Preprocessed Monomer Interfacial Polymerization for Scalable Fabrication of High-Valent Cluster-Based Metal–Organic Framework MembranesClick to copy article linkArticle link copied!
- Yang FengYang FengSchool of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaState Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaCollege of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaMore by Yang Feng
- Zixi Kang*Zixi Kang*Email: [email protected]School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaState Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaMore by Zixi Kang
- Zhikun WangZhikun WangSchool of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaMore by Zhikun Wang
- Zhanning LiuZhanning LiuSchool of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, P. R. ChinaMore by Zhanning Liu
- Q. Jason NiuQ. Jason NiuThe Institute for Advanced Study, Shenzhen University, Shenzhen 518060, P. R. ChinaMore by Q. Jason Niu
- Weidong FanWeidong FanSchool of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaState Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaMore by Weidong Fan
- Lu QiaoLu QiaoSchool of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaMore by Lu Qiao
- Jia PangJia PangSchool of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaMore by Jia Pang
- Hu ChangHu ChangSchool of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaMore by Hu Chang
- Xiaolei CuiXiaolei CuiState Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaCollege of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaMore by Xiaolei Cui
- Lili FanLili FanSchool of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaState Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaMore by Lili Fan
- Hailing GuoHailing GuoState Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaMore by Hailing Guo
- Rongming WangRongming WangSchool of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaState Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaMore by Rongming Wang
- Dan Zhao*Dan Zhao*Email: [email protected]Department of Chemical & Biomolecular Engineering, National University of Singapore, Singapore 117585, SingaporeMore by Dan Zhao
- Daofeng Sun*Daofeng Sun*Email: [email protected]School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaState Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, Shandong 266580, P. R. ChinaMore by Daofeng Sun
Abstract
Current research on emergent membrane materials with ordered and stable nanoporous structures often overlooks the vital facet of manufacturing scalability. We propose the preprocessed monomer interfacial polymerization (PMIP) strategy for the scalable fabrication of high-valent cluster-based metal–organic framework (MOF) membranes with robust structures. Using a roll-to-roll device on commercial polymer supports, Zr-fum-MOF membranes are continuously processed at room temperature through the PMIP approach. These large-area membranes demonstrate the preeminent hydrogen separation capabilities, boasting an order of magnitude of permeance and a thrice-enhanced selectivity when juxtaposed with conventional polymeric membranes. The obtained PMIP-Zr-fum-MOF membranes possess superior stability in water compared with interfacial polymerization (IP)-processed low-valent metal-ion-based ZIF-8 membranes. Moreover, we have implemented the PMIP strategy’s universality to process the other four diverse MOF membranes. The proposal of PMIP significantly advances the scalable fabrication of water-stable high-valent cluster MOF membranes.
Cited By
This article is cited by 1 publications.
- Yiming Zhang, Hang Ben Yin, Lingzhi Huang, Li Ding, Song Lei, Shane G. Telfer, Jürgen Caro, Haihui Wang. MOF membranes for gas separations. Progress in Materials Science 2025, 26 , 101432. https://doi.org/10.1016/j.pmatsci.2025.101432
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