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Anion Concentration Gradient-Assisted Construction of a Solid–Electrolyte Interphase for a Stable Zinc Metal Anode at High Rates

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Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2022, 144, 25, 11168-11177
    Article

    Anion Concentration Gradient-Assisted Construction of a Solid–Electrolyte Interphase for a Stable Zinc Metal Anode at High Rates
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    • Xiaofeng He
      Xiaofeng He
      Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
      University of Chinese Academy of Sciences, Beijing 100049, P. R. China
      More by Xiaofeng He
    • Yanglansen Cui
      Yanglansen Cui
      Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
      More by Yanglansen Cui
    • Yongchao Qian
      Yongchao Qian
      Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
      More by Yongchao Qian
    • Yadong Wu
      Yadong Wu
      Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
      University of Chinese Academy of Sciences, Beijing 100049, P. R. China
      More by Yadong Wu
    • Haoyang Ling
      Haoyang Ling
      Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
      University of Chinese Academy of Sciences, Beijing 100049, P. R. China
      More by Haoyang Ling
    • Huanrong Zhang
      Huanrong Zhang
      Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
      More by Huanrong Zhang
    • Xiang-Yu Kong
      Xiang-Yu Kong
      Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
      University of Chinese Academy of Sciences, Beijing 100049, P. R. China
      More by Xiang-Yu Kong
      Orcidhttps://orcid.org/0000-0002-4475-2162
    • Yong Zhao*
      Yong Zhao
      Key Laboratory for Special Functional Materials of Ministry of Education; National & Local Joint Engineering Research Center for High-efficiency Display and Lighting Technology; School of Materials Science and Engineering, Collaborative Innovation Center of Nano Functional Materials and Applications, Henan University, Kaifeng 475004, P. R. China
      *Email: [email protected]
      More by Yong Zhao
      Orcidhttps://orcid.org/0000-0002-5039-4576
    • Mianqi Xue
      Mianqi Xue
      Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
      More by Mianqi Xue
      Orcidhttps://orcid.org/0000-0002-6023-2618
    • Lei Jiang
      Lei Jiang
      Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
      University of Chinese Academy of Sciences, Beijing 100049, P. R. China
      More by Lei Jiang
    • Liping Wen*
      Liping Wen
      Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
      University of Chinese Academy of Sciences, Beijing 100049, P. R. China
      *Email: [email protected]
      More by Liping Wen
      Orcidhttps://orcid.org/0000-0001-8546-8988
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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2022, 144, 25, 11168–11177
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jacs.2c01815
    Published June 6, 2022
    Copyright © 2022 American Chemical Society
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    Abstract

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    Coulombic efficiency (CE) and cycle life of metal anodes (lithium, sodium, zinc) are limited by dendritic growth and side reactions in rechargeable metal batteries. Here, we proposed a concept for constructing an anion concentration gradient (ACG)-assisted solid–electrolyte interphase (SEI) for ultrahigh ionic conductivity on metal anodes, in which the SEI layer is fabricated through an in situ chemical reaction of the sulfonic acid polymer and zinc (Zn) metal. Owing to the driving force of the sulfonate concentration gradient and high bulky sulfonate concentration, a promoted Zn2+ ionic conductivity and inhibited anion diffusion in the SEI layer are realized, resulting in a significant suppression of dendrite growth and side reaction. The presence of ACG-SEI on the Zn metal enables stable Zn plating/stripping over 2000 h at a high current density of 20 mA cm–2 and a capacity of 5 mAh cm–2 in Zn/Zn symmetric cells, and moreover an improved cycling stability is also observed in Zn/MnO2 full cells and Zn/AC supercapacitors. The SEI layer containing anion concentration gradients for stable cycling of a metal anode sheds a new light on the fundamental understanding of cation plating/stripping on metal electrodes and technical advances of rechargeable metal batteries with remarkable performance under practical conditions.

    Copyright © 2022 American Chemical Society

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    Cited By

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    This article is cited by 33 publications.

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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2022, 144, 25, 11168–11177
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jacs.2c01815
    Published June 6, 2022
    Copyright © 2022 American Chemical Society
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