Two Isostructural 3D Lanthanide Coordination Networks (Ln = Gd3+, Dy3+) with Squashed Cuboid-Type Nanoscopic Cages Showing Significant Cryogenic Magnetic Refrigeration and Slow Magnetic RelaxationClick to copy article linkArticle link copied!
Abstract
Two isostructural lanthanide-based 3D coordination networks [Ln = Gd3+ (1), Dy3+(2)] with densely packed distorted cuboid nanoscopic cages are reported for the first time. Magnetic characterization reveals that complex 1 shows a significant cryogenic magnetocaloric effect (−ΔSm = 44 J kg–1 K–1), whereas 2 shows slow relaxation of magnetization.
Cited By
This article is cited by 109 publications.
- Tian-Tian Wang, Qi Tan, Wen-Bin Sun. Two Three-Dimensional LnIII Coordination Polymers Exhibiting Luminescent Sensing and a Magnetocaloric Effect. Inorganic Chemistry 2024, 63
(24)
, 11347-11353. https://doi.org/10.1021/acs.inorgchem.4c01346
- Tucker J. Ball, Matthew J. Polinski. Lanthanide Squarate Complexes Containing Mono- and Trivalent Thallium. Inorganic Chemistry 2023, 62
(24)
, 9618-9629. https://doi.org/10.1021/acs.inorgchem.3c01099
- Natasha Brenner, Joseph M. Sperling, Todd N. Poe, Cristian Celis-Barros, Kristi Brittain, Eric M. Villa, Thomas E. Albrecht-Schmitt, Matthew J. Polinski. Trivalent f-Element Squarates, Squarate-Oxalates, and Cationic Materials, and the Determination of the Nine-Coordinate Ionic Radius of Cf(III). Inorganic Chemistry 2020, 59
(13)
, 9384-9395. https://doi.org/10.1021/acs.inorgchem.0c01254
- Ludmila dos S. Mariano, Iara M. L. Rosa, Nathália R. De Campos, Antônio C. Doriguetto, Danielle F. Dias, Walace D. do Pim, Ana Karoline S. M. Valdo, Felipe T. Martins, Marcos A. Ribeiro, Elgte E. B. De Paula, Emerson F. Pedroso, Humberto O. Stumpf, Joan Cano, Francesc Lloret, Miguel Julve, Maria Vanda Marinho. Polymorphic Derivatives of NiII and CoII Mesocates with 3D Networks and “Brick and Mortar” Structures: Preparation, Structural Characterization, and Cryomagnetic Investigation of New Single-Molecule Magnets. Crystal Growth & Design 2020, 20
(4)
, 2462-2476. https://doi.org/10.1021/acs.cgd.9b01638
- Ning-Fang Li, Qing-Fang Lin, Xi-Ming Luo, Jia-Peng Cao, Yan Xu. Cl–-Templated Assembly of Novel Peanut-like Ln40Ni44 Heterometallic Clusters Exhibiting a Large Magnetocaloric Effect. Inorganic Chemistry 2019, 58
(16)
, 10883-10889. https://doi.org/10.1021/acs.inorgchem.9b01261
- Richard J. C. Dixey, Paul J. Saines. Optimization of the Magnetocaloric Effect in Low Applied Magnetic Fields in LnOHCO3 Frameworks. Inorganic Chemistry 2018, 57
(20)
, 12543-12551. https://doi.org/10.1021/acs.inorgchem.8b01549
- Xi-Ming Luo, Zhao-Bo Hu, Qing-fang Lin, Weiwei Cheng, Jia-Peng Cao, Chen-Hui Cui, Hua Mei, You Song, Yan Xu. Exploring the Performance Improvement of Magnetocaloric Effect Based Gd-Exclusive Cluster Gd60. Journal of the American Chemical Society 2018, 140
(36)
, 11219-11222. https://doi.org/10.1021/jacs.8b07841
- Sourav Biswas, Kochan S. Bejoymohandas, Sourav Das, Pankaj Kalita, Mundalapudi L. P. Reddy, Itziar Oyarzabal, Enrique Colacio, and Vadapalli Chandrasekhar . Mononuclear Lanthanide Complexes: Energy-Barrier Enhancement by Ligand Substitution in Field-Induced DyIII SIMs. Inorganic Chemistry 2017, 56
(14)
, 7985-7997. https://doi.org/10.1021/acs.inorgchem.7b00689
- Zhong-Yi Li, Yan Chen, Xin-Ying Dong, Bin Zhai, Xiang-Fei Zhang, Chi Zhang, Fu-Li Zhang, Su-Zhi Li, and Guang-Xiu Cao . Two Types of Lanthanide Coordination Polymers Based on a Homophthalate Ligand Exhibiting Luminescence and a Significant Magnetocaloric Effect. Crystal Growth & Design 2017, 17
(7)
, 3877-3884. https://doi.org/10.1021/acs.cgd.7b00501
- Soumava Biswas, Jayita Chakraborty, Vijay Singh Parmar, Siba Prasad Bera, Nirmal Ganguli, and Sanjit Konar . Channel-Assisted Proton Conduction Behavior in Hydroxyl-Rich Lanthanide-Based Magnetic Metal–Organic Frameworks. Inorganic Chemistry 2017, 56
(9)
, 4956-4965. https://doi.org/10.1021/acs.inorgchem.6b03147
- Sourav Biswas, Joydeb Goura, Sourav Das, Craig V. Topping, Jamie Brambleby, Paul A. Goddard, and Vadapalli Chandrasekhar . Octanuclear Heterobimetallic {Ni4Ln4} Assemblies Possessing Ln4 Square Grid [2 × 2] Motifs: Synthesis, Structure, and Magnetism. Inorganic Chemistry 2016, 55
(17)
, 8422-8436. https://doi.org/10.1021/acs.inorgchem.6b01019
- Cai-Ming Liu, Deqing Zhang, Xiang Hao, and Dao-Ben Zhu . Field-Induced Relaxation of Magnetization in a Three-Dimensional LnMOF with the Second Bridging Ligand Squarate. ACS Omega 2016, 1
(2)
, 286-292. https://doi.org/10.1021/acsomega.6b00083
- Zhong-Yi Li, Bin Zhai, Su-Zhi Li, Guang-Xiu Cao, Fu-Qiang Zhang, Xiang-Fei Zhang, Fu-Li Zhang, and Chi Zhang . Two Series of Lanthanide Coordination Polymers with 2-Methylenesuccinate: Magnetic Refrigerant, Slow Magnetic Relaxation, and Luminescence Properties. Crystal Growth & Design 2016, 16
(8)
, 4574-4581. https://doi.org/10.1021/acs.cgd.6b00678
- Manasi Roy, Satirtha Sengupta, Sukhen Bala, Sudeshna Bhattacharya, and Raju Mondal . Systematic Study of Mutually Inclusive Influences of Temperature and Substitution on the Coordination Geometry of Co(II) in a Series of Coordination Polymers and Their Properties. Crystal Growth & Design 2016, 16
(6)
, 3170-3179. https://doi.org/10.1021/acs.cgd.5b01835
- Soumava Biswas, Amit Kumar Mondal, and Sanjit Konar . Densely Packed Lanthanide Cubane Based 3D Metal–Organic Frameworks for Efficient Magnetic Refrigeration and Slow Magnetic Relaxation. Inorganic Chemistry 2016, 55
(5)
, 2085-2090. https://doi.org/10.1021/acs.inorgchem.5b02486
- Debarati Das, Goutam Mahata, Amit Adhikary, Sanjit Konar, and Kumar Biradha . Structural Adaptation of Ni4O4 Units To Form Cubane, Open Dicubane, Dimeric Cubane, and One-Dimensional Polymeric Cubanes: Magnetostructural Correlation of Ni4 Clusters. Crystal Growth & Design 2015, 15
(8)
, 4132-4141. https://doi.org/10.1021/acs.cgd.5b00736
- Long-Yang Xu, Jiong-Peng Zhao, Ting Liu, and Fu-Chen Liu . Gadolinium Sulfate Modified by Formate To Obtain Optimized Magneto-Caloric Effect. Inorganic Chemistry 2015, 54
(11)
, 5249-5256. https://doi.org/10.1021/acs.inorgchem.5b00214
- Yan Li, Jia-Wen Yu, Zhong-Yi Liu, En-Cui Yang, and Xiao-Jun Zhao . Three Isostructural One-Dimensional LnIII Chains with Distorted Cubane Motifs Showing Dual Fluorescence and Slow Magnetic Relaxation/Magnetocaloric Effect. Inorganic Chemistry 2015, 54
(1)
, 153-160. https://doi.org/10.1021/ic501952b
- Yi-Xia Ren, Xiang-Jun Zheng, Li-Cun Li, Da-Qiang Yuan, Miao An, and Lin-Pei Jin . Three-Dimensional Frameworks Based on Dodecanuclear Dy–hydroxo Wheel Cluster with Slow Relaxation of Magnetization. Inorganic Chemistry 2014, 53
(23)
, 12234-12236. https://doi.org/10.1021/ic502042h
- Somnath, Ashok Kumar Bharati, Musheer Ahmad, Robert L. LaDuca, Anwar Jahan Wahidi, Kafeel Ahmad Siddiqui. 1D + 3D → 3D zinc polyrotaxane MOF: Selective fluorescent detection of nitrobenzene, uric acid and sucrose and photocatalytic degradation of Rose Bengal and Congo Red dyes. Journal of Molecular Structure 2024, 1299 , 137200. https://doi.org/10.1016/j.molstruc.2023.137200
- Himanshu Sekhar Jena, Chidharth Krishnaraj, Jashobanta Sahoo, Javeed Ahmad Sheikh. Development of new generation magnets based on porous coordination polymers. 2024, 317-339. https://doi.org/10.1016/B978-0-323-95535-5.00011-0
- Qingqing Yan, Jing Wang, Linda Zhang, Jiaqi Liu, Mohammad Wahiduzzaman, Nana Yan, Liang Yu, Romain Dupuis, Hao Wang, Guillaume Maurin, Michael Hirscher, Peng Guo, Sujing Wang, Jiangfeng Du. A squarate-pillared titanium oxide quantum sieve towards practical hydrogen isotope separation. Nature Communications 2023, 14
(1)
https://doi.org/10.1038/s41467-023-39871-x
- Somnath, Musheer Ahmad, Kafeel Ahmad Siddiqui. Cu(II)-based coordination polymer encapsulated formate: Unveiling efficient photocatalytic degradation of Rose Bengal dye and remarkable sensing of DMF, acetone and acetonitrile. Journal of Molecular Structure 2023, 1280 , 135055. https://doi.org/10.1016/j.molstruc.2023.135055
- Somnath, Musheer Ahmad, Kafeel Ahmad Siddiqui. Ratiometric luminescent sensing of a biomarker for sugar consumption in an aqueous medium using a Cu(
ii
) coordination polymer. Dalton Transactions 2023, 52
(12)
, 3643-3660. https://doi.org/10.1039/D3DT00022B
- Shuvankar Mandal, Abhishek Pramanik, Sourav Dey, Luca M. Carrella, Gopalan Rajaraman, Eva Rentschler, Sasankasekhar Mohanta. Experimental and theoretical investigations on three Dy
III
4
single molecule magnets: structural and magneto-structural correlations. Dalton Transactions 2022, 51
(38)
, 14753-14766. https://doi.org/10.1039/D2DT02348B
- Bo-Liang Liu, Qiao-Fei Xu, La-Sheng Long, Lan-Sun Zheng. Magnetocaloric Effect of Two Gd-Based Frameworks. Inorganics 2022, 10
(7)
, 91. https://doi.org/10.3390/inorganics10070091
- Yin Zhang, Wei‐Dong Yu, Cai‐Feng Zhao, Jun Yan. Dimensional Reduction of
Eu‐Based Metal‐Organic
Framework as Catalysts for Oxidation Catalysis of C(sp
3
)–H Bond. Chinese Journal of Chemistry 2022, 40
(4)
, 480-486. https://doi.org/10.1002/cjoc.202100659
- Chen Yang, Yu-Heng Wei, Shuang Xu, Hao-Yu Zhang, Yue-Qi Yang, Bo Zhang, Ming Fang. Single molecule magnet behavior and magnetic refrigeration of carbonyl oxygen-bridged tetranuclear lanthanide complexes. New Journal of Chemistry 2021, 45
(31)
, 14103-14110. https://doi.org/10.1039/D1NJ01833G
- Xiao-Fen Guan, Peng-Fei Shi, Miao-Miao Xue, Zhi-Xuan Fang, Li-Rong Yang, Wen-Min Wang. Structures and magnetic properties of acyloxy-O bridged Ln2 compounds: Gd2 compound displaying magnetic refrigeration property. Journal of Molecular Structure 2021, 1233 , 129984. https://doi.org/10.1016/j.molstruc.2021.129984
- Jason P. Stone, Elizabeth A. Decoteau, Matthew J. Polinski. Synthesis and structural characterization of an air and water stable divalent Europium squarate prepared by in situ reduction. Journal of Solid State Chemistry 2021, 297 , 122048. https://doi.org/10.1016/j.jssc.2021.122048
- Marta Orts-Arroyo, Renato Rabelo, Ainoa Carrasco-Berlanga, Nicolás Moliner, Joan Cano, Miguel Julve, Francesc Lloret, Giovanni De Munno, Rafael Ruiz-García, Júlia Mayans, José Martínez-Lillo, Isabel Castro. Field-induced slow magnetic relaxation and magnetocaloric effects in an oxalato-bridged gadolinium(
iii
)-based 2D MOF. Dalton Transactions 2021, 50
(11)
, 3801-3805. https://doi.org/10.1039/D1DT00462J
- Arpan Mondal, Sanjit Konar. Strong Equatorial Crystal Field Enhances the Axial Anisotropy and Energy Barrier for Spin Reversal Process in Yb
2
Single Molecule Magnets. Chemistry – A European Journal 2021, 27
(10)
, 3449-3456. https://doi.org/10.1002/chem.202004379
- Richard A. Layfield. Lanthanides. 2021, 418-470. https://doi.org/10.1016/B978-0-08-102688-5.00057-X
- Xiao-Hong Shi, Sha-Sha Hao, Mei-Jiao Wang, Lin Zhang, Wen-Hui Liang, Hui-Min Gao, Jie Wang, Ying Shi, Wen-Min Wang. Two Ln(III)2 (Ln = Gd and Dy) compounds showing magnetic refrigeration and slow magnetic relaxation. Journal of Molecular Structure 2020, 1210 , 127997. https://doi.org/10.1016/j.molstruc.2020.127997
- Zhong-Yi Li, Xue-Qing Zhou, Rong-Rong Zhang, Xiang-Fei Zhang, Dong-Qing Wu, Bin Zhai. A new approach to prepare the Mn(II)-based magnetic refrigerant through incorporating diamagnetic Cd(II) ion. Inorganica Chimica Acta 2020, 506 , 119527. https://doi.org/10.1016/j.ica.2020.119527
- Zhong-Yi Li, Hui Zhang, Fen-Fen Wang, Fu-Li Zhang, Chi Zhang, Bin Zhai. Two series of lanthanide complexes with 4-chlorophenylacetate ligand displaying luminescence and significant magnetocaloric effect. Journal of Molecular Structure 2020, 1208 , 127887. https://doi.org/10.1016/j.molstruc.2020.127887
- A. V. Pavlishchuk, V. V. Pavlishchuk. Principles for Creating “Molecular Refrigerators” Derived from Gadolinium(III) Coordination Compounds: A Review. Theoretical and Experimental Chemistry 2020, 56
(1)
, 1-25. https://doi.org/10.1007/s11237-020-09635-5
- Hong Yu, Jia-Miao Cao, Jun-Rui Zhang, Rui-Cong Li, Yan Cheng, Chen Yang, Yin-Ling Hou, Ming Fang. Single molecule magnet behavior and magnetic refrigeration of four tetranuclear lanthanide (Ln = Gd
III
, Tb
III
, Dy
III
) clusters. New Journal of Chemistry 2019, 43
(48)
, 19429-19436. https://doi.org/10.1039/C9NJ04260A
- Siba Prasad Bera, Arpan Mondal, Sanjit Konar. Lanthanide‐Based Layer‐Type Two‐Dimensional Coordination Polymers Featuring Slow Magnetic Relaxation, Magnetocaloric Effect and Proton Conductivity. Chemistry – An Asian Journal 2019, 14
(20)
, 3702-3711. https://doi.org/10.1002/asia.201900842
- Sui-Jun Liu, Song-De Han, Jiong-Peng Zhao, Jialiang Xu, Xian-He Bu. In-situ synthesis of molecular magnetorefrigerant materials. Coordination Chemistry Reviews 2019, 394 , 39-52. https://doi.org/10.1016/j.ccr.2019.05.009
- Dou-Dou Feng, Yu-Di Zhao, Xiao-Qing Wang, Dong-Dong Fang, Jing Tang, Li-Ming Fan, Jie Yang. Two novel metal–organic frameworks based on pyridyl-imidazole-carboxyl multifunctional ligand: selective CO
2
capture and multiresponsive luminescence sensor. Dalton Transactions 2019, 48
(29)
, 10892-10900. https://doi.org/10.1039/C9DT01430F
- Hong Yu, Jia-Xing Yang, Ju-Qing Han, Peng-Fei Li, Yin-Ling Hou, Wen-Min Wang, Ming Fang. Tetranuclear lanthanide complexes showing magnetic refrigeration and single molecule magnet behavior. New Journal of Chemistry 2019, 43
(21)
, 8067-8074. https://doi.org/10.1039/C8NJ05109G
- Jun-Jie Wang, Pan-Pan Si, Jie Yang, Shan-Shan Zhao, Pan-Pan Li, Bo Li, Si-Yin Wang, Ming Lu, Su-Xin Yu. La(III)-based MOFs with 5-aminoisophthalic acid for optical detection and degradation of organic molecules in water. Polyhedron 2019, 162 , 255-262. https://doi.org/10.1016/j.poly.2019.01.045
- Shuvayan Roy, Sagar Ghosh, Daniel O. T. A. Martins, Floriana Tuna, Sasankasekhar Mohanta. Synthesis, Crystal Structures, and Magnetic Properties of New Hexanuclear Mn
III
2
Ln
III
4
Complexes: SMM Behavior of the Terbium(III) Analogue. European Journal of Inorganic Chemistry 2018, 2018
(48)
, 5191-5202. https://doi.org/10.1002/ejic.201800792
- Yue Han, Song-De Han, Jie Pan, Yu-Juan Ma, Guo-Ming Wang. An excellent cryogenic magnetic cooler: magnetic and magnetocaloric study of an inorganic frame material. Materials Chemistry Frontiers 2018, 2
(12)
, 2327-2332. https://doi.org/10.1039/C8QM00439K
- Siba Prasad Bera, Arpan Mondal, Subhadip Roy, Bijoy Dey, Atanu Santra, Sanjit Konar. 3D isomorphous lanthanide coordination polymers displaying magnetic refrigeration, slow magnetic relaxation and tunable proton conduction. Dalton Transactions 2018, 47
(43)
, 15405-15415. https://doi.org/10.1039/C8DT03498B
- Xiaojun Xie, Tiejun Li, Mingyu Sui, Lili Han, Zhipeng Ci, Jiachi Zhang, Haiyan Jiao, Yuhua Wang. A potential temperature-sensitive fluorescent material based on thermal coupling effect for temperature sensors. Energy 2018, 159 , 429-439. https://doi.org/10.1016/j.energy.2018.06.176
- Yunhui Yang, Xiaofei Liu, Zhiyong Guo, Hongbing Zhan. A series of near-infrared rare earth metal–organic frameworks based on a ketone functionalized aromatic tricarboxylate ligand. Inorganic Chemistry Communications 2018, 92 , 18-21. https://doi.org/10.1016/j.inoche.2018.03.023
- Jianhang Shi, Shiqi Yin, Mohindar S. Seehra, Menka Jain. Enhancement in magnetocaloric properties of ErCrO3 via A-site Gd substitution. Journal of Applied Physics 2018, 123
(19)
https://doi.org/10.1063/1.5022584
- Liangqin Huo, Liming Fan, Jie Zhang, Lingling Gao, Lijun Zhai, Xiaoqing Wang, Tuoping Hu. Three novel coordination polymers based on tris(p-carboxyphenyl)phosphane oxide: Syntheses, structural characterization and magnetic properties. Journal of Solid State Chemistry 2018, 261 , 37-42. https://doi.org/10.1016/j.jssc.2018.02.007
- V. Franco, J.S. Blázquez, J.J. Ipus, J.Y. Law, L.M. Moreno-Ramírez, A. Conde. Magnetocaloric effect: From materials research to refrigeration devices. Progress in Materials Science 2018, 93 , 112-232. https://doi.org/10.1016/j.pmatsci.2017.10.005
- Liang-Qin Huo, Ling-Ling Gao, Jian-Feng Gao, Fu-Qiang An, Xiao-Yan Niu, Tuo-Ping Hu. Three coordination polymers based on tris(p-carboxyphenyl) phosphane oxide with luminescent sensing acetone, nitrobenzene derivatives and Fe3+ ion. Inorganic Chemistry Communications 2018, 89 , 83-88. https://doi.org/10.1016/j.inoche.2018.01.021
- Mei-Na Zhang, Ting-Ting Fan, Qiu-Shuang Wang, Hong-Liang Han, Xia Li. Zn/Cd/Cu- frameworks constructed by 3,3′-diphenyldicarboxylate and 1,4-bis(1,2,4-triazol-1-yl)butane: Syntheses, structure, luminescence and luminescence sensing for metal ion in aqueous medium. Journal of Solid State Chemistry 2018, 258 , 744-752. https://doi.org/10.1016/j.jssc.2017.12.005
- Xiao-Yan Lin, Li-Ming Zhao, Dao-Hua Wang, Yu-Kang Wang, Min Li, Hao-Hong Li, Zhi-Rong Chen. Structural diversities of squarate-based complexes: photocurrent responses and thermochromic behaviours enchanced by viologens. Inorganic Chemistry Frontiers 2018, 5
(1)
, 189-199. https://doi.org/10.1039/C7QI00672A
- Sagar Ghosh, Shuvankar Mandal, Mukesh Kumar Singh, Cai-Ming Liu, Gopalan Rajaraman, Sasankasekhar Mohanta. Experimental and theoretical exploration of magnetic exchange interactions and single-molecule magnetic behaviour of bis(η
1
:η
2
:μ
2
-carboxylate)GdIII2/DyIII2 systems. Dalton Transactions 2018, 47
(33)
, 11455-11469. https://doi.org/10.1039/C8DT02008F
- Ming Fang, Li-Jun Shao, Tian-Xing Shi, Ying-Ying Chen, Hong Yu, Peng-Fei Li, Wen-Min Wang, Bin Zhao. Four tetra-nuclear lanthanide complexes based on 8-hydroxyquinolin derivatives: magnetic refrigeration and single-molecule magnet behaviour. New Journal of Chemistry 2018, 42
(14)
, 11847-11853. https://doi.org/10.1039/C8NJ02161A
- Sagar Ghosh, Nairita Hari, Dawid Pinkowicz, Magdalena Fitta, Sasankasekhar Mohanta. Syntheses, crystal structures and magnetic properties of a series of ZnII2LnIII2 compounds (Ln = Gd, Tb, Dy, Ho and Er): contrasting structural and magnetic features. New Journal of Chemistry 2018, 42
(19)
, 15917-15929. https://doi.org/10.1039/C8NJ02532K
- Yuan Gao, Marta Viciano-Chumillas, Ana Maria Toader, Simon J. Teat, Marilena Ferbinteanu, Stefania Tanase. Cyanide-bridged coordination polymers constructed from lanthanide ions and octacyanometallate building-blocks. Inorganic Chemistry Frontiers 2018, 5
(8)
, 1967-1977. https://doi.org/10.1039/C8QI00357B
- Shu‐Li Yao, Chen Cao, Xue‐Mei Tian, Teng‐Fei Zheng, Sui‐Jun Liu, Xiao‐Lan Tong, Jin‐Sheng Liao, Jing‐Lin Chen, He‐Rui Wen. Three Gd‐Based Metal‐Organic Frameworks Constructed from Similar Dicarboxylate Ligands with Large Magnetic Entropy Changes. ChemistrySelect 2017, 2
(33)
, 10673-10677. https://doi.org/10.1002/slct.201702223
- Wen-Min Wang, Wei-Wei Duan, Li-Chun Yue, Yu-Ling Wang, Wen-Yan Ji, Cai-Feng Zhang, Ming Fang, Zhi-Lei Wu. Magnetic refrigeration and single-molecule magnet behaviour of two lanthanide dinuclear complexes (Ln = GdIII, TbIII) based on 8-hydroxyquinolin derivatives. Inorganica Chimica Acta 2017, 466 , 145-150. https://doi.org/10.1016/j.ica.2017.05.059
- Wen-Min Wang, Hong-Hong Liu, Liu-Ting He, Xue-Rong Han, Zhi-Lei Wu, Yun-Gen Ran, Ji-Yong Zou, Ming Fang. Structures, luminescence properties, magnetocaloric effect and slow magnetic relaxation of three Ln (III) complexes based on 8‑hydroxyquinoline Schiff-base ligand. Polyhedron 2017, 133 , 119-124. https://doi.org/10.1016/j.poly.2017.04.034
- Zheng Zhu, Lian-sheng Cui, Chuan-bin Fan, Xiao-yin Zhang, Dong-mei Zhang, Fan Jin, Yu-hua Fan. Syntheses, structures, photocatalysis properties and photoluminescent properties of four two-dimensional functional coordination polymers based on a semi-rigid tetracarboxylic acid. Polyhedron 2017, 133 , 374-382. https://doi.org/10.1016/j.poly.2017.05.034
- Wen-Min Wang, Xiao-Fen Guan, Xiao-Di Liu, Meng Fang, Cai-Feng Zhang, Ming Fang, Zhi-Lei Wu. Two Gd 2 compounds constructed by 8-hydroxyquinoline Schiff base ligands: Synthesis, structure, and magnetic refrigeration. Inorganic Chemistry Communications 2017, 79 , 8-11. https://doi.org/10.1016/j.inoche.2017.03.014
- Sourav Biswas, Sourav Das, Joydev Acharya, Vierandra Kumar, Jan van Leusen, Paul Kögerler, Juan Manuel Herrera, Enrique Colacio, Vadapalli Chandrasekhar. Homometallic Dy
III
Complexes of Varying Nuclearity from 2 to 21: Synthesis, Structure, and Magnetism. Chemistry – A European Journal 2017, 23
(21)
, 5154-5170. https://doi.org/10.1002/chem.201700471
- Zheng Zhu, Xiang-min Meng, Dong-mei Zhang, Xia Zhang, Mei Wang, Fan Jin, Yu-hua Fan. Syntheses, structures and selective dye adsorption of five formic-based coordination polymers prepared by in-situ hydrolysis of N, N′-dimethylformamide. Journal of Solid State Chemistry 2017, 248 , 109-118. https://doi.org/10.1016/j.jssc.2017.01.027
- Elena Bartolomé, Ana Arauzo, Javier Luzón, Juan Bartolomé, Fernando Bartolomé. Magnetic Relaxation of Lanthanide-Based Molecular Magnets. 2017, 1-289. https://doi.org/10.1016/bs.hmm.2017.09.002
- He-Rui Wen, Piao-Ping Dong, Fu-Yong Liang, Sui-Jun Liu, Xin-Rong Xie, Yun-Zhi Tang. A family of 2D lanthanide complexes based on flexible thiodiacetic acid with magnetocaloric or ferromagnetic properties. Inorganica Chimica Acta 2017, 455 , 190-196. https://doi.org/10.1016/j.ica.2016.10.026
- Sui-Jun Liu, Shu-Li Yao, Chen Cao, Teng-Fei Zheng, Cao Liu, Zheng-Xiang Wang, Qiang Zhao, Jin-Sheng Liao, Jing-Lin Chen, He-Rui Wen. Two di- and trinuclear Gd(III) clusters derived from monocarboxylates exhibiting significant magnetic entropy changes. Polyhedron 2017, 121 , 180-184. https://doi.org/10.1016/j.poly.2016.09.040
- Sui-Jun Liu, Chen Cao, Shu-Li Yao, Teng-Fei Zheng, Zheng-Xiang Wang, Chao Liu, Jin-Sheng Liao, Jing-Lin Chen, Yun-Wu Li, He-Rui Wen. Temperature- and vapor-induced reversible single-crystal-to-single-crystal transformations of three 2D/3D Gd
III
–organic frameworks exhibiting significant magnetocaloric effects. Dalton Transactions 2017, 46
(1)
, 64-70. https://doi.org/10.1039/C6DT03589B
- Muhammad Nadeem Akhtar, Yan-Cong Chen, Murad A. AlDamen, Ming-Liang Tong. 3D oxalato-bridged lanthanide(
iii
) MOFs with magnetocaloric, magnetic and photoluminescence properties. Dalton Transactions 2017, 46
(1)
, 116-124. https://doi.org/10.1039/C6DT03843C
- Feng Liu, Hong Huang, Wei Gao, Xiu-Mei Zhang, Jie-Ping Liu. 3D Ln-MOFs containing pentanuclear clusters exhibiting magnetic refrigeration and slow magnetic relaxation. CrystEngComm 2017, 19
(26)
, 3660-3665. https://doi.org/10.1039/C7CE00698E
- Peng Hu, Lei Yin, Nan-nan Mao, Fan Yu, Bao Li, Zhen-xing Wang, Tianle Zhang. A series of six-membered lanthanide rings based on 2,2-bis(hydroxymethyl)-2,2′,2″-nitrilotriethanol: synthesis, crystal structures and magnetic properties. CrystEngComm 2017, 19
(32)
, 4807-4814. https://doi.org/10.1039/C7CE01063J
- Teng-Fei Zheng, Shu-Li Yao, Chen Cao, Sui-Jun Liu, Hui-Kang Hu, Tao Zhang, Hai-Ping Huang, Jin-Sheng Liao, Jing-Lin Chen, He-Rui Wen. Large magnetic entropy changes in three Gd
III
coordination polymers containing Gd
III
chains. New Journal of Chemistry 2017, 41
(16)
, 8598-8603. https://doi.org/10.1039/C7NJ01463E
- Sourav Biswas, Sourav Das, Tulika Gupta, Saurabh Kumar Singh, Michael Pissas, Gopalan Rajaraman, Vadapalli Chandrasekhar. Observation of Slow Relaxation and Single‐Molecule Toroidal Behavior in a Family of Butterfly‐Shaped Ln
4
Complexes. Chemistry – A European Journal 2016, 22
(51)
, 18532-18550. https://doi.org/10.1002/chem.201603640
- Yi‐Ming Li, Wei‐Wei Kuang, Li‐Li Zhu, Yun Xu, Pei‐Pei Yang. Two Discrete Ln
12
Shelf‐Shaped Clusters: Magnetic Studies Reveal a Significant Cryogenic Magnetocaloric Effect and Slow Magnetic Relaxation. European Journal of Inorganic Chemistry 2016, 2016
(31)
, 4996-5003. https://doi.org/10.1002/ejic.201600556
- Sourav Biswas, Sourav Das, Sakiat Hossain, Arun Kumar Bar, Jean‐Pascal Sutter, Vadapalli Chandrasekhar. Tetranuclear Lanthanide(III) Complexes Containing a Square‐Grid Core: Synthesis, Structure, and Magnetism. European Journal of Inorganic Chemistry 2016, 2016
(28)
, 4683-4692. https://doi.org/10.1002/ejic.201600744
- Shaowei Zhang, Peng Cheng. Magnetocaloric Effect of Two Isostructural Heterometallic Organic Frameworks Based on {M
II
Gd
III
2
} Clusters (M
II
=Mn, Ni). ChemPlusChem 2016, 81
(8)
, 811-816. https://doi.org/10.1002/cplu.201600143
- Shaowei Zhang, Peng Cheng. Coordination‐Cluster‐Based Molecular Magnetic Refrigerants. The Chemical Record 2016, 16
(4)
, 2077-2126. https://doi.org/10.1002/tcr.201600038
- Teng-Fei Zheng, Chen Cao, Piao-Ping Dong, Sui-Jun Liu, Feng-Feng Wang, Xiao-Lan Tong, Jin-Sheng Liao, Jing-Lin Chen, He-Rui Wen. Synthesis, structures and magnetocaloric properties of two dinuclear GdIII clusters derived from monocarboxylate ligands. Polyhedron 2016, 113 , 96-101. https://doi.org/10.1016/j.poly.2016.04.011
- Sourav Biswas, Sourav Das, Guillaume Rogez, Vadapalli Chandrasekhar. Hydrazone‐Ligand‐Based Homodinuclear Lanthanide Complexes: Synthesis, Structure, and Magnetism. European Journal of Inorganic Chemistry 2016, 2016
(20)
, 3322-3329. https://doi.org/10.1002/ejic.201600335
- Y. Ren, H. Chai, M. An, L. Gao, G. Zhou. Two 3D zinc-bpe frameworks constructed from 2-carboxyl/sulfo-terephthalate: Crystal structures and luminescent properties. Russian Journal of Coordination Chemistry 2016, 42
(5)
, 338-344. https://doi.org/10.1134/S1070328416050067
- Roberto Köferstein, Christian Robl. Synthesis, Crystal Structure, and Hydrogen Bonding of μ‐Hydroxo‐μ‐peroxo‐bis[bis(ethylenediamine)cobalt(III)] Squarate. Zeitschrift für anorganische und allgemeine Chemie 2016, 642
(7)
, 560-565. https://doi.org/10.1002/zaac.201600080
- Jiang‐Zhen Qiu, Long‐Fei Wang, Yan‐Cong Chen, Ze‐Min Zhang, Quan‐Wen Li, Ming‐Liang Tong. Magnetocaloric Properties of Heterometallic 3d–Gd Complexes Based on the [Gd(oda)
3
]
3−
Metalloligand. Chemistry – A European Journal 2016, 22
(2)
, 802-808. https://doi.org/10.1002/chem.201503796
- Sheng-Chun Chen, An-Qi Dai, Kun-Lin Huang, Zhi-Hui Zhang, Ai-Jun Cui, Ming-Yang He, Qun Chen. Assembly of 1D, 2D and 3D lanthanum(
iii
) coordination polymers with perchlorinated benzenedicarboxylates: positional isomeric effect, structural transformation and ring-opening polymerisation of glycolide. Dalton Transactions 2016, 45
(8)
, 3577-3589. https://doi.org/10.1039/C5DT04687D
- Tuo-Ping Hu, Zhi-Jia Xue, Bao-Hua Zheng, Xiao-Qing Wang, Xue-Na Hao, You Song. Two novel nickel(
ii
) and cobalt(
ii
) metal–organic frameworks based on a rigid aromatic multicarboxylate ligand: syntheses, structural characterization and magnetic properties. CrystEngComm 2016, 18
(28)
, 5386-5392. https://doi.org/10.1039/C6CE00674D
- Xiao-Xiao Wang, Xiao-Qing Wang, Xiao-Yan Niu, Tuo-Ping Hu. Three novel metal–organic frameworks based on an unsymmetrical rigid carboxylate ligand for luminescence sensing of nitrobenzene derivatives and magnetic properties. CrystEngComm 2016, 18
(39)
, 7471-7477. https://doi.org/10.1039/C6CE01457G
- Jin-Xia Yang, Ye-Yan Qin, Run-Ping Ye, Xin Zhang, Yuan-Gen Yao. Employing mixed-ligand strategy to construct a series of luminescent Cd(
ii
) compounds with structural diversities. CrystEngComm 2016, 18
(42)
, 8309-8320. https://doi.org/10.1039/C6CE01607C
- Sui-Jun Liu, Chen Cao, Chen-Chao Xie, Teng-Fei Zheng, Xiao-Lan Tong, Jin-Sheng Liao, Jing-Lin Chen, He-Rui Wen, Ze Chang, Xian-He Bu. Tricarboxylate-based Gd
III
coordination polymers exhibiting large magnetocaloric effects. Dalton Transactions 2016, 45
(22)
, 9209-9215. https://doi.org/10.1039/C6DT01349J
- Soumava Biswas, Himanshu Sekhar Jena, Suresh Sanda, Sanjit Konar. Proton‐Conducting Magnetic Coordination Polymers. Chemistry – A European Journal 2015, 21
(39)
, 13793-13801. https://doi.org/10.1002/chem.201501526
- Suresh Sanda, Soumava Biswas, Srinivasulu Parshamoni, Sanjit Konar. Unraveling the multi-functional behavior in a series of Metal Organic Frameworks. Journal of Solid State Chemistry 2015, 229 , 103-111. https://doi.org/10.1016/j.jssc.2015.05.012
- Amita Malviya, Himanshu Sekhar Jena, Amit Kumar Mondal, Sanjit Konar. Europium‐Based Dinuclear Triple‐Stranded Helicate vs. Tetranuclear Quadruple‐Stranded Helicate: Effect of Stoichiometric Ratio on the Supramolecular Self‐Assembly. European Journal of Inorganic Chemistry 2015, 2015
(17)
, 2901-2907. https://doi.org/10.1002/ejic.201500301
- Jin-Zhong Qiao, Mao-Sheng Zhan, Tuo-Ping Hu. One novel 3D tetranuclear cadmium coordination polymer based on 2,3′,4,5′-biphenyltetracarboxylic acid: Synthesis, crystal structure and luminescence. Inorganic Chemistry Communications 2015, 55 , 157-160. https://doi.org/10.1016/j.inoche.2015.03.019
- Ana María Atria, Maria Teresa Garland, Ricardo Baggio. Three isotypic polymeric complexes with rare earth cations, but-2-enoate anions and 4,4′-(ethane-1,2-diyl)dipyridine and 4,4′-(ethene-1,2-diyl)dipyridine bridging ligands. Acta Crystallographica Section C Structural Chemistry 2015, 71
(4)
, 301-305. https://doi.org/10.1107/S2053229615004751
- Yi‐Xia Ren, Miao An, Hong‐Mei Chai, Mei‐Li Zhang, Ji‐Jiang Wang. Cooperation of Coordinative and π···π Interaction in Directing Two‐fold Interpenetrated Architecture of Two Eu/Dy(III) 2‐Sulfoterephthalate Complexes with 4,4′‐Bipyridine. Zeitschrift für anorganische und allgemeine Chemie 2015, 641
(3-4)
, 525-528. https://doi.org/10.1002/zaac.201400488
- Yan-Fei He, Di-Ming Chen, Hang Xu, Peng Cheng. Structural diversity of luminescent lanthanide metal–organic frameworks based on a V-shaped ligand. CrystEngComm 2015, 17
(12)
, 2471-2478. https://doi.org/10.1039/C4CE02380C
- Mei Zhu, Juanjuan Wang, Meng Yang, Yue Ma, Licun Li. Slow magnetic relaxation in two-dimensional 3d–4f complexes based on phenyl pyrimidyl substituted nitronyl nitroxide radicals. Dalton Transactions 2015, 44
(21)
, 9815-9822. https://doi.org/10.1039/C4DT03330B
- Sui-Jun Liu, Xin-Rong Xie, Teng-Fei Zheng, Jun Bao, Jin-Sheng Liao, Jing-Lin Chen, He-Rui Wen. Three-dimensional two-fold interpenetrated Cr
III
–Gd
III
heterometallic framework as an attractive cryogenic magnetorefrigerant. CrystEngComm 2015, 17
(38)
, 7270-7275. https://doi.org/10.1039/C5CE00997A
- Tuoping Hu, Baohua Zheng, Xiaoqing Wang, Xuena Hao. Syntheses, structures and magnetic properties of four manganese(
ii
) and cobalt(
ii
) complexes. CrystEngComm 2015, 17
(48)
, 9348-9356. https://doi.org/10.1039/C5CE01857A
- Amit Adhikary, Himanshu Sekhar Jena, Sanjit Konar. A family of Fe
3+
based double-stranded helicates showing a magnetocaloric effect, and Rhodamine B dye and DNA binding activities. Dalton Transactions 2015, 44
(35)
, 15531-15543. https://doi.org/10.1039/C5DT01569C
- Hai-Yun Shen, Wen-Min Wang, Yan-Xia Bi, Hong-Ling Gao, Shuang Liu, Jian-Zhong Cui. Luminescence, magnetocaloric effect and single-molecule magnet behavior in lanthanide complexes based on a tridentate ligand derived from 8-hydroxyquinoline. Dalton Transactions 2015, 44
(43)
, 18893-18901. https://doi.org/10.1039/C5DT02894A
Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.
Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.
The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.