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Plasmon Energy Transfer in Hybrid Nanoantennas

  • Sean S. E. Collins
    Sean S. E. Collins
    Department of Chemistry, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Smalley-Curl Institute, Rice University, 6100 Main Street, Houston, Texas 77005, United States
  • Emily K. Searles
    Emily K. Searles
    Department of Chemistry, Rice University, 6100 Main Street, Houston, Texas 77005, United States
  • Lawrence J. Tauzin
    Lawrence J. Tauzin
    Department of Chemistry, Rice University, 6100 Main Street, Houston, Texas 77005, United States
  • Minhan Lou
    Minhan Lou
    Laboratory for Nanophotonics, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Department of Electrical and Computer Engineering, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    More by Minhan Lou
  • Luca Bursi
    Luca Bursi
    Laboratory for Nanophotonics, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Department of Physics & Astronomy, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    More by Luca Bursi
  • Yawei Liu
    Yawei Liu
    Department of Chemistry, Emory University, 1515 Dickey Drive, NE, Atlanta, Georgia 30322, United States
    More by Yawei Liu
  • Jia Song
    Jia Song
    Department of Chemistry, Emory University, 1515 Dickey Drive, NE, Atlanta, Georgia 30322, United States
    More by Jia Song
  • Charlotte Flatebo
    Charlotte Flatebo
    Department of Chemistry, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Applied Physics Program, Rice University, 6100 Main Street, Houston, Texas 77005, United States
  • Rashad Baiyasi
    Rashad Baiyasi
    Department of Electrical and Computer Engineering, Rice University, 6100 Main Street, Houston, Texas 77005, United States
  • Yi-Yu Cai
    Yi-Yu Cai
    Department of Chemistry, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    More by Yi-Yu Cai
  • Benjamin Foerster
    Benjamin Foerster
    Advanced Materials & Systems Research, Polymer Colloid Technology, BASF SE, 67056 Ludwigshafen am Rhein, Germany
  • Tianquan Lian
    Tianquan Lian
    Department of Chemistry, Emory University, 1515 Dickey Drive, NE, Atlanta, Georgia 30322, United States
  • Peter Nordlander
    Peter Nordlander
    Smalley-Curl Institute, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Laboratory for Nanophotonics, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Department of Electrical and Computer Engineering, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Department of Physics & Astronomy, Rice University, 6100 Main Street, Houston, Texas 77005, United States
  • Stephan Link*
    Stephan Link
    Department of Chemistry, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Smalley-Curl Institute, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Department of Electrical and Computer Engineering, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    *Email: [email protected] (S.L.).
    More by Stephan Link
  • , and 
  • Christy F. Landes*
    Christy F. Landes
    Department of Chemistry, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Smalley-Curl Institute, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Department of Electrical and Computer Engineering, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Department of Chemical and Biomolecular Engineering, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    *Email: [email protected] (C.F.L.).
Cite this: ACS Nano 2021, 15, 6, 9522–9530
Publication Date (Web):December 22, 2020
https://doi.org/10.1021/acsnano.0c08982
Copyright © 2020 American Chemical Society

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    Abstract

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    Plasmonic metal nanoparticles exhibit large dipole moments upon photoexcitation and have the potential to induce electronic transitions in nearby materials, but fast internal relaxation has to date limited the spatial range and efficiency of plasmonic mediated processes. In this work, we use photo-electrochemistry to synthesize hybrid nanoantennas comprised of plasmonic nanoparticles with photoconductive polymer coatings. We demonstrate that the formation of the conductive polymer is selective to the nanoparticles and that polymerization is enhanced by photoexcitation. In situ spectroscopy and simulations support a mechanism in which up to 50% efficiency of nonradiative energy transfer is achieved. These hybrid nanoantennas combine the unmatched light-harvesting properties of a plasmonic antenna with the similarly unmatched device processability of a polymer shell.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsnano.0c08982.

    • pNiTAPc film characterization; AuNR polymerization electrochemical data, further analysis, and characterization; spectroelectrochemical control experiments; FEM and FDTD simulation descriptions; further Eres and ΔΓ analysis; negligible CT justification; ultrafast measurements; PL measurements and calculations (PDF)

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    Cited By

    This article is cited by 34 publications.

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