Structural Analyses and Magnetic Properties of 3D Coordination Polymeric Networks of Nickel(II) Maleate and Manganese(II) Adipate with the Flexible 1,2-Bis(4-pyridyl)ethane LigandClick to copy article linkArticle link copied!
Abstract
Two novel inorganic−organic hybrid 3D extended networks of Ni(II) and Mn(II) having molecular formulas [(maleate)2Ni3(bpe)4(H2O)4](NO3)2·H2O (1) and [(adipate)Mn(bpe)] (2) (bpe = 1, 2-bis(4-pyridyl)ethane), respectively, have been synthesized and characterized by single-crystal X-ray diffraction studies and low-temperature (300−2 K) magnetic measurements. Compound 1 crystallizes in the monoclinic system, space group C2/c (No. 15), with chemical formula C56H62N10Ni3O19, a = 30.955(4) Å, b = 12.705(3) Å, c = 17.058(5) Å, β = 117.26(2)°, and Z = 4. Compound 2 crystallizes in the triclinic system, space group P1̄ (No. 2), with chemical formula C18H20MnN2O4, a = 8.492(2) Å, b = 9.444(2) Å, c = 11.533(3) Å, α = 97.19(1)°, β = 94.64(1)°, γ = 105.02(1)°, and Z = 2. The structure determination reveals for both a 3D network. Compound 1 contains two crystallographically independent Ni(II) ions in different octahedral environments. Ni(1) lies on an inversion center, and its coordination environment comprises two chelating maleate anions and two bpe nitrogen donors, while the Ni(2) ion is surrounded by meridionally disposed three bpe N atoms, two water molecules, and one oxygen donor from the dicarboxylate anion. Of the three crystallographic independent bpe ligand, one presents an anti and the others a gauche conformation. The corresponding N-to-N distances are 9.344, 6.543, and 6.187 Å. Variable-temperature magnetic susceptibility measurement of the complex reveals the existence of a dominant ferromagnetic interaction within the molecule. Compound 2 is composed of Mn2 dimer units linked by adipate anions to form corrugated 2D sheets which, on interconnection through bpe (anti conformation, N-to-N distance of 9.391 Å), produces an interpenetrated 3D α-polonium-related type net. Complex 2 reveals to be antiferromagnetic fitting data using a dimeric Mn(II) model that considers negligible magnetic transmission through the carbon skeleton of adipate and the bpe pathway.
†
Indian Association for the Cultivation of Science.
‡
University of Trieste.
§
Universit de Paris-Sud.
*
To whom correspondence should be addressed. E-mail: [email protected] (N.R.C.); [email protected] (J.R.). Fax: (91)(33) 2473-2805 (N.R.C.).
‖
Universitat de Barcelona.
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