ACS Publications. Most Trusted. Most Cited. Most Read
Magnetophoresis-Assisted Capillary Assembly: A Versatile Approach for Fabricating Tailored 3D Magnetic Supercrystals

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:ACS Nano 2021, 15, 3, 5096-5108
    Article

    Magnetophoresis-Assisted Capillary Assembly: A Versatile Approach for Fabricating Tailored 3D Magnetic Supercrystals
    Click to copy article linkArticle link copied!

    • Pierre Moritz
      Pierre Moritz
      Laboratoire de Physique et Chimie des Nano-Objets, UMR 5215 INSA, CNRS, UPS, Université de Toulouse, 135 avenue de Rangueil, 31077 Toulouse, France
      LAAS-CNRS, Université de Toulouse, 7 avenue du Colonel Roche, 31077 Toulouse, France
      More by Pierre Moritz
    • Antoine Gonon
      Antoine Gonon
      Laboratoire de Physique et Chimie des Nano-Objets, UMR 5215 INSA, CNRS, UPS, Université de Toulouse, 135 avenue de Rangueil, 31077 Toulouse, France
      More by Antoine Gonon
    • Thomas Blon
      Thomas Blon
      Laboratoire de Physique et Chimie des Nano-Objets, UMR 5215 INSA, CNRS, UPS, Université de Toulouse, 135 avenue de Rangueil, 31077 Toulouse, France
      More by Thomas Blon
    • Nicolas Ratel-Ramond
      Nicolas Ratel-Ramond
      CEMES-CNRS, 29 rue Jeanne Marvig, 31055 Toulouse, France
      More by Nicolas Ratel-Ramond
    • Fabrice Mathieu
      Fabrice Mathieu
      LAAS-CNRS, Université de Toulouse, 7 avenue du Colonel Roche, 31077 Toulouse, France
      More by Fabrice Mathieu
    • Pierre Farger
      Pierre Farger
      Laboratoire de Physique et Chimie des Nano-Objets, UMR 5215 INSA, CNRS, UPS, Université de Toulouse, 135 avenue de Rangueil, 31077 Toulouse, France
      More by Pierre Farger
    • Juan-Manuel Asensio-Revert
      Juan-Manuel Asensio-Revert
      Laboratoire de Physique et Chimie des Nano-Objets, UMR 5215 INSA, CNRS, UPS, Université de Toulouse, 135 avenue de Rangueil, 31077 Toulouse, France
      More by Juan-Manuel Asensio-Revert
    • Simon Cayez
      Simon Cayez
      Laboratoire de Physique et Chimie des Nano-Objets, UMR 5215 INSA, CNRS, UPS, Université de Toulouse, 135 avenue de Rangueil, 31077 Toulouse, France
      More by Simon Cayez
    • David Bourrier
      David Bourrier
      LAAS-CNRS, Université de Toulouse, 7 avenue du Colonel Roche, 31077 Toulouse, France
      More by David Bourrier
    • Daisuke Saya
      Daisuke Saya
      LAAS-CNRS, Université de Toulouse, 7 avenue du Colonel Roche, 31077 Toulouse, France
      More by Daisuke Saya
    • Liviu Nicu
      Liviu Nicu
      LAAS-CNRS, Université de Toulouse, 7 avenue du Colonel Roche, 31077 Toulouse, France
      More by Liviu Nicu
    • Guillaume Viau
      Guillaume Viau
      Laboratoire de Physique et Chimie des Nano-Objets, UMR 5215 INSA, CNRS, UPS, Université de Toulouse, 135 avenue de Rangueil, 31077 Toulouse, France
      More by Guillaume Viau
      Orcidhttp://orcid.org/0000-0001-7062-4183
    • Thierry Leïchlé
      Thierry Leïchlé
      LAAS-CNRS, Université de Toulouse, 7 avenue du Colonel Roche, 31077 Toulouse, France
      School of Electrical and Computer Engineering, Georgia Tech−CNRS International Research Laboratory, Atlantic Drive, Atlanta, Georgia 30332, United States
      More by Thierry Leïchlé
    • Lise-Marie Lacroix*
      Lise-Marie Lacroix
      Laboratoire de Physique et Chimie des Nano-Objets, UMR 5215 INSA, CNRS, UPS, Université de Toulouse, 135 avenue de Rangueil, 31077 Toulouse, France
      *Email: [email protected]. Tel: +33567048833. Fax: +33561559697.
      More by Lise-Marie Lacroix
      Orcidhttp://orcid.org/0000-0003-3351-7949
    Other Access OptionsSupporting Information (3)

    ACS Nano

    Cite this: ACS Nano 2021, 15, 3, 5096–5108
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsnano.0c10215
    Published February 23, 2021
    Copyright © 2021 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    The fabrication and integration of sub-millimeter magnetic materials into predefined circuits is of major importance for the realization of portable devices designed for telecommunications, automotive, biomedical, and space applications but remains highly challenging. We report here a versatile approach for the fabrication and direct integration of nanostructured magnetic materials of controlled shaped at specific locations onto silicon substrates. The magnetophoresis-assisted capillary assembly of magnetic nanoparticles, either spherical or anisotropic, leads to the fabrication of high-performance Co-based permanent magnets and Fe-based supercrystals. Integrated sub-millimeter magnets as well as millimeter self-standing magnets exhibiting magnetic properties competing with NdFeB-based composites were obtained through this cost- and time-efficient process. The proof-of-concept of electromagnetic actuation of a micro-electromechanical system cantilever by means of these supercrystals highlights their potentiality as efficient integrated magnetic materials within nomadic devices.

    Copyright © 2021 American Chemical Society

    Subjects

    what are subjects

    Keywords

    what are keywords

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsnano.0c10215.

    • Details of the different forces called into play during the magnetophoresis-assisted capillary assembly considering isotropic (Fe2.2C NPs) or anisotropic objects (Co NRs) and additional snapshots; TEM images and magnetic hysteresis of the starting nanoparticles (Fe2.2C NPs and Co NRs); additional simulations of the magnetic field gradients induced by Ni blocks or Fe bars and the corresponding 2D maps and profile evolution; additional SEM and XRD characterization of the final supercrystal prepared (PDF)

    • Deposition of a dilute suspension of Co NRs ([Co] ∼ 20 g/L) on top of two Ni blocks (AVI)

    • Fabrication process of a 150 μm thick Co NR-based permanent magnet (MP4)

    Terms & Conditions

    Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machine-readable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!
    Citation Statements
    Explore this article's citation statements on scite.ai
    powered by  Scite

    This article is cited by 5 publications.

    1. Leonie Wittmann, Emily Krucker-Velasquez, Julia Schaupp, Laura Westphal, James W. Swan, Alfredo Alexander-Katz, Martin Z. Bazant, Sebastian P. Schwaminger, Sonja Berensmeier. Influence of magnetic convection on separation efficiency in magnetophoretic microfluidic processes: a combined simulation and experimental study. Nanoscale 2025, 17 (3) , 1574-1584. https://doi.org/10.1039/D4NR02225D
    2. Jeotikanta Mohapatra, Pramanand Joshi, J. Ping Liu. Low-dimensional hard magnetic materials. Progress in Materials Science 2023, 138 , 101143. https://doi.org/10.1016/j.pmatsci.2023.101143
    3. Clémence Chinaud-Chaix, Nataliia Marchenko, Thomas Fernique, Simon Tricard. Do chemists control plane packing, i.e. two-dimensional self-assembly, at all scales?. New Journal of Chemistry 2023, 47 (15) , 7014-7025. https://doi.org/10.1039/D3NJ00208J
    4. Abhirup Basu, Lilian B. Okello, Natasha Castellanos, Sangchul Roh, Orlin D. Velev. Assembly and manipulation of responsive and flexible colloidal structures by magnetic and capillary interactions. Soft Matter 2023, 19 (14) , 2466-2485. https://doi.org/10.1039/D3SM00090G
    5. Pierre Moritz, Ilona Lecerf, Antoine Gonon, Georgiana Maties, Thomas Blon, Simon Cayez, David Bourrier, Fabrice Mathieu, José Elías Angulo-Cervera, Liviu Nicu, Thierry Leïchlé, Thierry Ondarçuhu, Guillaume Viau, Lise-Marie Lacroix. Hybrid Ni–Co–Ni Structures Prepared by Magnetophoresis as Efficient Permanent Magnets for Integration into Microelectromechanical Systems. Advanced Engineering Materials 2022, 24 (12) https://doi.org/10.1002/adem.202200733
    Download PDF
    Go to ACS Nano
    Get e-Alerts
    Get e-Alerts

    ACS Nano

    Cite this: ACS Nano 2021, 15, 3, 5096–5108
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsnano.0c10215
    Published February 23, 2021
    Copyright © 2021 American Chemical Society
    Request reuse permissions

    Article Views

    989

    Altmetric

    -

    Citations

    5
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.