ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img

Hydrogen Bonded Structures of Confined Water Molecules and Electric Field Induced Shift of Their Equilibrium Revealed by IR Electroabsorption Spectroscopy

View Author Information
Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, Sanda 669-1337, Japan
Cite this: J. Phys. Chem. B 2017, 121, 22, 5573–5581
Publication Date (Web):May 17, 2017
https://doi.org/10.1021/acs.jpcb.7b02171
Copyright © 2017 American Chemical Society

    Article Views

    876

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options
    Supporting Info (1)»

    Abstract

    Abstract Image

    Water confined on a nanometer scale plays an essential role in various chemical and biological processes. Confined water molecules are often exposed to electric fields as manifested by those that occur on protein surfaces or in electrical double layers, but the electric field effects on confined water are not fully understood. We used IR electroabsorption (EA) spectroscopy with unprecedented sensitivity to observe electric-field-induced changes in the OH stretching absorption of water (H2O) molecules dissolved in 1,4-dioxane, which constitute a simple model system for confined water. A multivariate curve resolution analysis of the normal IR spectra (without an electric field) of water in 1,4-dioxane at different concentrations indicates the presence of the monomer and dimer of the confined water molecules and equilibrium between them. We find that the IR EA spectrum that is free from the contribution of field-induced molecular reorientation is mainly attributable to a field-induced shift of the equilibrium toward the dimer. This result demonstrates a possible control of the polarity of confined water by simply applying an external electric field and the ability of our method to elucidate how it is achieved.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jpcb.7b02171.

    • SVD results, comparison of the FTIR spectra of water in 1,4-dioxane at [H2O] = 0.050 and 0.10 M, MCR–ALS analysis of the FTIR spectra of water in THF, IR spectra of H2O in the OH stretching region measured with isotopic dilution with D2O, definition of the angle χ, IR EA spectra of D2O dissolved in 1,4-dioxane, an independent set of the χ-dependent EA spectra of water in 1,4-dioxane, and comparison between the EA spectrum at χ = 55° and the first derivative of the absorption spectrum (PDF)

    Terms & Conditions

    Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machine-readable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 12 publications.

    1. Kosuke Yamazoe, Yuji Higaki, Yoshihiro Inutsuka, Jun Miyawaki, Atsushi Takahara, Yoshihisa Harada. Critical In-Plane Density of Polyelectrolyte Brush for the Ordered Hydrogen-Bonded Structure of Incorporated Water. Langmuir 2022, 38 (10) , 3076-3081. https://doi.org/10.1021/acs.langmuir.1c02895
    2. Shogo Toda, Ryan Clark, Tom Welton, Shinsuke Shigeto. Observation of the Pockels Effect in Ionic Liquids and Insights into the Length Scale of Potential-Induced Ordering. Langmuir 2021, 37 (17) , 5193-5201. https://doi.org/10.1021/acs.langmuir.1c00130
    3. Szu-Hua Chen, Hirotsugu Hiramatsu. Tautomer Structures in Ketose–Aldose Transformation of 1,3-Dihydroxyacetone Studied by Infrared Electroabsorption Spectroscopy. The Journal of Physical Chemistry B 2019, 123 (50) , 10663-10671. https://doi.org/10.1021/acs.jpcb.9b08557
    4. Shogo Toda, Shinsuke Shigeto. Distinct Effects of External Electric Field on Interfacial and Bulk-like Water Confined in Reverse Micelles. The Journal of Physical Chemistry C 2018, 122 (44) , 25515-25523. https://doi.org/10.1021/acs.jpcc.8b08464
    5. Hyosim Yang, Gangseon Ji, Min Choi, Seondo Park, Hyeonjun An, Hyoung-Taek Lee, Joonwoo Jeong, Yun Daniel Park, Kyungwan Kim, Noejung Park, Jeeyoon Jeong, Dai-Sik Kim, Hyeong-Ryeol Park. Suppressed terahertz dynamics of water confined in nanometer gaps. Science Advances 2024, 10 (17) https://doi.org/10.1126/sciadv.adm7315
    6. L. V. Belovolova, M. V. Glushkov. Specific Features of the Structure and Dynamics of Water in Microemulsions of Surface-Active Substances in Organic Solvents. Physics of Wave Phenomena 2021, 29 (4) , 330-351. https://doi.org/10.3103/S1541308X21040026
    7. Yiran Sun, Fei Yu, Cong Li, Xiaohu Dai, Jie Ma. Nano-/Micro-confined Water in Graphene Hydrogel as Superadsorbents for Water Purification. Nano-Micro Letters 2020, 12 (1) https://doi.org/10.1007/s40820-019-0336-3
    8. Takayuki Hiraoka, Shinsuke Shigeto. Interactions of water confined in a metal–organic framework as studied by a combined approach of Raman, FTIR, and IR electroabsorption spectroscopies and multivariate curve resolution analysis. Physical Chemistry Chemical Physics 2020, 22 (32) , 17798-17806. https://doi.org/10.1039/D0CP02958K
    9. Myong In Oh, Mayuri Gupta, Chang In Oh, Donald F. Weaver. Understanding the effect of nanoconfinement on the structure of water hydrogen bond networks. Physical Chemistry Chemical Physics 2019, 21 (47) , 26237-26250. https://doi.org/10.1039/C9CP05014K
    10. Ilia V. Kopanichuk, Valentin A. Novikov, Aleksandr A. Vanin, Elena N. Brodskaya. The electric properties of AOT reverse micelles by molecular dynamics simulations. Journal of Molecular Liquids 2019, 296 , 111960. https://doi.org/10.1016/j.molliq.2019.111960
    11. Moeka Oshiro, Kenji Takashima, Yukio Furukawa. Infrared Stark spectra for a Nylon 6 film. Chemical Physics Letters 2019, 728 , 32-36. https://doi.org/10.1016/j.cplett.2019.04.068
    12. Hirotsugu Hiramatsu. Electric field effects on 1-hydroxyacetone revealed by IR electroabsorption spectroscopy. Chemical Physics Letters 2019, 714 , 18-23. https://doi.org/10.1016/j.cplett.2018.10.064

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect