ACS Publications. Most Trusted. Most Cited. Most Read
Direct Access to Hierarchically Porous Inorganic Oxide Materials with Three-Dimensionally Interconnected Networks

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2014, 136, 45, 16066-16072
    Article

    Direct Access to Hierarchically Porous Inorganic Oxide Materials with Three-Dimensionally Interconnected Networks
    Click to copy article linkArticle link copied!

    View Author Information
    † Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), Pohang 790-784, Republic of Korea
    ‡ Center for Computational Science, Korea Institute of Science and Technology (KIST), Seoul 136-791, Republic of Korea
    § Beamline Division, Pohang Light Source, Pohang 790-784, Republic of Korea
    [email protected]
    Other Access OptionsSupporting Information (2)

    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2014, 136, 45, 16066–16072
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ja5091172
    Published October 22, 2014
    Copyright © 2014 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    Hierarchically porous oxide materials have immense potential for applications in catalysis, separation, and energy devices, but the synthesis of these materials is hampered by the need to use multiple templates and the associated complicated steps and uncontrollable mixing behavior. Here we report a simple one-pot strategy for the synthesis of inorganic oxide materials with multiscale porosity. The inorganic precursor and block copolymer are coassembled into an ordered mesostructure (microphase separation), while the in situ-polymerized organic precursor forms organic-rich macrodomains (macrophase separation) around which the mesostructure grows. Calcination generates hierarchical meso/macroporous SiO2 and TiO2 with three-dimensionally interconnected pore networks. The continuous 3D macrostructures were clearly visualized by nanoscale X-ray computed tomography. The resulting TiO2 was used as the anode in a lithium ion battery and showed excellent rate capability compared with mesoporous TiO2. This work is of particular importance because it (i) expands the base of BCP self-assembly from mesostructures to complex porous structures, (ii) shows that the interplay of micro- and macrophase separation can be fully exploited for the design of hierarchically porous inorganic materials, and therefore (iii) provides strategies for researchers in materials science and polymer science.

    Copyright © 2014 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    Experimental details, materials characterization, electrochemical characterization, and supporting data. This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machine-readable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!
    Citation Statements
    Explore this article's citation statements on scite.ai
    powered by  Scite

    This article is cited by 114 publications.

    1. Min Ren, Mengmeng Zhang, Zaiyan Hou, Xinghao Yan, Lianbin Zhang, Jiangping Xu, Jintao Zhu. Bicontinuous Block Copolymer Microparticles through Hydrogen-Bonding-Mediated Dual Phase Separation between Polymer Segments and Fluorinated Additives. ACS Nano 2025, 19 (1) , 1159-1166. https://doi.org/10.1021/acsnano.4c13152
    2. Minkyeong Ban, Dongyoon Woo, Jongkook Hwang, Seongseop Kim, Jinwoo Lee. Spinodal Decomposition-Driven Structural Hierarchy of Mesoporous Inorganic Materials for Energy Applications. Accounts of Chemical Research 2023, 56 (23) , 3428-3440. https://doi.org/10.1021/acs.accounts.3c00524
    3. Keyu Chen, Wenhe Xie, Yu Deng, Jingting Han, Yongheng Zhu, Jianguo Sun, Kaiping Yuan, Limin Wu, Yonghui Deng. Alkaloid Precipitant Reaction Inspired Controllable Synthesis of Mesoporous Tungsten Oxide Spheres for Biomarker Sensing. ACS Nano 2023, 17 (16) , 15763-15775. https://doi.org/10.1021/acsnano.3c03549
    4. Cindy Mutiara Septani, Orion Shih, Yi-Qi Yeh, Ya-Sen Sun. Structural Evolution of a Polystyrene-Block-Poly(Ethylene Oxide) Block Copolymer in Tetrahydrofuran/Water Cosolvents. Langmuir 2022, 38 (19) , 5987-5995. https://doi.org/10.1021/acs.langmuir.2c00041
    5. Wei Han Tu, Geok Leng Seah, Yun Li, Xinghui Wang, Kwan W. Tan. Transient Laser-Annealing-Induced Mesophase Transitions of Block Copolymer–Resol Thin Films. ACS Polymers Au 2022, 2 (1) , 42-49. https://doi.org/10.1021/acspolymersau.1c00040
    6. Seongseop Kim, Won-Gwang Lim, Hyeonae Im, Minkyeong Ban, Jeong Woo Han, Jisung Lee, Jongkook Hwang, Jinwoo Lee. Polymer Interface-Dependent Morphological Transition toward Two-Dimensional Porous Inorganic Nanocoins as an Ultrathin Multifunctional Layer for Stable Lithium–Sulfur Batteries. Journal of the American Chemical Society 2021, 143 (38) , 15644-15652. https://doi.org/10.1021/jacs.1c05562
    7. Geok Leng Seah, Leyan Wang, Li Fang Tan, Chanikarn Tipjanrawee, Wardhana A. Sasangka, Adam K. Usadi, Jonathan M. McConnachie, Kwan W. Tan. Ordered Mesoporous Alumina with Tunable Morphologies and Pore Sizes for CO2 Capture and Dye Separation. ACS Applied Materials & Interfaces 2021, 13 (30) , 36117-36129. https://doi.org/10.1021/acsami.1c06151
    8. Zhi Xu, Le Li, Xiaoxia Chen, Guyu Xiao. N,S-Codoped Mesoporous Carbons Derived from Polymer Micelle-Based Assemblies for the Oxygen Reduction Reaction. ACS Applied Energy Materials 2021, 4 (2) , 1954-1961. https://doi.org/10.1021/acsaem.0c03075
    9. Guokang He, Peng Wang, Kai Feng, Hao Dong, Hongwei Zhao, Fuwei Sun, Hang Yin, Wenyun Li, Guangtao Li. Efficient Fabrication of Diverse Mesostructured Materials from the Self-Assembly of Pyrrole-Containing Block Copolymers and Their Confined Chemical Transformation. Macromolecules 2021, 54 (2) , 906-918. https://doi.org/10.1021/acs.macromol.0c02435
    10. Wei Zhang, Bin Li, Yong-Gang Sun, An-Min Cao, Li-Jun Wan. Spherical Mesoporous Metal Oxides with Tunable Orientation Enabled by Growth Kinetics Control. Journal of the American Chemical Society 2020, 142 (42) , 17897-17902. https://doi.org/10.1021/jacs.0c07938
    11. Cindy M. Septani, Chen-An Wang, U-Ser Jeng, Yu-Chia Su, Bao-Tsan Ko, Ya-Sen Sun. Hierarchically Porous Carbon Materials from Self-Assembled Block Copolymer/Dopamine Mixtures. Langmuir 2020, 36 (40) , 11754-11764. https://doi.org/10.1021/acs.langmuir.0c01431
    12. Seongseop Kim, Mieun Ju, Jisung Lee, Jongkook Hwang, Jinwoo Lee. Polymer Interfacial Self-Assembly Guided Two-Dimensional Engineering of Hierarchically Porous Carbon Nanosheets. Journal of the American Chemical Society 2020, 142 (20) , 9250-9257. https://doi.org/10.1021/jacs.0c00311
    13. Seongbeen Kim, Changhyeok Choi, Jongkook Hwang, Jinkyu Park, Jooyoung Jeong, Hyunwoo Jun, Seonggyu Lee, Soo-Kil Kim, Jong Hyun Jang, Yousung Jung, Jinwoo Lee. Interaction Mediator Assisted Synthesis of Mesoporous Molybdenum Carbide: Mo-Valence State Adjustment for Optimizing Hydrogen Evolution. ACS Nano 2020, 14 (4) , 4988-4999. https://doi.org/10.1021/acsnano.0c01285
    14. Kwan Wee Tan, Ulrich Wiesner. Block Copolymer Self-Assembly Directed Hierarchically Structured Materials from Nonequilibrium Transient Laser Heating. Macromolecules 2019, 52 (2) , 395-409. https://doi.org/10.1021/acs.macromol.8b01766
    15. Yuan Liu, Xiaodong Yan, Bingqing Xu, Jinle Lan, Yunhua Yu, Xiaoping Yang, Yuanhua Lin, Cewen Nan. Self-Reconstructed Formation of a One-Dimensional Hierarchical Porous Nanostructure Assembled by Ultrathin TiO2 Nanobelts for Fast and Stable Lithium Storage. ACS Applied Materials & Interfaces 2018, 10 (22) , 19047-19058. https://doi.org/10.1021/acsami.8b04322
    16. Yongyi Wei, Zhan Mao, Zhenzhong Li, Fang Zhang, Hexing Li. Aerosol-Assisted Rapid Fabrication of a Heterogeneous Organopalladium Catalyst with Hierarchical Bimodal Pores. ACS Applied Materials & Interfaces 2018, 10 (16) , 13914-13923. https://doi.org/10.1021/acsami.8b04543
    17. Jongkook Hwang, Tobias Heil, Markus Antonietti, and Bernhard V. K. J. Schmidt . Morphogenesis of Metal–Organic Mesocrystals Mediated by Double Hydrophilic Block Copolymers. Journal of the American Chemical Society 2018, 140 (8) , 2947-2956. https://doi.org/10.1021/jacs.7b12633
    18. Mohamad Hassan Amin, Putla Sudarsanam, Matthew R. Field, Jim Patel, and Suresh K. Bhargava . Effect of a Swelling Agent on the Performance of Ni/Porous Silica Catalyst for CH4–CO2 Reforming. Langmuir 2017, 33 (40) , 10632-10644. https://doi.org/10.1021/acs.langmuir.7b02753
    19. Xiao-Rong Sun, Zhi-Qiang Cao, Rui-Ying Bao, Zhengying Liu, Bang-Hu Xie, Ming-Bo Yang, and Wei Yang . A Green and Facile Melt Approach for Hierarchically Porous Polylactide Monoliths Based on Stereocomplex Crystallite Network. ACS Sustainable Chemistry & Engineering 2017, 5 (9) , 8334-8343. https://doi.org/10.1021/acssuschemeng.7b02121
    20. Michael G. Fischer, Xiao Hua, Bodo D. Wilts, Ilja Gunkel, Thomas M. Bennett, and Ullrich Steiner . Mesoporous Titania Microspheres with Highly Tunable Pores as an Anode Material for Lithium Ion Batteries. ACS Applied Materials & Interfaces 2017, 9 (27) , 22388-22397. https://doi.org/10.1021/acsami.7b03155
    21. Daniel Mieritz, Xiang Li, Alex Volosin, Minghui Liu, Hao Yan, Nils G. Walter, and Dong-Kyun Seo . Tracking Single DNA Nanodevices in Hierarchically Meso-Macroporous Antimony-Doped Tin Oxide Demonstrates Finite Confinement. Langmuir 2017, 33 (25) , 6410-6418. https://doi.org/10.1021/acs.langmuir.7b00761
    22. Byung Gon Kim, Changshin Jo, Jaeho Shin, Yeongdong Mun, Jinwoo Lee, and Jang Wook Choi . Ordered Mesoporous Titanium Nitride as a Promising Carbon-Free Cathode for Aprotic Lithium-Oxygen Batteries. ACS Nano 2017, 11 (2) , 1736-1746. https://doi.org/10.1021/acsnano.6b07635
    23. Yuan Sheng and Hua Chun Zeng . Monodisperse Aluminosilicate Spheres with Tunable Al/Si Ratio and Hierarchical Macro-Meso-Microporous Structure. ACS Applied Materials & Interfaces 2015, 7 (24) , 13578-13589. https://doi.org/10.1021/acsami.5b03011
    24. Changshin Jo, Yuwon Park, Jooyoung Jeong, Kyu Tae Lee, and Jinwoo Lee . Structural Effect on Electrochemical Performance of Ordered Porous Carbon Electrodes for Na-Ion Batteries. ACS Applied Materials & Interfaces 2015, 7 (22) , 11748-11754. https://doi.org/10.1021/acsami.5b03186
    25. Jongkook Hwang, Changshin Jo, Min Gyu Kim, Jinyoung Chun, Eunho Lim, Seongseop Kim, Sanha Jeong, Youngsik Kim, and Jinwoo Lee . Mesoporous Ge/GeO2/Carbon Lithium-Ion Battery Anodes with High Capacity and High Reversibility. ACS Nano 2015, 9 (5) , 5299-5309. https://doi.org/10.1021/acsnano.5b00817
    26. Seongbeen Kim, Seung-Jae Shin, Hoyoung Kim, Bupmo Kim, Namgyu Noh, Kug-Seung Lee, Jinkyu Park, Hyunwoo Jun, Jiwon Kim, Jaeho Byeon, Seonggyu Lee, Huawei Huang, Sunghyun Noh, Han Beom Jeong, Jong Hyun Jang, Jong Min Yuk, Wooyul Kim, Hyungjun Kim, Jinwoo Lee. Self-assembly-assisted dynamic placement of noble metals selectively on multifunctional carbide supports for alkaline hydrogen electrocatalysis. Energy & Environmental Science 2025, 18 (2) , 659-673. https://doi.org/10.1039/D4EE04660A
    27. Jongyoon Park, Kangseok Kim, Eunho Lim, Jongkook Hwang. Tuning Internal Accessibility via Nanochannel Orientation of Mesoporous Carbon Spheres for High‐Rate Potassium‐Ion Storage in Hybrid Supercapacitors. Advanced Functional Materials 2025, 35 (5) https://doi.org/10.1002/adfm.202410010
    28. Geok Leng Seah, Edward W. Corcoran, Adam K. Usadi, Jonathan M. McConnachie, Kwan W. Tan. Order–disorder–order mesophase transitions in self-assembled mesoporous alumina for enhanced CO2 adsorption. Materials Today Chemistry 2024, 38 , 102062. https://doi.org/10.1016/j.mtchem.2024.102062
    29. Minkyeong Ban, Jisung Lee, Jioh Kim, Seung‐Jae Shin, Taesoo Kim, Changshin Jo, Jongkook Hwang, Seongseop Kim, Jinwoo Lee. Hierarchically Superstructured Anisotropic Carbon Particles by Multiscale Assembly Driven by Spinodal Decomposition. Small 2024, 20 (13) https://doi.org/10.1002/smll.202306154
    30. Jin Wook Yang, Hee Ryeong Kwon, Jin Ho Seo, Sangwoo Ryu, Ho Won Jang. Nanoporous oxide electrodes for energy conversion and storage devices. RSC Applied Interfaces 2024, 1 (1) , 11-42. https://doi.org/10.1039/D3LF00094J
    31. Jie Jing, Kerun Zhu, Shun Wang, Yihan Gao, Angang Dong, Dong Yang, Zhihong Nie, Wei Zhang. Nanoscale Phase Separations for Versatile Synthesis of Centimeter‐Sized Hierarchically Mesoporous Metal‐Oxide Films. Advanced Materials Technologies 2024, 9 (1) https://doi.org/10.1002/admt.202301350
    32. Longlong Fan, Qinghong Geng, Lian Ma, Chengming Wang, Jun-Xuan Li, Wei Zhu, Ruiwen Shao, Wei Li, Xiao Feng, Yusuke Yamauchi, Cuiling Li, Lei Jiang. Evoking C 2+ production from electrochemical CO 2 reduction by the steric confinement effect of ordered porous Cu 2 O. Chemical Science 2023, 14 (47) , 13851-13859. https://doi.org/10.1039/D3SC04840C
    33. Jörg G. Werner, Yuanzhi Li, Ulrich Wiesner. Block‐Copolymer‐Architected Materials in Electrochemical Energy Storage. Small Science 2023, 3 (12) https://doi.org/10.1002/smsc.202300074
    34. Keon-Woo Kim, Bomi Park, Jun Kim, Changshin Jo, Jin Kon Kim. Recent progress in block copo lymer s oft-template-assisted synthesis of versatile mesoporous materials for energy storage systems. Journal of Materials Chemistry A 2023, 11 (14) , 7358-7386. https://doi.org/10.1039/D2TA09353G
    35. Cindy Mutiara Septani, Meng-Fan Ku, Chun-Yu Chen, Jhih-Min Lin, Ya-Sen Sun. Micellization, aggregation, and gelation of polystyrene-block-poly(ethylene oxide) in cosolvents added with hydrochloric acid. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2022, 652 , 129857. https://doi.org/10.1016/j.colsurfa.2022.129857
    36. Weimin Xie, Jie Wang, Kaixuan Shang, Hongyun Chen, Aidong Tang, Mingjie Wu, Xun Cui, Huaming Yang. A nanoclay-based 3D aerogel framework for flexible flame retardants. Materials Advances 2022, 3 (17) , 6799-6808. https://doi.org/10.1039/D2MA00556E
    37. Rui Luo, Zhengwei Wan, Peng Mei, Zhengjiao Xie, Dean Shi, Yingkui Yang. Cross-linked copolymer-derived nitrogen-doped hierarchical porous carbon with high-performance lithium storage capability. Materials Advances 2022, 3 (16) , 6636-6642. https://doi.org/10.1039/D2MA00310D
    38. Leyan Wang, Geok Leng Seah, Yun Li, Wei Han Tu, William Manalastas, Matthew J.‐H. Reavley, Edward W. Corcoran, Adam K. Usadi, Zehui Du, Srinivasan Madhavi, Jonathan M. McConnachie, Hock Guan Ong, Kwan W. Tan. Ultrafast Crystallization of Ordered Mesoporous Metal Oxides and Carbon from Block Copolymer Self‐Assembly and Joule Heating. Advanced Materials Interfaces 2022, 9 (19) https://doi.org/10.1002/admi.202200151
    39. Kayode Adesina Adegoke, Nobanathi Wendy Maxakato. Porous metal oxide electrocatalytic nanomaterials for energy conversion: Oxygen defects and selection techniques. Coordination Chemistry Reviews 2022, 457 , 214389. https://doi.org/10.1016/j.ccr.2021.214389
    40. Suzhe Liang, Xiaoyan Wang, Ya-Jun Cheng, Yonggao Xia, Peter Müller-Buschbaum. Anatase titanium dioxide as rechargeable ion battery electrode - A chronological review. Energy Storage Materials 2022, 45 , 201-264. https://doi.org/10.1016/j.ensm.2021.11.023
    41. Qian Chen, Dandan Yang, Yi Wang, Yan Long, Guangyin Fan. Hollow Hydrangea‐Like CoRu/Co Architecture as an Excellent Electrocatalyst for Oxygen Evolution. ChemSusChem 2021, 14 (18) , 3959-3966. https://doi.org/10.1002/cssc.202101316
    42. Jiaming Sun, Zhenwei Wu, Bang An, Chunhui Ma, Lifei Xu, Zhanshuo Zhang, Sha Luo, Wei Li, Shouxin Liu. Thermal-insulating, flame-retardant and mechanically resistant aerogel based on bio-inspired tubular cellulose. Composites Part B: Engineering 2021, 220 , 108997. https://doi.org/10.1016/j.compositesb.2021.108997
    43. Biao Yu, Simin Zhang, Xun Wang. Helical Microporous Nanorods Assembled by Polyoxometalate Clusters for the Photocatalytic Oxidation of Toluene. Angewandte Chemie 2021, 133 (32) , 17544-17549. https://doi.org/10.1002/ange.202105587
    44. Biao Yu, Simin Zhang, Xun Wang. Helical Microporous Nanorods Assembled by Polyoxometalate Clusters for the Photocatalytic Oxidation of Toluene. Angewandte Chemie International Edition 2021, 60 (32) , 17404-17409. https://doi.org/10.1002/anie.202105587
    45. Bhuvanenthiran Mutharani, Palraj Ranganathan, Hsieh-Chih Tsai, Juin-Yih Lai. RETRACTED ARTICLE: Synthesis of hierarchically porous 3D polymeric carbon superstructures with nitrogen-doping by self-transformation: a robust electrocatalyst for the detection of herbicide bentazone. Microchimica Acta 2021, 188 (8) https://doi.org/10.1007/s00604-021-04910-1
    46. Zirun Chen, Shaohong Liu, Luyi Chen, Junlong Huang, Bingna Zheng, Wen Huang, Shimei Li, Yuheng Lu, Ruowen Fu. A scalable molecular-templating strategy toward well-defined microporous carbon aerogels for efficient water treatment and electrocatalysis. Chemical Engineering Journal 2021, 418 , 129315. https://doi.org/10.1016/j.cej.2021.129315
    47. Hailong Xiong, Ruicheng Qian, Zhilin Liu, Rui Zhang, Ge Sun, Bingkun Guo, Fei Du, Shuyan Song, Zhen‐An Qiao, Sheng Dai. A Polymer‐Assisted Spinodal Decomposition Strategy toward Interconnected Porous Sodium Super Ionic Conductor‐Structured Polyanion‐Type Materials and Their Application as a High‐Power Sodium‐Ion Battery Cathode. Advanced Science 2021, 8 (11) https://doi.org/10.1002/advs.202004943
    48. Jongkook Hwang. A review of synthesis strategies for MOF-derived single atom catalysts. Korean Journal of Chemical Engineering 2021, 38 (6) , 1104-1116. https://doi.org/10.1007/s11814-021-0741-4
    49. Ryan R. Larder, Thomas M. Bennett, L. Scott Blankenship, Jesum A. Fernandes, Bethany K. Husband, Rachel L. Atkinson, Matthew J. Derry, Daniel T. W. Toolan, Higor A. Centurion, Paul D. Topham, Renato V. Gonçalves, Vincenzo Taresco, Steven M. Howdle. Porous hollow TiO 2 microparticles for photocatalysis: exploiting novel ABC triblock terpolymer templates synthesised in supercritical CO 2. Polymer Chemistry 2021, 12 (19) , 2904-2913. https://doi.org/10.1039/D1PY00334H
    50. Jongyoon Park, Jiyun Lee, Seongseop Kim, Jongkook Hwang. Graphene-Based Two-Dimensional Mesoporous Materials: Synthesis and Electrochemical Energy Storage Applications. Materials 2021, 14 (10) , 2597. https://doi.org/10.3390/ma14102597
    51. Qingqing Sheng, Qian Li, Luoxing Xiang, Tao Huang, Yiyong Mai, Lu Han. Double diamond structured bicontinuous mesoporous titania templated by a block copolymer for anode material of lithium-ion battery. Nano Research 2021, 14 (4) , 992-997. https://doi.org/10.1007/s12274-020-3139-4
    52. Yash Boyjoo, Haodong Shi, Qiang Tian, Shaomin Liu, Ji Liang, Zhong-Shuai Wu, Mietek Jaroniec, Jian Liu. Engineering nanoreactors for metal–chalcogen batteries. Energy & Environmental Science 2021, 14 (2) , 540-575. https://doi.org/10.1039/D0EE03316B
    53. Jürgen Schoiber, Christian Koczwara, Simon Rumswinkel, Lawrence Whitmore, Christian Prehal, Florian Putz, Michael S. Elsaesser, Oskar Paris, Nicola Hüsing. A Facile One‐Pot Synthesis of Hierarchically Organized Carbon/TiO 2 Monoliths with Ordered Mesopores. ChemPlusChem 2021, 86 (2) , 275-283. https://doi.org/10.1002/cplu.202000740
    54. Eunho Lim, Jinyoung Chun, Changshin Jo, Jongkook Hwang. Recent advances in the synthesis of mesoporous materials and their application to lithium-ion batteries and hybrid supercapacitors. Korean Journal of Chemical Engineering 2021, 38 (2) , 227-247. https://doi.org/10.1007/s11814-020-0693-0
    55. Limei Qin, Dechao Niu, Nan Li, Xiaofeng Luo, Xing Qin, Jianzhuang Chen, Yongsheng Li, Jianlin Shi. Hydrophobicity-induced electrostatic interfacial self-assembly for porous silica nanospheres with tunable pore sizes and pore hierarchies. Chemical Engineering Journal 2021, 405 , 126936. https://doi.org/10.1016/j.cej.2020.126936
    56. Seongseop Kim, Jinwoo Lee. Spinodal decomposition: a new approach to hierarchically porous inorganic materials for energy storage. National Science Review 2020, 7 (11) , 1635-1637. https://doi.org/10.1093/nsr/nwz217
    57. Seongseop Kim, Jongkook Hwang, Jisung Lee, Jinwoo Lee. Polymer blend directed anisotropic self-assembly toward mesoporous inorganic bowls and nanosheets. Science Advances 2020, 6 (33) https://doi.org/10.1126/sciadv.abb3814
    58. Chen Li, Qian Li, Yusuf Valentino Kaneti, Dan Hou, Yusuke Yamauchi, Yiyong Mai. Self-assembly of block copolymers towards mesoporous materials for energy storage and conversion systems. Chemical Society Reviews 2020, 49 (14) , 4681-4736. https://doi.org/10.1039/D0CS00021C
    59. Jongkook Hwang, Aleksander Ejsmont, Ralph Freund, Joanna Goscianska, Bernhard V. K. J. Schmidt, Stefan Wuttke. Controlling the morphology of metal–organic frameworks and porous carbon materials: metal oxides as primary architecture-directing agents. Chemical Society Reviews 2020, 49 (11) , 3348-3422. https://doi.org/10.1039/C9CS00871C
    60. Shanshan Yin, Lin Song, Senlin Xia, Yajun Cheng, Nuri Hohn, Wei Chen, Kun Wang, Wei Cao, Shujin Hou, Peter Müller‐Buschbaum. Key Factors for Template‐Oriented Porous Titania Synthesis: Solvents and Catalysts. Small Methods 2020, 4 (3) https://doi.org/10.1002/smtd.201900689
    61. Meng Gao, Jie Zeng, Kang Liang, Dongyuan Zhao, Biao Kong. Interfacial Assembly of Mesoporous Silica‐Based Optical Heterostructures for Sensing Applications. Advanced Functional Materials 2020, 30 (9) https://doi.org/10.1002/adfm.201906950
    62. Apparav Wale, Archana Nalawade, Surendra Ponrathnam, C. R. Rajan, Manohar Badiger. One-pot synthesis of bimodal (macro-meso, micro-mesoporous) silica by polyHIPE: parameter studies. Journal of Porous Materials 2020, 27 (1) , 263-275. https://doi.org/10.1007/s10934-019-00807-w
    63. Jin Zhang, Alfred Mensah, Christopher Narh, Xuebin Hou, Yibing Cai, Hui Qiao, Qufu Wei. Fabrication of flexible TiO2-SiO2 composite nanofibers with variable structure as efficient adsorbent. Ceramics International 2020, 46 (3) , 3543-3549. https://doi.org/10.1016/j.ceramint.2019.10.071
    64. Won‐Gwang Lim, Seoa Kim, Changshin Jo, Jinwoo Lee. A Comprehensive Review of Materials with Catalytic Effects in Li–S Batteries: Enhanced Redox Kinetics. Angewandte Chemie 2019, 131 (52) , 18920-18931. https://doi.org/10.1002/ange.201902413
    65. Won‐Gwang Lim, Seoa Kim, Changshin Jo, Jinwoo Lee. A Comprehensive Review of Materials with Catalytic Effects in Li–S Batteries: Enhanced Redox Kinetics. Angewandte Chemie International Edition 2019, 58 (52) , 18746-18757. https://doi.org/10.1002/anie.201902413
    66. Kwan Wee Tan, , , , , . Laser-induced hierarchically-structured materials from block copolymer self-assembly. 2019, 10. https://doi.org/10.1117/12.2539062
    67. Jongkook Hwang, Ralf Walczak, Martin Oschatz, Nadezda V. Tarakina, Bernhard V. K. J. Schmidt. Micro‐Blooming: Hierarchically Porous Nitrogen‐Doped Carbon Flowers Derived from Metal‐Organic Mesocrystals. Small 2019, 15 (37) https://doi.org/10.1002/smll.201901986
    68. Yaxuan Li, Xinyong Li, Shiying Fan, Jincheng Mu, Zhifan Yin, Hangfan Ma, Shaobin Wang. Facile tailoring of Co-based spinel hierarchical hollow microspheres for highly efficient catalytic conversion of CO2. Journal of Colloid and Interface Science 2019, 552 , 476-484. https://doi.org/10.1016/j.jcis.2019.05.054
    69. Zhaoruxin Guan, Xiaoxue Wang, Tingting Li, Qizhen Zhu, Mengqiu Jia, Bin Xu. Facile synthesis of rutile TiO2/carbon nanosheet composite from MAX phase for lithium storage. Journal of Materials Science & Technology 2019, 35 (9) , 1977-1981. https://doi.org/10.1016/j.jmst.2019.04.021
    70. Bo‐xing Zhang, Yubei Zhang, Zhenhua Luo, Weijian Han, Wenfeng Qiu, Tong Zhao. Monolithic silicon carbide with interconnected and hierarchical pores fabricated by reaction‐induced phase separation. Journal of the American Ceramic Society 2019, 102 (7) , 3860-3869. https://doi.org/10.1111/jace.16263
    71. Shujuan Ma, Luwei Zhang, Shuyue Wang, Haiyang Zhang, Xin You, Junjie Ou, Mingliang Ye, Yinmao Wei. Preparation of epoxy-functionalized hierarchically porous hybrid monoliths via free radical polymerization and application in HILIC enrichment of glycopeptides. Analytica Chimica Acta 2019, 1058 , 97-106. https://doi.org/10.1016/j.aca.2019.01.011
    72. Cheng Wang, Xinwei Liu, Wei Li, Xin Huang, Sen Luan, Xiaojian Hou, Mengnan Zhang, Qian Wang. CO2 mediated fabrication of hierarchically porous metal-organic frameworks. Microporous and Mesoporous Materials 2019, 277 , 154-162. https://doi.org/10.1016/j.micromeso.2018.10.031
    73. Woong Gi Lee, Sang Wook Kang. Control of pore in cellulose acetate containing Mg salt by water pressure treatment for applications to separators. Journal of Industrial and Engineering Chemistry 2019, 70 , 103-106. https://doi.org/10.1016/j.jiec.2018.09.035
    74. Won‐Gwang Lim, Changshin Jo, Ara Cho, Jongkook Hwang, Seongseop Kim, Jeong Woo Han, Jinwoo Lee. Approaching Ultrastable High‐Rate Li–S Batteries through Hierarchically Porous Titanium Nitride Synthesized by Multiscale Phase Separation. Advanced Materials 2019, 31 (3) https://doi.org/10.1002/adma.201806547
    75. Mariana Marcos-Hernández, Dino Villagrán. Mesoporous Composite Nanomaterials for Dye Removal and Other Applications. 2019, 265-293. https://doi.org/10.1016/B978-0-12-814132-8.00012-5
    76. Yuan Liu, Xiaodong Yan, Bingqing Xu, Jinle Lan, Yaochun Liu, Xiaoping Yang, Yuanhua Lin, Cewen Nan. Tunable pseudocapacitive contribution in nanosheet-constructed titania hierarchical tubes to achieve superior lithium-storage properties by phase control. Journal of Materials Chemistry A 2018, 6 (47) , 24298-24310. https://doi.org/10.1039/C8TA09241A
    77. Jingfeng Wang, Yang Li, Yadong Qiao, Guangzhi Yu, Jinzhu Wu, Xiaohong Wu, Wei Qin, Liang Xu. Visible light-enhanced thermal decomposition performance of ammonium perchlorate with a metal–organic framework-derived Ag-embedded porous ZnO nanocomposite. New Journal of Chemistry 2018, 42 (22) , 18001-18009. https://doi.org/10.1039/C8NJ04143A
    78. Jinhwan Kim, Changshin Jo, Won‐Gwang Lim, Sungjin Jung, Yeong Mi Lee, Jun Lim, Haeshin Lee, Jinwoo Lee, Won Jong Kim. Programmed Nanoparticle‐Loaded Nanoparticles for Deep‐Penetrating 3D Cancer Therapy. Advanced Materials 2018, 30 (29) https://doi.org/10.1002/adma.201707557
    79. Jongkook Hwang, Seongseop Kim, Ulrich Wiesner, Jinwoo Lee. Generalized Access to Mesoporous Inorganic Particles and Hollow Spheres from Multicomponent Polymer Blends. Advanced Materials 2018, 30 (27) https://doi.org/10.1002/adma.201801127
    80. Yu Zhang, Qin Yue, Lei Yu, Xuanyu Yang, Xiu‐Feng Hou, Dongyuan Zhao, Xiaowei Cheng, Yonghui Deng. Amphiphilic Block Copolymers Directed Interface Coassembly to Construct Multifunctional Microspheres with Magnetic Core and Monolayer Mesoporous Aluminosilicate Shell. Advanced Materials 2018, 30 (26) https://doi.org/10.1002/adma.201800345
    81. Zhenyuan Liu, Xiaoyu Yang, Lirui Cui, Zhaoping Shi, Bingqing Lu, Xiaomeng Guo, Jubing Zhang, Lin Xu, Yawen Tang, Yan Xiang. High‐Performance Oxygen Reduction Electrocatalysis Enabled by 3D PdNi Nanocorals with Hierarchical Porosity. Particle & Particle Systems Characterization 2018, 35 (5) https://doi.org/10.1002/ppsc.201700366
    82. Zhi‐Long Yu, Ning Yang, Varvara Apostolopoulou‐Kalkavoura, Bing Qin, Zhi‐Yuan Ma, Wei‐Yi Xing, Chan Qiao, Lennart Bergström, Markus Antonietti, Shu‐Hong Yu. Fire‐Retardant and Thermally Insulating Phenolic‐Silica Aerogels. Angewandte Chemie 2018, 130 (17) , 4628-4632. https://doi.org/10.1002/ange.201711717
    83. Zhi‐Long Yu, Ning Yang, Varvara Apostolopoulou‐Kalkavoura, Bing Qin, Zhi‐Yuan Ma, Wei‐Yi Xing, Chan Qiao, Lennart Bergström, Markus Antonietti, Shu‐Hong Yu. Fire‐Retardant and Thermally Insulating Phenolic‐Silica Aerogels. Angewandte Chemie International Edition 2018, 57 (17) , 4538-4542. https://doi.org/10.1002/anie.201711717
    84. Yeongdong Mun, Min Jeong Kim, Shin-Ae Park, Eunsung Lee, Youngjin Ye, Seonggyu Lee, Yong-Tae Kim, Sungjun Kim, Ok-Hee Kim, Yong-Hun Cho, Yung-Eun Sung, Jinwoo Lee. Soft-template synthesis of mesoporous non-precious metal catalyst with Fe-N x /C active sites for oxygen reduction reaction in fuel cells. Applied Catalysis B: Environmental 2018, 222 , 191-199. https://doi.org/10.1016/j.apcatb.2017.10.015
    85. Changshin Jo, Jongkook Hwang, Won‐Gwang Lim, Jun Lim, Kahyun Hur, Jinwoo Lee. Multiscale Phase Separations for Hierarchically Ordered Macro/Mesostructured Metal Oxides. Advanced Materials 2018, 30 (6) https://doi.org/10.1002/adma.201703829
    86. Seongmin Jin, Keon Ho, Chang-Ha Lee. Facile synthesis of hierarchically porous MgO sorbent doped with CaCO3 for fast CO2 capture in rapid intermediate temperature swing sorption. Chemical Engineering Journal 2018, 334 , 1605-1613. https://doi.org/10.1016/j.cej.2017.11.095
    87. Min Chen, Yueguang Zhang, Lidan Xing, Youhao Liao, Yongcai Qiu, Shihe Yang, Weishan Li. Morphology‐Conserved Transformations of Metal‐Based Precursors to Hierarchically Porous Micro‐/Nanostructures for Electrochemical Energy Conversion and Storage. Advanced Materials 2017, 29 (48) https://doi.org/10.1002/adma.201607015
    88. Youngjin Choi, Ji Hoon Jeong, Jaeyun Kim. Mechanically Enhanced Hierarchically Porous Scaffold Composed of Mesoporous Silica for Host Immune Cell Recruitment. Advanced Healthcare Materials 2017, 6 (8) https://doi.org/10.1002/adhm.201601160
    89. Changxiang Zhu, Duo Hu, Zhi Liu. Interconnected three-dimensionally hierarchical heterostructures with homogeneously-dispersed V2O5 nanocrystals and carbon for high performance supercapacitor electrodes. Electrochimica Acta 2017, 229 , 155-165. https://doi.org/10.1016/j.electacta.2017.01.144
    90. Min Su Kim, Eunho Lim, Seongbeen Kim, Changshin Jo, Jinyoung Chun, Jinwoo Lee. General Synthesis of N-Doped Macroporous Graphene-Encapsulated Mesoporous Metal Oxides and Their Application as New Anode Materials for Sodium-Ion Hybrid Supercapacitors. Advanced Functional Materials 2017, 27 (3) , 1603921. https://doi.org/10.1002/adfm.201603921
    91. Seongseop Kim, Inyoung Jeong, Jongkook Hwang, Min Jae Ko, Jinwoo Lee. Simple synthesis of multiple length-scale structured Nb 2 O 5 with functional macrodomain-integrated mesoporous frameworks. Chemical Communications 2017, 53 (29) , 4100-4103. https://doi.org/10.1039/C7CC01400G
    92. Changshin Jo, Won-Gwang Lim, Anh Ha Dao, Seongbeen Kim, Seoa Kim, Songhun Yoon, Jinwoo Lee. Tracking the confinement effect of highly dispersive carbon in a tungsten oxide/carbon nanocomposite: conversion anode materials in lithium ion batteries. Journal of Materials Chemistry A 2017, 5 (47) , 24782-24789. https://doi.org/10.1039/C7TA07979F
    93. Fen Wang, Xing Wang, Jianfeng Zhu, Haibo Yang, Xingang Kong, Xiao Liu. Lightweight NiFe2O4 with controllable 3D network structure and enhanced microwave absorbing properties. Scientific Reports 2016, 6 (1) https://doi.org/10.1038/srep37892
    94. Jinze Lyu, Luna Sun, Junbo Zhong, Qiang Fu, Min Zhang, Shuo Wang, Ji Li. Shielding of surface photogenerated charges by SiO2 coating for the photocatalytic degradation of air pollutants. Chemical Engineering Journal 2016, 303 , 314-321. https://doi.org/10.1016/j.cej.2016.06.014
    95. Weiyang Dong, Youwei Yao, Yaojun Sun, Weiming Hua, Guoshun Zhuang. Preparation of three-dimensional interconnected mesoporous anatase TiO2-SiO2 nanocomposites with high photocatalytic activities. Chinese Journal of Catalysis 2016, 37 (6) , 846-854. https://doi.org/10.1016/S1872-2067(15)61081-6
    96. Wei Li, Jun Liu, Dongyuan Zhao. Mesoporous materials for energy conversion and storage devices. Nature Reviews Materials 2016, 1 (6) https://doi.org/10.1038/natrevmats.2016.23
    97. John B. Cook, Hyung‐Seok Kim, Yan Yan, Jesse S. Ko, Shauna Robbennolt, Bruce Dunn, Sarah H. Tolbert. Mesoporous MoS 2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na‐Ion Charge Storage. Advanced Energy Materials 2016, 6 (9) https://doi.org/10.1002/aenm.201501937
    98. Weiyang Dong, Yaojun Sun, Weiming Hua, Youwei Yao, Guoshun Zhuang, Xinchun Lv, Qingwei Ma, Dongyuan Zhao. Preparation of Secondary Mesopores in Mesoporous Anatase–Silica Nanocomposites with Unprecedented‐High Photocatalytic Degradation Performances. Advanced Functional Materials 2016, 26 (6) , 964-976. https://doi.org/10.1002/adfm.201504001
    99. Wei Wei, Yongcheng Wang, Hao Wu, Abdullah M Al-Enizi, Lijuan Zhang, Gengfeng Zheng. Transition metal oxide hierarchical nanotubes for energy applications. Nanotechnology 2016, 27 (2) , 02LT01. https://doi.org/10.1088/0957-4484/27/2/02LT01
    100. Hai-Bo Huang, Yue Yang, Li-Hua Chen, Yun Wang, Shao-Zhuan Huang, Jia-Wei Tao, Xiao-Ting Ma, Tawfique Hasan, Yu Li, Yan Xu, Bao-Lian Su. Hierarchical TiO 2 /C nanocomposite monoliths with a robust scaffolding architecture, mesopore–macropore network and TiO 2 –C heterostructure for high-performance lithium ion batteries. Nanoscale 2016, 8 (21) , 10928-10937. https://doi.org/10.1039/C5NR09149G
    Load all citations
    Download PDF
    Go to Journal of the American Chemical Society
    Get e-Alerts
    Get e-Alerts

    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2014, 136, 45, 16066–16072
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ja5091172
    Published October 22, 2014
    Copyright © 2014 American Chemical Society
    Request reuse permissions

    Article Views

    5883

    Altmetric

    -

    Citations

    114
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.