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Two Isostructural 3D Lanthanide Coordination Networks (Ln = Gd3+, Dy3+) with Squashed Cuboid-Type Nanoscopic Cages Showing Significant Cryogenic Magnetic Refrigeration and Slow Magnetic Relaxation
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    Two Isostructural 3D Lanthanide Coordination Networks (Ln = Gd3+, Dy3+) with Squashed Cuboid-Type Nanoscopic Cages Showing Significant Cryogenic Magnetic Refrigeration and Slow Magnetic Relaxation
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    Department of Chemistry, IISER Bhopal, Bhopal 462066, India
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2014, 53, 8, 3926–3928
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    https://doi.org/10.1021/ic4030316
    Published April 1, 2014
    Copyright © 2014 American Chemical Society

    Abstract

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    Two isostructural lanthanide-based 3D coordination networks [Ln = Gd3+ (1), Dy3+(2)] with densely packed distorted cuboid nanoscopic cages are reported for the first time. Magnetic characterization reveals that complex 1 shows a significant cryogenic magnetocaloric effect (−ΔSm = 44 J kg–1 K–1), whereas 2 shows slow relaxation of magnetization.

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    X-ray crystallographic data in CIF format, synthetic details, materials and method, structural figures, PXRD and TGA plots, magnetic plots and crystallographic table, tables containing bond distances and angles, and hydrogen-bonding parameters. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2014, 53, 8, 3926–3928
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    https://doi.org/10.1021/ic4030316
    Published April 1, 2014
    Copyright © 2014 American Chemical Society

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