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Formation of Highly Ordered Terminal Alkyne Self-Assembled Monolayers on the Au{111} Surface through Substitution of 1-Decaboranethiolate

  • Shenkai Wang
    Shenkai Wang
    Department of Chemistry and Biochemistry  and  California NanoSystems Institute, University of California, Los Angeles, Los Angeles, California 90095, United States
    More by Shenkai Wang
  • Dominic P. Goronzy
    Dominic P. Goronzy
    Department of Chemistry and Biochemistry  and  California NanoSystems Institute, University of California, Los Angeles, Los Angeles, California 90095, United States
  • Thomas D. Young
    Thomas D. Young
    Department of Chemistry and Biochemistry  and  California NanoSystems Institute, University of California, Los Angeles, Los Angeles, California 90095, United States
  • Natcha Wattanatorn
    Natcha Wattanatorn
    Department of Chemistry and Biochemistry  and  California NanoSystems Institute, University of California, Los Angeles, Los Angeles, California 90095, United States
  • Logan Stewart
    Logan Stewart
    Department of Chemistry and Biochemistry  and  California NanoSystems Institute, University of California, Los Angeles, Los Angeles, California 90095, United States
  • Tomáš Baše*
    Tomáš Baše
    Institute of Inorganic Chemistry, The Czech Academy of Sciences, Husinec-Řež 250 68, Czech Republic
    *E-mail: [email protected] (T.B.).
  • , and 
  • Paul S. Weiss*
    Paul S. Weiss
    Department of Chemistry and Biochemistry,  California NanoSystems Institute  and  Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, California 90095, United States
    *E-mail: [email protected] (P.S.W.).
Cite this: J. Phys. Chem. C 2019, 123, 2, 1348–1353
Publication Date (Web):December 25, 2018
https://doi.org/10.1021/acs.jpcc.8b11033
Copyright © 2018 American Chemical Society

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    Abstract

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    The reaction aimed at completing and closing the open cages of 1-decaboranethiol self-assembled monolayers (SAMs) on Au{111} with 4-phenyl-1-butyne results in highly ordered monolayers of 4-phenyl-1-butyne. The initially disordered 1-decaboranethiolate changed into ordered (√3×√3)R 30° lattices on Au{111} typical of alkyne SAMs, indicating the complete substitution of 1-decaboranethiolate moieties, as determined by nanoscale imaging with scanning tunneling microscopy and X-ray photoelectron spectroscopy. Vibrational spectroscopy results indicate that the process happens gradually and that alkynyl groups are not totally oxidized in the ordered 4-phenyl-1-butyne monolayer.

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