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High-Speed Complementary Integrated Circuit with a Stacked Structure Using Fine Electrodes Formed by Reverse Offset Printing
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    High-Speed Complementary Integrated Circuit with a Stacked Structure Using Fine Electrodes Formed by Reverse Offset Printing
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    • Yasunori Takeda*
      Yasunori Takeda
      Research Center for Organic Electronics, Yamagata University, 4-3-16, Jonan, Yonezawa, Yamagata 992-8510, Japan
      *E-mail: [email protected] (Y.T.).
    • Tomohito Sekine
      Tomohito Sekine
      Research Center for Organic Electronics, Yamagata University, 4-3-16, Jonan, Yonezawa, Yamagata 992-8510, Japan
    • Yi-Fei Wang
      Yi-Fei Wang
      Research Center for Organic Electronics, Yamagata University, 4-3-16, Jonan, Yonezawa, Yamagata 992-8510, Japan
      More by Yi-Fei Wang
    • Tomoko Okamoto
      Tomoko Okamoto
      DIC Corporation, 631, Sakado, Sakura, Chiba 285-8668, Japan
    • Hiroyuki Matsui
      Hiroyuki Matsui
      Research Center for Organic Electronics, Yamagata University, 4-3-16, Jonan, Yonezawa, Yamagata 992-8510, Japan
    • Daisuke Kumaki
      Daisuke Kumaki
      Research Center for Organic Electronics, Yamagata University, 4-3-16, Jonan, Yonezawa, Yamagata 992-8510, Japan
    • Shizuo Tokito*
      Shizuo Tokito
      Research Center for Organic Electronics, Yamagata University, 4-3-16, Jonan, Yonezawa, Yamagata 992-8510, Japan
      *E-mail: [email protected] (S.T.).
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    ACS Applied Electronic Materials

    Cite this: ACS Appl. Electron. Mater. 2020, 2, 3, 763–768
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    https://doi.org/10.1021/acsaelm.9b00829
    Published February 20, 2020
    Copyright © 2020 American Chemical Society

    Abstract

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    A reverse offset-printed stacked-structure complementary ring oscillator and operational amplifier (OPA) circuits were constructed on a large-area substrate. Uniform and fine electrodes were fabricated using reverse offset printing with a width of 30 μm and a channel length of 10 μm. Compared to silver nanoparticle electrodes constructed using inkjet printing, a narrow line with a width of 1/5 or less could be formed. All components except the insulating film were formed using a solution process with the printing method. The complementary integrated circuit had a stacked structure, wherein a p-type organic thin-film transistor (OTFT) was stacked on an n-type OTFT with a common gate electrode layer. Because the source and drain electrode layers of the n- and p-type OTFTs were separated, different self-assembled monolayers could be treated using a simple method. The complementary ring oscillator circuit oscillated at a frequency of 2 kHz (12.5 V, five stages) and operated at 1.25 V (96 Hz, nine stages). The fabricated OPA circuit had an output/input voltage ratio of 20. Additionally, it operated over 40 times faster than a similar circuit formed by inkjet printing. Fine electrodes formed by reverse offset printing are useful for improving the performance and miniaturization of printed organic integrated circuits.

    Copyright © 2020 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsaelm.9b00829.

    • Inverter characteristics; symbol diagram of ring oscillators; ring oscillator characteristics; table showing the comparison of ring oscillator characteristics; XPS surface elemental analysis of the printed Ag electrode; and standard deviation of propagation delay time (PDF)

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    This article is cited by 15 publications.

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    ACS Applied Electronic Materials

    Cite this: ACS Appl. Electron. Mater. 2020, 2, 3, 763–768
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsaelm.9b00829
    Published February 20, 2020
    Copyright © 2020 American Chemical Society

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