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    Perspective

    Renaissance of Strong Metal–Support Interactions
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    • Ming Xu
      Ming Xu
      Beijing National Laboratory for Molecular Sciences, New Cornerstone Science Laboratory, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
      State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China
      More by Ming Xu
    • Mi Peng
      Mi Peng
      Beijing National Laboratory for Molecular Sciences, New Cornerstone Science Laboratory, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
      More by Mi Peng
      Orcidhttps://orcid.org/0000-0001-7713-4398
    • Hailian Tang
      Hailian Tang
      School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, P. R. China
      More by Hailian Tang
    • Wu Zhou
      Wu Zhou
      School of Physical Sciences, CAS Key Laboratory of Vacuum Physics, University of Chinese Academy of Sciences, Beijing 100049, P. R. China
      More by Wu Zhou
      Orcidhttps://orcid.org/0000-0002-6803-1095
    • Botao Qiao*
      Botao Qiao
      CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China
      *[email protected]
      More by Botao Qiao
      Orcidhttps://orcid.org/0000-0001-6351-455X
    • Ding Ma*
      Ding Ma
      Beijing National Laboratory for Molecular Sciences, New Cornerstone Science Laboratory, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
      *[email protected]
      More by Ding Ma
      Orcidhttps://orcid.org/0000-0002-3341-2998
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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2024, 146, 4, 2290–2307
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    https://doi.org/10.1021/jacs.3c09102
    Published January 18, 2024
    Copyright © 2024 American Chemical Society
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    Abstract

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    Strong metal–support interactions (SMSIs) have emerged as a significant and cutting-edge area of research in heterogeneous catalysis. They play crucial roles in modifying the chemisorption properties, interfacial structure, and electronic characteristics of supported metals, thereby exerting a profound influence on the catalytic properties. This Perspective aims to provide a comprehensive summary of the latest advancements and insights into SMSIs, with a focus on state-of-the-art in situ/operando characterization techniques. This overview also identifies innovative designs and applications of new types of SMSI systems in catalytic chemistry and highlights their pivotal role in enhancing catalytic performance, selectivity, and stability in specific cases. Particularly notable is the discovery of SMSI between active metals and metal carbides, which opens up a new era in the field of SMSI. Additionally, the strong interactions between atomically dispersed metals and supports are discussed, with an emphasis on the electronic effects of the support. The chemical nature of SMSI and its underlying catalytic mechanisms are also elaborated upon. It is evident that SMSI modification has become a powerful tool for enhancing catalytic performance in various catalytic applications.

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