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Metal-Organic-Framework-Mediated Nitrogen-Doped Carbon for CO2 Electrochemical Reduction

  • Riming Wang
    Riming Wang
    Catalysis Engineering, Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of Technology, van der Maasweg, 2629 HZ Delft, The Netherlands
    More by Riming Wang
  • Xiaohui Sun
    Xiaohui Sun
    Catalysis Engineering, Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of Technology, van der Maasweg, 2629 HZ Delft, The Netherlands
    More by Xiaohui Sun
  • Samy Ould-Chikh
    Samy Ould-Chikh
    KAUST Catalysis Center, Advanced Catalytic Materials, King Abdullah University of Science and Technology, Thuwal 23955, Saudi Arabia
  • Dmitrii Osadchii
    Dmitrii Osadchii
    Catalysis Engineering, Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of Technology, van der Maasweg, 2629 HZ Delft, The Netherlands
  • Fan Bai
    Fan Bai
    Catalysis Engineering, Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of Technology, van der Maasweg, 2629 HZ Delft, The Netherlands
    More by Fan Bai
  • Freek Kapteijn
    Freek Kapteijn
    Catalysis Engineering, Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of Technology, van der Maasweg, 2629 HZ Delft, The Netherlands
  • , and 
  • Jorge Gascon*
    Jorge Gascon
    Catalysis Engineering, Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of Technology, van der Maasweg, 2629 HZ Delft, The Netherlands
    KAUST Catalysis Center, Advanced Catalytic Materials, King Abdullah University of Science and Technology, Thuwal 23955, Saudi Arabia
    *E-mail: [email protected]
    More by Jorge Gascon
Cite this: ACS Appl. Mater. Interfaces 2018, 10, 17, 14751–14758
Publication Date (Web):April 11, 2018
https://doi.org/10.1021/acsami.8b02226
Copyright © 2018 American Chemical Society

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    Abstract

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    A nitrogen-doped carbon was synthesized through the pyrolysis of the well-known metal-organic framework ZIF-8, followed by a subsequent acid treatment, and has been applied as a catalyst in the electrochemical reduction of carbon dioxide. The resulting electrode shows Faradaic efficiencies to carbon monoxide as high as ∼78%, with hydrogen being the only byproduct. The pyrolysis temperature determines the amount and the accessibility of N species in the carbon electrode, in which pyridinic-N and quaternary-N species play key roles in the selective formation of carbon monoxide.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.8b02226.

    • Figures of catalyst structural characterization, including Raman spectroscopy, SEM–EDX, and XPS; summary of N2-physisorption and XPS data; and additional CO2 electroreduction performance (PDF)

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