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Novel Photoanode Structure Templated from Butterfly Wing Scales
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    Novel Photoanode Structure Templated from Butterfly Wing Scales
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    State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 200240 Shanghai, P.R. China, University of Michigan−Shanghai Jiao Tong University Joint Institute, and Department of Electrical and Electronic Engineering, Saga University, Saga 840-8502, Japan
    * Corresponding author. Fax: 86-021-3420 2749. Tel: 86-021-3420 2634. E-mail: [email protected]
    †Shanghai Jiao Tong University.
    ‡University of Michigan−Shanghai Jiao Tong University Joint Institute.
    §Saga University.
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    Chemistry of Materials

    Cite this: Chem. Mater. 2009, 21, 1, 33–40
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    https://doi.org/10.1021/cm702458p
    Published December 15, 2008
    Copyright © 2008 American Chemical Society

    Abstract

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    We studied a novel photoanode structure inspired by butterfly wing scales with potential application on dye-sensitized solar cell in this paper. Quasi-honeycomb like structure (QHS), shallow concavities structure (SCS), and cross-ribbing structure (CRS) were synthesized onto a fluorine-doped tin-oxide-coated glass substrate using butterfly wings as biotemplates separately. Morphologies of the photoanodes, which were maintained from the original butterfly wings, were characterized by scanning and transmission electron microscopies. The results show that the calcined photoanodes with butterfly wings’ structures, which comprised arranged ridges and ribs consisting of nanoparticles, were fully crystallined. Analysis of absorption spectra measurements under visible light wavelength indicates that the light-harvesting efficiencies of the QHS photoanode were higher than the normal titania photoanode without biotemplates because of the special microstructures, and then the whole solar cell efficiency can be lifted based on this.

    Copyright © 2008 American Chemical Society

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    Nature image of the butterfly used. The sketch map of standard honeycomb structures and the corresponding FFT image. FESEM images of the original cross-ribbing structure (CRS) scale from Thaumantis diores. EDXS analyses of the original and titania replicas. UV−vis absorption spectra of different samples loading in RB solution at the same condition. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Chemistry of Materials

    Cite this: Chem. Mater. 2009, 21, 1, 33–40
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    https://doi.org/10.1021/cm702458p
    Published December 15, 2008
    Copyright © 2008 American Chemical Society

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