973, United States
      More by Mircea Cotlet
    • Jingbo Du
      Jingbo Du
      Key Laboratory for Green Chemical Technology of Ministry of Education, R&D Center for Petrochemical Technology, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, 20 Yizhi Road, Nankai District, Tianjin 300072, P.R. China
      More by Jingbo Du
    • Leila Kasaei
      Leila Kasaei
      Department of Physics and Astronomy, Rutgers University, 136 Frelinghuysen Road, Piscataway Township, New Jersey 08854, United States
      More by Leila Kasaei
    • Simon J. Teat
      Simon J. Teat
      Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720, United States
      More by Simon J. Teat
    • Wei Liu
      Wei Liu
      Department of Chemistry and Chemical Biology, Rutgers University, 123 Bevier Road, Piscataway, New Jersey 08854, United States
      More by Wei Liu
      Orcidhttps://orcid.org/0000-0002-8543-1605
    • Yifei Chen
      Yifei Chen
      Key Laboratory for Green Chemical Technology of Ministry of Education, R&D Center for Petrochemical Technology, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, 20 Yizhi Road, Nankai District, Tianjin 300072, P.R. China
      More by Yifei Chen
      Orcidhttps://orcid.org/0000-0002-6001-4899
    • Leonard C. Feldman
      Leonard C. Feldman
      Department of Physics and Astronomy, Rutgers University, 136 Frelinghuysen Road, Piscataway Township, New Jersey 08854, United States
      More by Leonard C. Feldman
    • Deirdre M. O’Carroll
      Deirdre M. O’Carroll
      Department of Chemistry and Chemical Biology, Rutgers University, 123 Bevier Road, Piscataway, New Jersey 08854, United States
      Department of Materials Science and Engineering, Rutgers University, 607 Taylor Road, Piscataway, New Jersey 08854, United States
      More by Deirdre M. O’Carroll
      Orcidhttps://orcid.org/0000-0001-7209-4278
    • Jing Li*
      Jing Li
      Department of Chemistry and Chemical Biology, Rutgers University, 123 Bevier Road, Piscataway, New Jersey 08854, United States
      *[email protected]
      More by Jing Li
      Orcidhttps://orcid.org/0000-0001-7792-4322
    Other Access OptionsSupporting Information (1)

    ACS Energy Letters

    Cite this: ACS Energy Lett. 2021, 6, 7, 2565–2574
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsenergylett.1c00993
    Published June 28, 2021
    Copyright © 2021 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    Perovskite-based light-emitting diodes (PeLEDs) are promising candidates for next-generation solid-state lighting and display technologies. However, all current high-performance PeLEDs contain a toxic element (lead) and suffer from relatively low stability. Herein, we report a new type of lead-free LED using low-cost, eco-friendly, and robust copper(I) iodide hybrid material as the emissive layer (EML). Specifically, they are composed of copper iodide chains and organic ligands through ionic and coordinate bonds. Their remarkable stability and solution processability stem from this unique multifold bonding feature. High-quality thin films of 1D-Cu4I6(bttmp)2 were fabricated by a simple, one-step spin-coating process. They exhibit high photoluminescence quantum yield (91%) and long-term air stability (>2000 h). An EQE of 5.02% was achieved for a prototype yellow LED using 1D-Cu4I6(bttmp)2 EML. Its half-lifetime of 35.5 h obtained in open air outperforms that of most PeLEDs reported to date. This work opens a new direction for making LEDs based on ecofriendly and robust hybrid materials.

    Copyright © 2021 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsenergylett.1c00993.

    • Figures S1–S32; Tables S1–S9; and detailed descriptions on the ligand synthesis, crystal growth, device fabrication, material characterization, calculation methods, and device performance evaluation (PDF)

    Terms & Conditions

    Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machine-readable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 60 publications.

    1. Guanlei Gao, Si-Yu Xu, Xinghui Qi, Jie-Ru Yang, Peiqi Lin, Jin Chen, Xiao-Ying Huang, Ke-Zhao Du. Organic Ligand Exchange: The Chiral Structure–Property Regulation of Cuprous Halides. Inorganic Chemistry 2024, 63 (52) , 24554-24562. https://doi.org/10.1021/acs.inorgchem.4c03561
    2. Kun Zhu, Gia M. Carignan, Simon J. Teat, Sylvie Rangan, Xiuze Hei, Le Hong Nguyen, Jing Li. Narrow Band Gap Hybrid Copper(I)Iodides: Designer Materials for Optoelectronic Applications. Chemistry of Materials 2024, 36 (22) , 11139-11149. https://doi.org/10.1021/acs.chemmater.4c02044
    3. Jialin Zhu, Chen Su, Jing Yang, Hua Tong, Haibo Li, Wei Liu, Gangfeng Ouyang. Highly Emissive Organic Antimony Halide with Ferromagnetism and Methanol Sensing Properties. Crystal Growth & Design 2024, 24 (11) , 4293-4299. https://doi.org/10.1021/acs.cgd.4c00234
    4. Chuanying Shen, Hanzhang Chen, Longyun Xu, Kui Wu, Lingqiang Meng, Shoubao Zhang, Jiyang Wang, Duanliang Wang. Ultra-Broad-Band-Excitable Cu-Based Halide (C4H10N)4Cu4I8 with High Stability for LED Applications. Inorganic Chemistry 2024, 63 (6) , 3173-3180. https://doi.org/10.1021/acs.inorgchem.3c04318
    5. Raquel Utrera-Melero, Marie Cordier, Florian Massuyeau, Jean-Yves Mevellec, Aydar Rakhmatullin, Charlotte Martineau-Corcos, Camille Latouche, Sandrine Perruchas. Cubane Dimerization: Cu4 vs Cu8 Copper Iodide Clusters. Inorganic Chemistry 2023, 62 (44) , 18157-18171. https://doi.org/10.1021/acs.inorgchem.3c02634
    6. Zhao-Feng Wu, Chuanzhe Wang, Xingwu Liu, Kui Tan, Zhihua Fu, Simon J. Teat, Zi-Wei Li, Xiuze Hei, Xiao-Ying Huang, Gang Xu, Jing Li. Confinement of 1D Chain and 2D Layered CuI Modules in K-INA-R Frameworks via Coordination Assembly: Structure Regulation and Semiconductivity Tuning. Journal of the American Chemical Society 2023, 145 (35) , 19293-19302. https://doi.org/10.1021/jacs.3c05095
    7. Xiuze Hei, Simon J. Teat, Mingxing Li, Megan Bonite, Jing Li. Solution-Processable Copper Halide Based Hybrid Materials Consisting of Cationic Ligands with Different Coordination Modes. Inorganic Chemistry 2023, 62 (8) , 3660-3668. https://doi.org/10.1021/acs.inorgchem.2c04547
    8. Yanyan Li, Zhicong Zhou, Fu Kit Sheong, Zengshan Xing, Kam Sing Wong, Herman H. Y. Sung, Ian D. Williams, Jonathan E. Halpert. Organic–Inorganic Hybrid Alkali Copper Iodides for Bright Emission across the Visible Spectrum. Chemistry of Materials 2023, 35 (3) , 1318-1324. https://doi.org/10.1021/acs.chemmater.2c03353
    9. Rui Xu, Dingshuo Zhang, Junjie Si, Yihang Du, Qianqing Hu, Xiaoming Hao, Hong Zhao, Peiqing Cai, Qi Ai, Xin Yao, Yun Gao, Meiyi Zhu, Zenan Zhang, Muzhi Cai, Hin Wai Mo, Kentaro Harada, Zhizhen Ye, Xingliang Dai, Chihaya Adachi, Zugang Liu. Low-Voltage Driving Copper Iodide-Based Broadband Electroluminescence. ACS Energy Letters 2022, 7 (12) , 4408-4416. https://doi.org/10.1021/acsenergylett.2c02471
    10. Diana Temerova, Tai-Che Chou, Kristina S. Kisel, Toni Eskelinen, Niko Kinnunen, Janne Jänis, Antti J. Karttunen, Pi-Tai Chou, Igor O. Koshevoy. Hybrid Inorganic–Organic Complexes of Zn, Cd, and Pb with a Cationic Phenanthro-diimine Ligand. Inorganic Chemistry 2022, 61 (48) , 19220-19231. https://doi.org/10.1021/acs.inorgchem.2c02867
    11. Yang Fang, Kun Zhu, Simon J. Teat, Obadiah G. Reid, Xiuze Hei, Kai Zhu, Xiaochen Fang, Mingxing Li, Christopher A. Sojdak, Mircea Cotlet, Jing Li. Robust and Highly Conductive Water-Stable Copper Iodide-Based Hybrid Single Crystals. Chemistry of Materials 2022, 34 (22) , 10040-10049. https://doi.org/10.1021/acs.chemmater.2c02490
    12. Huixian Miao, Xiancheng Pan, Miao Li, Wenjiang Zhaxi, Jing Wu, Zetao Huang, Luying Liu, Xiao Ma, Shenlong Jiang, Wei Huang, Qun Zhang, Dayu Wu. A Copper Iodide Cluster-Based Coordination Polymer as an Unconventional Zero-Thermal-Quenching Phosphor. Inorganic Chemistry 2022, 61 (46) , 18779-18788. https://doi.org/10.1021/acs.inorgchem.2c03322
    13. Shuxin Wang, Emily E. Morgan, Shobhana Panuganti, Lingling Mao, Pratap Vishnoi, Guang Wu, Quanlin Liu, Mercouri G. Kanatzidis, Richard D. Schaller, Ram Seshadri. Ligand Control of Structural Diversity in Luminescent Hybrid Copper(I) Iodides. Chemistry of Materials 2022, 34 (7) , 3206-3216. https://doi.org/10.1021/acs.chemmater.1c04408
    14. Zhexin Song, Binyin Yu, Guokui Liu, Lingqiang Meng, Yangyang Dang. Chiral Hybrid Copper(I) Iodide Single Crystals Enable Highly Selective Ultraviolet-Pumped Circularly Polarized Luminescence Applications. The Journal of Physical Chemistry Letters 2022, 13 (11) , 2567-2575. https://doi.org/10.1021/acs.jpclett.2c00494
    15. Raquel Utrera-Melero, Florian Massuyeau, Camille Latouche, Franck Camerel, Sandrine Perruchas. Copper Iodide Clusters Coordinated by Emissive Cyanobiphenyl-Based Ligands. Inorganic Chemistry 2022, 61 (9) , 4080-4091. https://doi.org/10.1021/acs.inorgchem.1c03876
    16. Johnpaul K. Pious, Chinnadurai Muthu, Chakkooth Vijayakumar. Organic Spacer Cation Assisted Modulation of the Structure and Properties of Bismuth Halide Perovskites. Accounts of Chemical Research 2022, 55 (3) , 275-285. https://doi.org/10.1021/acs.accounts.1c00545
    17. Jingwen Chen, Kang Zhou, Jingbai Li, Guozhong Xu, Xiuze Hei, Jing Li. Strongly photoluminescent and radioluminescent copper( i ) iodide hybrid materials made of coordinated ionic chains. Chemical Science 2025, 16 (3) , 1106-1114. https://doi.org/10.1039/D4SC06242F
    18. Jia‐Yu Yao, He Liu, Zhong‐Ning Chen, Biwu Ma, Liang‐Jin Xu. Low‐Dimensional Lead‐Free Metal Halides for Efficient Electrically Driven Light‐Emitting Diodes. Angewandte Chemie 2025, 15 https://doi.org/10.1002/ange.202423185
    19. Jia‐Yu Yao, He Liu, Zhong‐Ning Chen, Biwu Ma, Liang‐Jin Xu. Low‐Dimensional Lead‐Free Metal Halides for Efficient Electrically Driven Light‐Emitting Diodes. Angewandte Chemie International Edition 2025, 15 https://doi.org/10.1002/anie.202423185
    20. Dilruba A. Popy, Bayram Saparov. “This or that” – light emission from hybrid organic–inorganic vs. coordination Cu( i ) halides. Journal of Materials Chemistry C 2025, 13 (2) , 521-560. https://doi.org/10.1039/D4TC04153D
    21. Liping Chen, Shuaicong Huo, Piao Wang, Xuyan Bai, Yujia Gao, Ying Yang. Synthesis and characterization of Bis(imino)phosphine [NPN] ligands and their copper(I) halide complexes. Polyhedron 2025, 265 , 117278. https://doi.org/10.1016/j.poly.2024.117278
    22. Sayed Ali Khan, Noor Zamin Khan, Jahangeer Ahmed, Marcin Runowski, Saad M Alshehri, Simeon Agathopoulos, Simon J. Teat, Jing Li. Ultra broadband yellow emitting lead-free metal halide perovskite like compounds with near-unity emission quantum yields. Journal of Materials Chemistry C 2025, 563 https://doi.org/10.1039/D4TC04804K
    23. Abdusalam Ablez, Hao-Wei Lin, Sheng-Mao Zhang, Guo-Yang Chen, Jia-Hua Luo, Ke-Zhao Du, Ze-Ping Wang, Xiao-Ying Huang. Integrating multiple emission centers for photoluminescence regulation in copper–antimony/bismuth halides. Inorganic Chemistry Frontiers 2024, 12 (1) , 369-378. https://doi.org/10.1039/D4QI02614D
    24. Kun Zhou, Bingyu Qi, Zhongwei Liu, Xinjiang Wang, Yuanhui Sun, Lijun Zhang. Advanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications. Advanced Functional Materials 2024, 34 (52) https://doi.org/10.1002/adfm.202411671
    25. Dingshuo Zhang, Meiyi Zhu, Yifan He, Qingli Cao, Yun Gao, Hongjin Li, Guochao Lu, Qiaopeng Cui, Yongmiao Shen, Haiping He, Xingliang Dai, Zhizhen Ye. Efficient and bright broadband electroluminescence based on environment-friendly metal halide nanoclusters. Light: Science & Applications 2024, 13 (1) https://doi.org/10.1038/s41377-024-01427-z
    26. Minze Li, Yao Sun, Honglai Lu, Peifen Zhu, Ruihong Wang, Guofeng Wang. Simultaneous improving luminescence intensity and stability of CsPbBr3:SCN−@Eu/Zr-Uio-66-NH2 with tunable emissions from blue to green and applications in indoor photovoltaics. Nano Research 2024, 17 (8) , 6879-6887. https://doi.org/10.1007/s12274-024-6663-9
    27. Shuailing Lin, Zhuangzhuang Ma, Xinzhen Ji, Qicong Zhou, Weihong Chu, Jibin Zhang, Ying Liu, Yanbing Han, Linyuan Lian, Mochen Jia, Xu Chen, Di Wu, Xinjian Li, Yu Zhang, Chongxin Shan, Zhifeng Shi. Efficient Large‐Area (81 cm 2 ) Ternary Copper Halides Light‐Emitting Diodes with External Quantum Efficiency Exceeding 13% via Host‐Guest Strategy. Advanced Materials 2024, 36 (29) https://doi.org/10.1002/adma.202313570
    28. A C Demirok, H Sahin, M Yagmurcukardes. Ultra-thin double-layered hexagonal CuI: strain tunable properties and robust semiconducting behavior. Journal of Physics: Condensed Matter 2024, 36 (21) , 215401. https://doi.org/10.1088/1361-648X/ad294d
    29. Gia M. Carignan, Simon J. Teat, Xiuze Hei, Jing Li. Design, synthesis, structure analysis and photophysical characterization of robust and solution-processable one-dimensional copper(I) iodide-based inorganic-organic hybrid semiconductors. Journal of Luminescence 2024, 269 , 120435. https://doi.org/10.1016/j.jlumin.2023.120435
    30. Nahid Hassan, Suneetha Nagaraja, Sauvik Saha, Kartick Tarafder, Nirmalya Ballav. Excitonic cuprophilic interactions in one-dimensional hybrid organic–inorganic crystals. Chemical Science 2024, 15 (11) , 4075-4085. https://doi.org/10.1039/D3SC06255D
    31. Yi Lv, Jing Yang, Haibo Li, Wei Liu, Gangfeng Ouyang. Molecular design towards efficient light-emitting copper( i ) halide mononuclear hybrids. Materials Advances 2024, 5 (3) , 1234-1239. https://doi.org/10.1039/D3MA00904A
    32. Jing-Jing Wang, Li-Zhe Feng, Guangyi Shi, Jun-Nan Yang, Yi-Da Zhang, Huaiyu Xu, Kuang-Hui Song, Tian Chen, Guozhen Zhang, Xu-Sheng Zheng, Fengjia Fan, Zhengguo Xiao, Hong-Bin Yao. High efficiency warm-white light-emitting diodes based on copper–iodide clusters. Nature Photonics 2024, 18 (2) , 200-206. https://doi.org/10.1038/s41566-023-01340-8
    33. Tomoki Nishiyama, Hirotaka Kitoh-Nishioka, Senku Tanaka, Masahiko Maekawa, Takayoshi Kuroda-Sowa, Masaki Yoshida, Masako Kato, Takashi Okubo. A copper( i ) thiocyanate-based photoresponsive semiconducting 2D coordination polymer. Dalton Transactions 2024, 53 (4) , 1445-1448. https://doi.org/10.1039/D3DT03125J
    34. Xiuze Hei, Jing Li. Making coordination networks ionic: a unique strategy to achieve solution-processable hybrid semiconductors. Materials Chemistry Frontiers 2023, 7 (20) , 4598-4604. https://doi.org/10.1039/D3QM00515A
    35. Xiaoqin Ji, Yang Liu, Ruiqian Li, Zixuan Zhang, Xuanyu Zhang, Congcong Chen, Jian Chen, Haipeng Lu, Rui Chen, Lingling Mao. Mono‐ and Bi‐Dentate Chiral Ligands Lead to Efficient Circularly Polarized Luminescence in 0D and 3D Semiconducting Copper(I) Iodides. Advanced Optical Materials 2023, 11 (19) https://doi.org/10.1002/adom.202300541
    36. Ling-ou Yang, Linchun Zhang, Dongjie Tian, Min Ye, Fangyuan Lin, Xuelian Liu, Yiru Wang, Xi Chen. Oxygen sensing behavior modulation of tetranuclear copper iodide hybrid materials using ligand engineering. Sensors and Actuators B: Chemical 2023, 393 , 134310. https://doi.org/10.1016/j.snb.2023.134310
    37. Mokurala Krishnaiah, Ajit Kumar, Dhananjay Mishra, Hyeon-Bin Jo, Geun Lee, Sung Hun Jin. Process ambient effects on defect state generation in CuI films: Toward multimodal sensor application via patternable CuI arrays. Applied Surface Science 2023, 626 , 157251. https://doi.org/10.1016/j.apsusc.2023.157251
    38. Tinghui Zhuang, Yanpeng Lin, Jiance Jin, Zhonghua Deng, Yingchen Peng, Liaokuo Gong, Zeping Wang, Kezhao Du, Xiaoying Huang. A Mechanochemically Synthesized Hybrid Bismuth Halide as Highly Efficient Red Phosphor for Blue Chip‐Based WLED. Advanced Optical Materials 2023, 11 (12) https://doi.org/10.1002/adom.202202951
    39. Maosheng Chen, Chenyu Ye, Chengqin Dai, Ruixiang Li, Ruijuan Qi, Chunhua Luo, Hui Peng, Hechun Lin. Self-assembly formation of CuI hybrid micron phosphors with tunable emission for multifunctional applications. Journal of Colloid and Interface Science 2023, 638 , 834-841. https://doi.org/10.1016/j.jcis.2023.01.083
    40. Jiajing Wu, Yue Guo, Jing‐Li Qi, Wen‐Dong Yao, Su‐Xin Yu, Wenlong Liu, Sheng‐Ping Guo. Multi‐Stimuli Responsive Luminescence and Domino Phase Transition of Hybrid Copper Halides with Nonlinear Optical Switching Behavior. Angewandte Chemie 2023, 135 (18) https://doi.org/10.1002/ange.202301937
    41. Jiajing Wu, Yue Guo, Jing‐Li Qi, Wen‐Dong Yao, Su‐Xin Yu, Wenlong Liu, Sheng‐Ping Guo. Multi‐Stimuli Responsive Luminescence and Domino Phase Transition of Hybrid Copper Halides with Nonlinear Optical Switching Behavior. Angewandte Chemie International Edition 2023, 62 (18) https://doi.org/10.1002/anie.202301937
    42. Alexander V. Artem'ev, Evgeniya P. Doronina, Mariana I. Rakhmanova, Xiuze Hei, Dmitri V. Stass, Ol'ga A. Tarasova, Irina Yu. Bagryanskaya, Denis G. Samsonenko, Alexander S. Novikov, Nina A. Nedolya, Jing Li. A family of CuI-based 1D polymers showing colorful short-lived TADF and phosphorescence induced by photo- and X-ray irradiation. Dalton Transactions 2023, 52 (13) , 4017-4027. https://doi.org/10.1039/D3DT00035D
    43. Juan-Juan Shao, Wei-Min Chen, Abraham Mensah, Peng-Lai Liu, Jian-Ling Ni, Li-Zhuang Chen, Fang-Ming Wang. Realizing near white and warm light emission of cuprous iodide complexes by alkyl-isomerization of ligands. Dalton Transactions 2023, 52 (11) , 3254-3259. https://doi.org/10.1039/D2DT02526D
    44. Xiuze Hei, Simon J. Teat, Mingxing Li, Megan Bonite, Jing Li. Highly soluble copper( i ) iodide-based hybrid luminescent semiconductors containing molecular and one-dimensional coordinated anionic inorganic motifs. Journal of Materials Chemistry C 2023, 11 (8) , 3086-3094. https://doi.org/10.1039/D2TC05479E
    45. Si-Yu Xu, Jie-Ru Yang, Ya-Nan Wu, Hang-qing Lin, Yun Chai, Jia-Wei Lin, Ke-Zhao Du. Chemical etching strategy to prepare microtubes of a hybrid organic cuprous halide. CrystEngComm 2023, 25 (7) , 1053-1057. https://doi.org/10.1039/D2CE01558G
    46. Juan-Juan Shao, Jian-Ling Ni, Wei-Min Chen, Peng-Lai Liu, Abraham Mensah, Li-Zhuang Chen, Fang-Ming Wang. Systematic regulation of ligands realizes the transition of luminescence color cuprous iodide inorganic–organic hybrid materials from blue to green light. New Journal of Chemistry 2023, 47 (5) , 2556-2564. https://doi.org/10.1039/D2NJ04044A
    47. Shu-Hua Xue, Jia-Yu Yao, Liang-Jin Xu, Zhong-Ning Chen. Advances in electrically driven light-emitting diodes based on lead-free metal halides. Chemical Communications 2023, 59 (9) , 1116-1124. https://doi.org/10.1039/D2CC06680G
    48. Yoonseo Nah, Devan Solanki, Dong Ha Kim. All-inorganic non-perovskite copper halides for light emission. Cell Reports Physical Science 2022, 3 (12) , 101171. https://doi.org/10.1016/j.xcrp.2022.101171
    49. Xiuze Hei, Kun Zhu, Gia Carignan, Simon J. Teat, Mingxing Li, Guoyu Zhang, Megan Bonite, Jing Li. Solution-processable copper(I) iodide-based inorganic-organic hybrid semiconductors composed of both coordinate and ionic bonds. Journal of Solid State Chemistry 2022, 314 , 123427. https://doi.org/10.1016/j.jssc.2022.123427
    50. Fatma Garci, Hammouda Chebbi, Nahal Rouzbeh, Leonhard Rochels, Sabrina Disch, Axel Klein, Mohamed Faouzi Zid. Structure, optical and magnetic properties of the pyridinium cobaltate (C6H9N2)2[CoCl4]. Inorganica Chimica Acta 2022, 539 , 121003. https://doi.org/10.1016/j.ica.2022.121003
    51. Yan V. Demyanov, Evgeniy H. Sadykov, Marianna I. Rakhmanova, Alexander S. Novikov, Irina Yu. Bagryanskaya, Alexander V. Artem’ev. Tris(2-Pyridyl)Arsine as a New Platform for Design of Luminescent Cu(I) and Ag(I) Complexes. Molecules 2022, 27 (18) , 6059. https://doi.org/10.3390/molecules27186059
    52. Maosheng Chen, Chenyu Ye, Chengqin Dai, Ruijuan Qi, Hanmei Fu, Chunhua Luo, Hui Peng, Hechun Lin. Highly Luminescent Copper(I) Halide Phosphors Encapsulated in Fumed Silica for Anti‐Counterfeiting and Color‐Converting Applications. Advanced Optical Materials 2022, 10 (13) https://doi.org/10.1002/adom.202200278
    53. Xiaolin Yin, Chunmei Liu, Shuang Liu, Mengmeng Cao, Jeremy M. Rawson, Yan Xu, Bin Zhang. Structural characterization and luminescence properties of trigonal Cu( i ) iodine/bromine complexes comprising cation–π interactions. New Journal of Chemistry 2022, 46 (13) , 6185-6192. https://doi.org/10.1039/D2NJ00318J
    54. Zhexin Song, Binyin Yu, Lingqiang Meng, Guokui Liu, Yangyang Dang. Air-grown hybrid copper( i ) halide single crystals: structural transformations and ultraviolet-pumped photoluminescence applications. Materials Advances 2022, 3 (5) , 2447-2455. https://doi.org/10.1039/D1MA01055G
    55. Haibo Li, Yi Lv, Zhennan Zhou, Hua Tong, Wei Liu, Gangfeng Ouyang. Coordinated Anionic Inorganic Module—An Efficient Approach Towards Highly Efficient Blue‐Emitting Copper Halide Ionic Hybrid Structures. Angewandte Chemie 2022, 134 (8) https://doi.org/10.1002/ange.202115225
    56. Haibo Li, Yi Lv, Zhennan Zhou, Hua Tong, Wei Liu, Gangfeng Ouyang. Coordinated Anionic Inorganic Module—An Efficient Approach Towards Highly Efficient Blue‐Emitting Copper Halide Ionic Hybrid Structures. Angewandte Chemie International Edition 2022, 61 (8) https://doi.org/10.1002/anie.202115225
    57. Alexander V. Artem'ev, Yan V. Demyanov, Marianna I. Rakhmanova, Irina Yu. Bagryanskaya. Pyridylarsine-based Cu( i ) complexes showing TADF mixed with fast phosphorescence: a speeding-up emission rate using arsine ligands. Dalton Transactions 2022, 51 (3) , 1048-1055. https://doi.org/10.1039/D1DT03759E
    58. Jesús López, María Murillo, Ginés Lifante-Pedrola, Eugenio Cantelar, Javier Gonzalez-Platas, Ulises R. Rodríguez-Mendoza, Pilar Amo-Ochoa. Multi-stimulus semiconductor Cu( i )–I-pyrimidine coordination polymer with thermo- and mechanochromic sensing. CrystEngComm 2022, 24 (2) , 341-349. https://doi.org/10.1039/D1CE01315G
    59. Xiuze Hei, Yang Fang, Simon J. Teat, Colin Farrington, Megan Bonite, Jing Li. Copper(I) iodide-based organic–inorganic hybrid compounds as phosphor materials. Zeitschrift für Naturforschung B 2021, 76 (10-12) , 759-764. https://doi.org/10.1515/znb-2021-0126
    60. Zitang Wei, Kang Wang, Wenchao Zhao, Yao Gao, Qixuan Hu, Ke Chen, Letian Dou. A selenophene-containing conjugated organic ligand for two-dimensional halide perovskites. Chemical Communications 2021, 57 (87) , 11469-11472. https://doi.org/10.1039/D1CC04679A
    Download PDF
    Go to ACS Energy Letters
    Get e-Alerts
    Get e-Alerts

    ACS Energy Letters

    Cite this: ACS Energy Lett. 2021, 6, 7, 2565–2574
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsenergylett.1c00993
    Published June 28, 2021
    Copyright © 2021 American Chemical Society
    Request reuse permissions

    Article Views

    3472

    Altmetric

    -

    Citations

    60
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.