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Robust, Double-Walled Microcapsules for Self-Healing Polymeric Materials

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Download Hi-Res ImageDownload to MS-PowerPointCite This:ACS Appl. Mater. Interfaces 2010, 2, 4, 1195-1199
    Research Article

    Robust, Double-Walled Microcapsules for Self-Healing Polymeric Materials
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    Department of Chemistry, 600 S. Mathews Avenue, Department of Mechanical Science and Engineering, 1206 W. Green Street, Department of Aerospace Engineering, 104 S. Wright Street, Department of Materials Science and Engineering, 1304 W. Green Street, and Beckman Institute, 405 N. Mathews Avenue, University of Illinois at Urbana−Champaign, Urbana, Illinois 61801
    * Corresponding author. Phone: (217) 244-5289. E-mail: [email protected]
    †Department of Chemistry, University of Illinois at Urbana−Champaign.
    ‡Department of Mechanical Science and Engineering, University of Illinois at Urbana−Champaign.
    §Department of Aerospace Engineering, University of Illinois at Urbana−Champaign.
    ⊥Beckman Institute, University of Illinois at Urbana−Champaign.
    #Department of Materials Science and Engineering, University of Illinois at Urbana−Champaign.
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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2010, 2, 4, 1195–1199
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    https://doi.org/10.1021/am100084k
    Published March 30, 2010
    Copyright © 2010 American Chemical Society
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    Abstract

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    Double-walled polyurethane/poly(urea-formaldehyde) microcapsules (PU/UF) are prepared for use in self-healing materials. This modified encapsulation procedure combines two chemistries to form more robust capsule shell walls in a single operation. Robust capsules are formed by this procedure as long as the aromatic polyisocyanate prepolymer is soluble in the core liquid and the core liquid is compatible with isocyanates. Compared to a standard UF encapsulation, the modified procedure results in capsules with an increase in shell wall thickness from 200 to 675 nm as a function of the amount of PU added to the core liquid. Thermal stability of PU/UF microcapsules prepared with varying amounts of PU is compared to UF microcapsules. Mechanical properties of the PU/UF microcapsules are assessed from single-capsule compression testing.

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    Additional AFM images, TGA curves, shell thickness measurements, and results from capsule compression in a tabular format (PDF). This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cite this: ACS Appl. Mater. Interfaces 2010, 2, 4, 1195–1199
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